Multilayer film

Patent metadata

Field	Value
Publication number	US-11396165-B2
Application number	US-201816622643-A
Country	US
Kind code	B2
Filing date	May 18, 2018
Priority date	Jun 13, 2017
Publication date	Jul 26, 2022
Grant date	Jul 26, 2022

Abstract

Embodiments provide a multilayer film in which: a first acrylic resin layer (α1), an aromatic polycarbonate resin layer (β), and a second acrylic resin layer (α2) are directly laminated in the stated order; the aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (β) is a product of ester exchange between a polycarbonic acid ester of an aromatic dihydroxy compound and a low-crystalline or amorphous aromatic polyester; and the relationships (Tβ−Tα1)≤30 and (Tβ−Tα2)≤30 (where Tα1 is the glass transition temperature of the acrylic resin constituting the first acrylic resin layer (α1), Tα2 is the glass transition temperature of the acrylic resin constituting the second acrylic resin layer (α2), Tβ is the glass transition temperature of the aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (β), and all of the temperatures are measured in degrees Celsius) are satisfied. The glass transition temperature of the aromatic polycarbonate resin should be 100-140° C.

First claim

The invention claimed is:

1. A multilayer film comprising:
a first acrylic resin layer (α1);
an aromatic polycarbonate resin layer (β); and
a second acrylic resin layer (α2),
wherein the first acrylic resin layer (α1), the aromatic polycarbonate resin layer (β), and the second acrylic resin layer (α2) are directly laminated in the stated order, an aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (β) is a product of ester exchange between a polycarbonic acid ester of an aromatic dihydroxy compound and a low-crystalline or amorphous aromatic polyester, and the multilayer film satisfies the following formulae (1-1) and (1-2):
( Tβ−Tα 1 )≤30  (1-1)

( Tβ−Tα 2 )≤30  (1-2),

wherein Tα 1 is a glass transition temperature of an acrylic resin constituting the first acrylic resin layer (α1), Tα 2 is a glass transition temperature of an acrylic resin constituting the second acrylic resin layer (α2), Tβ is a glass transition temperature of an aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (β), and all of the temperatures are determined in ° C., and
wherein the acrylic resin constituting the first acrylic resin layer (α1) and the acrylic resin constituting the second acrylic resin layer (α2) are the same acrylic resin, and the acrylic resin consists of
a structural unit derived from methyl (meth)acrylate in an amount of 50-95 mol %, and
a structural unit derived from vinylcyclohexane in an amount of 50-5 mol % based on 100 mol % of the total sum of structural units derived from polymerizable monomers, or a poly(meth)acrylimide resin.

2. The multilayer film according to claim 1 , wherein the glass transition temperature of the aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (β) is 100-140° C.

3. The multilayer film according to claim 1 , wherein the polycarbonic acid ester of the aromatic dihydroxy compound is a polycarbonic acid ester of bisphenol A.

4. The multilayer film according to claim 1 , wherein the low-crystalline or amorphous aromatic polyester is comprised of:
(1) a structural unit derived from terephthalic acid in an amount of 90-100 mol % based on 100 mol % of the total sum of structural units derived from polycarboxylic acid; and
(2) a structural unit derived from ethylene glycol in an amount of 20-80 mol %, a structural unit derived from 1,4-cyclohexanedimethanol in an amount of 20-80 mol %, and a structural unit derived from diethylene glycol in an amount of 0-10 mol % based on 100 mol % of the total sum of structural units derived from polyol.

5. The multilayer film according to claim 1 , wherein the multilayer film satisfies the following formulae (1-1′), (1-2′), and (1-3):
( Tβ−Tα 1 )≤20  (1-1′)

( Tβ−Tα 2 )≤20  (1-2′)

Tβ≤ 140  (1-3).

6. The multilayer film according to claim 1 , wherein the aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (β) is the product of ester exchange between the polycarbonic acid ester of the aromatic dihydroxy compound and the low-crystalline or amorphous aromatic polyester in the presence of an ester exchange reaction catalyst.

