Method of producing medically applicable titanium

Patent metadata

Field	Value
Publication number	US-11396690-B2
Application number	US-202016742417-A
Country	US
Kind code	B2
Filing date	Jan 14, 2020
Priority date	Jan 14, 2020
Publication date	Jul 26, 2022
Grant date	Jul 26, 2022

Abstract

A method of producing medically applicable nanostructured titanium with improved mechanical properties includes performing an equal-channel angular pressing (ECAP) and subsequently performing a surface mechanical attrition treatment (SMAT). By performing the ECAP processing on a titanium sample, an ultrafine grained structure is obtained. The ultrafine grained structure may improve the biocompatibility and mechanical properties of pure titanium. When the SMAT processing is performed on the ultrafine grained structure, a nanostructured surface may be obtained. The SMAT processing may be used to enhance the strength of pure titanium to be used in medically applicable implants.

First claim

The invention claimed is:

1. A method of producing nanostructured titanium with improved mechanical properties, comprising:
equal-channel angular pressing (ECAP) a titanium tubing at a temperature of 275 to 325° C. to form an ultrafine grained titanium tubing,
wherein an average grain size of the ultrafine grained titanium tubing is within a range of 400 nanometers (nm) to 600 nm, then
randomly impacting an exposed surface of the ultrafine grained titanium tubing with zirconia shots with a vibration generator at a frequency of 25-75 Hz to subject the exposed surface of the ultrafine grained titanium tubing to a surface mechanical attrition treatment (SMAT) to thereby form
a nanostructured region on a portion of the exposed surface of the ultrafine grained titanium tubing, and
wherein the nanostructured region extends into the exposed surface of the ultrafine grained titanium tubing to a depth of from 100 micrometers (μm) to 125 μm.

2. The method of claim 1 , wherein the ECAPed and SMATed titanium sample improves a cell viability of the titanium sample by 5%-10% in comparison to the titanium sample before the ECAPing and SMATing.

3. The method of claim 1 , the ECAPing is carried out on a system comprising:
an ECAP die, wherein the ECAP die is configured to subject the titanium sample to plastic strain without reducing a cross-sectional area of the titanium sample; and
a sample-passing channel, wherein the sample-passing channel is integrated into the ECAP die,
wherein during the ECAPing the titanium sample is pushed into the sample-passing channel by a plunger at a first end of the sample-passing channel and out through a second end of the sample-passing channel, wherein the second end is configured to be positioned at a channel angle and at a curvature angle to the first end.

4. The method of claim 3 , wherein the channel angle is within a range of 80 degrees (°) to 120°.

5. The method of claim 3 , wherein the curvature angle is within a range of 15° to 28°.

6. The method of claim 3 , wherein a cross-sectional shape of the sample-passing channel and the titanium sample is square.

7. The method of claim 3 , wherein a cross-sectional shape of the sample-passing channel and the titanium sample is rectangular.

8. The method of claim 3 , wherein the ECAP die is 34CrNiMo6 steel alloy.

9. The method of claim 3 , further comprising:
pre-heating the titanium sample before the ECAPing to reduce plunger force.

10. The method of claim 3 , wherein the titanium sample is lubricated with graphite during the ECAPing.

11. The method of claim 3 , wherein during the ECAPing a punch speed of the plunger is within a range of 1 millimeter/second (mm/s) to 4 mm/s.

12. The method of claim 3 , wherein the plunger is H13 tool steel.

13. The method claim 1 , wherein a diameter of each of the plurality of spherical balls is within a range of 4 mm-12 mm.

14. The method of claim 1 , wherein the vibration generator operates at a frequency within a range of 60 Hertz (Hz) 75 Hz.

Assignees

• Univ Prince Mohammad Bin Fahd

Inventors

• Djavanroodi Faramarz

Classifications

• C22F1/183 Primary

  of titanium or alloys based thereon · CPC title