Inkjet inks

Patent metadata

Field	Value
Publication number	US-11390764-B2
Application number	US-201716617539-A
Country	US
Kind code	B2
Filing date	Sep 19, 2017
Priority date	Sep 19, 2017
Publication date	Jul 19, 2022
Grant date	Jul 19, 2022

Abstract

The present disclosure is drawn inkjet inks, which can include an aqueous ink vehicle and a pigment particle having a block copolymer attached to a surface of the pigment particle. The block copolymer can be linked to the surface through a nitrogen atom-containing coupling group bonded to the surface through the nitrogen atom. The block copolymer can include a steric stabilizing block formed by polymerizing a monomer having a sterically bulky group, and an ionic stabilizing block formed by polymerizing a monomer having an acidic group or a basic group.

First claim

What is claimed is:

1. An inkjet ink, comprising:
an aqueous ink vehicle; and
a pigment particle having a block copolymer attached to a surface of the pigment particle, wherein the block copolymer is linked to the surface through a nitrogen atom-containing coupling group bonded to the surface through the nitrogen atom, and wherein the block copolymer comprises:
a steric stabilizing block formed by polymerizing a monomer having a sterically bulky group, and
an ionic stabilizing block formed by polymerizing a monomer having an acid group or a base group.

2. The inkjet ink of claim 1 , wherein the block copolymer is a diblock copolymer comprising an inner ionic stabilizing group and an outer steric stabilizing group.

3. The inkjet ink of claim 1 , wherein the block copolymer is a triblock copolymer comprising an inner steric stabilizing group, a middle ionic stabilizing group, and an outer steric stabilizing group.

4. The inkjet ink of claim 1 , wherein the block copolymer linked to the nitrogen atom-containing coupling group has general formula 1, general formula 2, or general formula 3, as shown below:

wherein:
L 1 , L 2 , and L 3 are each independently a covalent bond or chemical structure providing a covalent bond between different blocks selected from C—C, C═C, or C—N;
SG 1 and SG 2 each independently represent a solubilizing and sterically bulky group, which helps to increase the solubility of the polymer and stabilize the colorant particles, selected from alkyl groups, alkoxy groups, branched alkyl groups, branched alkoxy groups, aliphatic esters, branched aliphatic esters, substituted phenyl groups, or macromolecular monomers;
FG represents a functional group that provides charging sites to pigment surfaces, selected from acidic functional groups and basic groups; and
x, y and z are each independently an integer from 1 to about 5,000; and n is an integer from 1 to about 100.

5. The inkjet ink of claim 1 , wherein the monomer of the ionic stabilizing block comprises an acidic or basic group that is a hydroxyl, a carboxylate, a sulfonic acid, a phosphonic acid, a phosphorous acid, a primary amine, a secondary amine, a tertiary amine, pyridine, or imidazoline.

6. The inkjet ink of claim 1 , wherein the monomer of the steric stabilizing block is

where m is an integer from 1 to 10 and n is an integer from 1 to 500.

7. The inkjet ink of claim 1 , wherein the monomer of the steric stabilizing block is

where R 1 , R 2 , R 3 , R 4 , and R 5 are independently alkyl groups, alkoxy groups, branched alkyl groups, branched alkoxy groups, or substituted aryl groups.

8. The inkjet ink of claim 1 , further comprising a binder.

9. The inkjet ink of claim 8 , wherein the binder comprises a polyurethane dispersion or a latex dispersion.

10. The inkjet ink of claim 8 , wherein the binder is curable with ultraviolet radiation and further comprises a photo initiator.

11. An inkjet printing system, comprising:
an intermediate transfer member;
an inkjet ink, comprising:
an aqueous ink vehicle, and
a pigment particle having a block copolymer attached to a surface of the pigment particle, wherein the block copolymer is linked to the surface through a nitrogen atom-containing coupling group bonded to the surface through the nitrogen atom, and wherein the block copolymer comprises a steric stabilizing block formed by polymerizing a monomer having a sterically bulky group, and an ionic stabilizing block formed by polymerizing a monomer having an acidic group or a basic group; and

an inkjet printhead positioned to jet the inkjet ink onto the intermediate transfer member.

12. The inkjet printing system of claim 11 , wherein the intermediate transfer member comprises a non-absorbent surface on which the inkjet ink is printed.

13. The inkjet printing system of claim 11 , wherein the intermediate transfer member is heated.

14. A method of inkjet printing, comprising:
jetting an inkjet ink onto an intermediate transfer member to form an image, wherein the inkjet ink comprises:
an aqueous ink vehicle, and
a pigment particle having a block copolymer attached to a surface of the pigment particle, wherein the block copolymer is linked to the surface through a nitrogen atom-containing coupling group bonded to the surface through the nitrogen atom, and wherein the block copolymer comprises a steric stabilizing block formed by polymerizing a monomer having a sterically bulky group, and an ionic stabilizing block formed by polymerizing a monomer having an acidic group or a basic group; and

transferring the image from the intermediate transfer member to a print medium.

15. The method of claim 14 , further comprising heating the intermediate transfer member to dry the image.

Assignees

• Hewlett Packard Development Co

Inventors

• Zhou Zhang-Lin
• Li Shao-Wei

Classifications

• B41M5/03

  by pressure · CPC title

• C08K5/56

  Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond · CPC title

• B41J2002/012

  with intermediate transfer member · CPC title

• B41M5/0256

  the transferable ink pattern being obtained by means of a computer driven printer, e.g. an ink jet or laser printer, or by electrographic means · CPC title

• B41J2/01 Primary

  Ink jet · CPC title