Nickel-cobalt-manganese complex hydroxide particles and method for producing same, positive electrode active material for nonaqueous electrolyte secondary battery and method for producing same, and nonaqueous electrolyte secondary battery

Patent metadata

Field	Value
Publication number	US-11394024-B2
Application number	US-201916592365-A
Country	US
Kind code	B2
Filing date	Oct 3, 2019
Priority date	Dec 2, 2009
Publication date	Jul 19, 2022
Grant date	Jul 19, 2022

Abstract

An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same. A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.

First claim

The invention claimed is:

1. Nickel cobalt manganese composite hydroxide particles represented by a general formula: Ni x Co y Mn 2 M t (OH) 2+α , where 0.3≤x≤0.7, 0.1≤y≤0.4, 0.1≤z≤0.5, 0≤t≤0.02, x+y+z+t=1, 0:91≤0.5, and M is at least one additional element selected from the group consisting of Ti, V, Cr, Al, Mg, Zr, Nb, Mo, Hf, Ta and W,
the nickel cobalt manganese composite hydroxide particles being spherical secondary particles formed by aggregation in a random direction of a plurality of platelike primary particles having an average thickness of 10 to 300 nm and an average length of 100 to 3000 nm,
the secondary particles have an average particle diameter of 3 to 7 μm, and a value represented by an expression of: [(d90−d10)/average particle diameter] as a marker indicating spreading of a particle size distribution of 0.55 or less.

2. The nickel cobalt manganese composite hydroxide particles according to claim 1 , wherein
at least one of the additional elements are uniformly distributed inside the secondary particles and/or surfaces thereof are uniformly covered with at least one of the additional elements.

3. The nickel cobalt manganese composite hydroxide particles according to claim 1 , wherein
the nickel cobalt manganese composite hydroxide particles are produced by the production method comprising:
a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation containing a metal compound having nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and
a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.

Assignees

• Sumitomo Metal Mining Co
• Toyota Motor Co Ltd

Inventors

• Toya Hiroyuki
• Imaizumi Shin
• Mori Kensaku
• Fukui Atsushi
• Ikeuchi Kenji
• Ryoshi Kazuomi
• Osako Toshiyuki
• Nagai Hiroki

Classifications

• C01G53/82 Primary

  Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• C01P2002/52

  containing elements as dopants · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/525 Primary

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title