Heat exchanger

Patent metadata

Field	Value
Publication number	US-11396605-B2
Application number	US-201816631931-A
Country	US
Kind code	B2
Filing date	Jul 12, 2018
Priority date	Jul 19, 2017
Publication date	Jul 26, 2022
Grant date	Jul 26, 2022

Abstract

A heat exchanger is provided that is operated in a cooling operation mode in which a region to be heat-exchanged is cooled by the heat exchanger or in a drying operation mode in which the heat exchanger is supplied with wind from a blowing fan. The heat exchanger includes a refrigerant pipe, a cooling fin coupled to the refrigerant pipe, and a hydrophilic coating coated on a surface of the refrigerant pipe or the cooling fin. The hydrophilic coating includes a first type transition metal oxide which becomes acidic by reacting with moisture formed on the refrigerant pipe or the cooling fin to have antimicrobial activity when the heat exchanger is operated in the cooling operation mode, and a second type transition metal oxide or a post-transition metal oxide which has antimicrobial activity when the heat exchanger is operated in the drying operation mode.

First claim

The invention claimed is:

1. A heat exchanger operated in a cooling operation mode for cooling a region to be heat-exchanged or in a drying operation mode for receiving wind supplied from a blowing fan, the heat exchanger comprising:
a refrigerant pipe that defines a flow path of a refrigerant;
a cooling fin coupled to the refrigerant pipe; and
a hydrophilic coating coated on a surface of at least one of the refrigerant pipe or the cooling fin, wherein the hydrophilic coating contains:
a first type transition metal oxide that becomes acidic by reacting with moisture formed on the refrigerant pipe or the cooling fin to have antimicrobial activity when the heat exchanger is operated in the cooling operation mode; and
a second type transition metal oxide or a post-transition metal oxide that has antimicrobial activity when the heat exchanger is operated in the drying operation mode, wherein the first type transition metal oxide exhibits acidity by a catalytic reaction with moisture formed on the refrigerant pipe or the cooling fin to have antimicrobial activity when the heat exchanger is operated in the cooling operation mode, wherein the second type transition metal oxide or the post-transition metal oxide performs antimicrobial activity through a photocatalytic reaction of the heat exchanger when the heat exchanger is operated in the drying operation mode, wherein a total content of the first type transition metal oxide and the second type transition metal oxide or a total content of the first type transition metal oxide and the post-transition metal oxide is 2 to 10 wt. % of the hydrophilic coating, wherein the first type transition metal oxide exhibits weak acidity by the catalytic reaction with moisture formed on the refrigerant pipe or the cooling fin, and wherein a pH value of the weak acidity is in a range of 5 pH to 6 pH.

2. The heat exchanger of claim 1 , wherein a transition metal of the first type transition metal oxide contains at least one selected from a group consisting of tungsten (W), molybdenum (Mo), and zirconium (Zr).

3. The heat exchanger of claim 1 , wherein a transition metal of the second type transition metal oxide contains at least one selected from a group consisting of zinc (Zn), titanium (Ti), and copper (Cu), and a post-transition metal of the post-transition metal oxide contains tin (Sn).

4. The heat exchanger of claim 1 , wherein the hydrophilic coating contains both the second type transition metal oxide and the post-transition metal oxide.

5. The heat exchanger of claim 1 , wherein a total content of the first type transition metal oxide, the second type transition metal oxide, and the post-transition metal oxide is 2 to 10 wt. % of the hydrophilic coating.

6. The heat exchanger of claim 1 , wherein the hydrophilic coating contains at least one hydrophilic polymer selected from a group consisting of polyvinyl alcohol, polyacrylic acid, polyacetic acid, and polyvinylpyrrolidone.

7. The heat exchanger of claim 1 , wherein an average thickness of the hydrophilic coating is 0.7 to 2 μm.

8. The heat exchanger of claim 1 , wherein an average size of the first type transition metal oxide, the second type transition metal oxide, or the post-transition metal oxide is 0.1 to 10 μm.

9. The heat exchanger of claim 2 , wherein the transition metal of the first type transition metal oxide is an alloy.

10. A heat exchanger operated in a cooling operation mode for cooling a region to be heat-exchanged or in a drying operation mode for receiving wind supplied from a blowing fan, the heat exchanger comprising:
a refrigerant pipe that defines a flow path of a refrigerant;
a cooling fin coupled to the refrigerant pipe; and
a hydrophilic coating coated on a surface of at least one of the refrigerant pipe or the cooling fin, wherein the hydrophilic coating contains:
a first type transition metal oxide that becomes acidic by reacting with moisture formed on the refrigerant pipe or the cooling fin to have antimicrobial activity when the heat exchanger is operated in the cooling operation mode; and
a second type transition metal oxide or a post-transition metal oxide that has antimicrobial activity when the heat exchanger is operated in the drying operation mode, wherein the first type transition metal oxide exhibits acidity by a catalytic reaction with moisture formed on the refrigerant pipe or the cooling fin to have antimicrobial activity when the heat exchanger is operated in the cooling operation mode, wherein the second type transition metal oxide or the post-transition metal oxide performs antimicrobial activity through a photocatalytic reaction of the heat exchanger when the heat exchanger is operated in the drying operation mode, wherein a total content of the first type transition metal oxide and the second type transition metal oxide or a total content of the first type transition metal oxide and the post-transition metal oxide is 2 to 10 wt. % of the hydrophilic coating, wherein the hydrophilic coating contains at least one hydrophilic polymer selected from a group consisting of polyvinyl alcohol, polyacrylic acid, polyacetic acid, and polyvinylpyrrolidone, and wherein the hydrophilic coating contains 89 to 98 wt. % of water, 0.1 to 10 wt. % of the hydrophilic polymer, 0.1 to 1 wt. % of a metallic salt, and 0.1 to 3 wt. % of acid and base chemicals.

11. The heat exchanger of claim 10 , wherein the metallic salt contains metal sulfate.

Assignees

• Lg Electronics Inc

Inventors

• Kim Jihyun
• Kim Donghan
• Oh Chohee
• Lee Seojin
• Jin Taegyu
• Hong Sanghyun

Classifications

• F28F2245/02

  hydrophilic · CPC title

• C09D167/04

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C09D167/06 takes precedence) · CPC title

• F24F2013/221

  to avoid the formation of condensate, e.g. dew · CPC title

• F28F2265/20

  for preventing development of microorganisms · CPC title

• F28D2021/0071

  Evaporators · CPC title