7. The multilayer film according to claim 1 , wherein the multilayer film satisfies the following properties (i) and (ii):
(i) a total light transmittance is 85% or more; and
(ii) a retardation is 75 nm or less.

8. The multilayer film according to claim 7 , wherein the multilayer film further satisfies the following property (iii):
(iii) a water absorption measured under a condition of an immersion time of 24 hours is 1% by mass or less according to a method A in JIS K7209:2009.

9. A multilayer film comprising:
a first acrylic resin layer (α1);
an aromatic polycarbonate resin layer (β); and
a second acrylic resin layer (α2),
wherein the first acrylic resin layer (α1), the aromatic polycarbonate resin layer (β), and the second acrylic resin layer (α2) are directly laminated in the stated order, an aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (β) is comprised of a structural unit derived from an aromatic dihydroxy compound in an amount of 15-80.8 mol %, a structural unit derived from terephthalic acid in an amount of 9.6-42 mol %, a structural unit derived from 1,4-cyclohexanedimethanol in an amount of 3-25 mol %, and a structural unit derived from ethylene glycol in an amount of 4-30 mol % based on 100 mol % of the total sum of structural units derived from all constituent monomers, and the multilayer film satisfies the following formulae (1-1) and (1-2):
( Tβ−Tα 1 )≤30  (1-1)

( Tβ−Tα 2 )≤30  (1-2),

wherein Tα 1 is a glass transition temperature of an acrylic resin constituting the first acrylic resin layer (α1), Tα 2 is a glass transition temperature of an acrylic resin constituting the second acrylic resin layer (α2), Tβ is a glass transition temperature of an aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (β), and all of the temperatures are determined in ° C.; and
wherein the acrylic resin constituting the first acrylic resin layer (α1) and the acrylic resin constituting the second acrylic resin layer (α2) are the same acrylic resin, and the acrylic resin consists of
a structural unit derived from methyl (meth)acrylate in an amount of 50-95 mol %, and
a structural unit derived from vinylcyclohexane in an amount of 50-5 mol % based on 100 mol % of the total sum of structural units derived from polymerizable monomers, or a poly(meth)acrylimide resin.

10. The multilayer film according to claim 9 , wherein the aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (β) is comprised of
a structural unit derived from bisphenol A in an amount of 15-80.8 mol %,
a structural unit derived from terephthalic acid in an amount of 9.6-42 mol %,
a structural unit derived from 1,4-cyclohexanedimethanol in an amount of 3-25 mol %, and
a structural unit derived from ethylene glycol in an amount of 4-30 mol %
based on 100 mol % of the total sum of the structural units derived from all constituent monomers.

11. The multilayer film according to claim 9 , wherein the multilayer film satisfies the following properties (i) and (ii):
(i) a total light transmittance is 85% or more; and
(ii) a retardation is 75 nm or less.

12. The multilayer film according to claim 9 , wherein the multilayer film satisfies the following formulae (1-1′), (1-2′), and (1-3):
( Tβ−Tα 1 )≤20  (1-1′)

( Tβ−Tα 2 )≤20  (1-2′)

Tβ≤ 140  (1-3).

13. The multilayer film according to claim 9 , wherein the aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (β) is a product of ester exchange between a polycarbonic acid ester of the aromatic dihydroxy compound and a low-crystalline or amorphous aromatic polyester in the presence of an ester exchange reaction catalyst.

14. A hard coat laminated film comprising a hard coat on at least one surface of the multilayer film according to claim 1 .

15. An article comprising the film according to claim 1 .

16. A hard coat laminated film comprising a hard coat on at least one surface of the multilayer film according to claim 9 .

17. An article comprising the film according to claim 9 .

Assignees

• Riken Technos Corp

Inventors

• YAMBE Hideaki
• Nakashima Kohei

Classifications

• B32B7/027 Primary

  Thermal properties · CPC title

• B32B27/308

  comprising acrylic (co)polymers · CPC title

• B32B27/36

  comprising polyesters · CPC title

• B32B7/02

  Physical, chemical or physicochemical properties · CPC title

• B32B2255/10

  on synthetic resin layer or on natural or synthetic rubber layer · CPC title