Polymer electrolyte and preparation method therefor

US11387489B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-11387489-B2
Application numberUS-201816487725-A
CountryUS
Kind codeB2
Filing dateSep 21, 2018
Priority dateSep 21, 2017
Publication dateJul 12, 2022
Grant dateJul 12, 2022

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Abstract

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A polymer electrolyte including a poly(ethylene oxide) (PEO) containing polymer; and a lithium salt, wherein a terminal of the poly(ethylene oxide) containing polymer is substituted with a sulfur compound functional group, a nitrogen compound functional group or a phosphorus compound functional group, and a method for preparing the same and a battery containing the same.

First claim

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The invention claimed is: 1. A polymer electrolyte comprising: a poly(ethylene oxide) containing polymer; and a lithium salt, wherein the poly(ethylene oxide) containing polymer is represented by formula 2 or formula 3 below: wherein n is a repeating unit of an integer of 10 to 120, and R is an alkyl chain having 1-4 carbon atoms. 2. The polymer electrolyte according to claim 1 , wherein the poly(ethylene oxide) containing polymer is represented by formula 2 below: wherein n is a repeating unit of an integer of 10 to 120, and R is an alkyl chain having 1-4 carbon atoms. 3. The polymer electrolyte according to claim 1 , wherein the poly(ethylene oxide) containing polymer is represented by formula 3 below: wherein n is a repeating unit of an integer of 10 to 120, and R is an alkyl chain having 1-4 carbon atoms. 4. The polymer electrolyte according to claim 1 , wherein the lithium salt is at least one selected from the group consisting of LiCl, LiBr, LiI, LiClO 4 , LiBF 4 , LiB 10 Cl 10 , LiPF 6 , LiCF 3 SO 3 , LiCF 3 CO 2 , LiAsF 6 , LiSbF 6 , LiAlCl 4 , CH 3 SO 3 Li, CF 3 SO 3 Li, LiSCN, LiC(CF 3 SO 2 ) 3 , (CF 3 SO 2 ) 2 NLi, (FSO 2 ) 2 NLi, chloroborane lithium, lithium lower aliphatic carboxylate, lithium 4-phenylborate, imide, and bis(trifluoromethane sulfonyl)imide (LiTFSI). 5. The polymer electrolyte according to claim 1 , wherein the poly(ethylene oxide) containing polymer has a molecular weight in the range of 1-20 kg/mol. 6. The polymer electrolyte according to claim 1 , wherein in the polymer electrolyte, ethylene oxide (EO) of the poly(ethylene oxide) containing polymer and lithium (Li + ) of the lithium salt are present in a ratio of concentration of [Li + ]/[EO] between 0.02 and 0.08. 7. The polymer electrolyte according to claim 1 , wherein an ion transference characteristic of the polymer electrolyte is 10 −5 to 10 −3 S/cm. 8. The polymer electrolyte according to claim 1 , wherein the polymer electrolyte is a solid electrolyte for an all-solid state battery. 9. A method of preparing the polymer electrolyte according to claim 1 , comprising the steps of: (a) adding a phosphorus compound to a poly(ethylene oxide) containing polymer to modify a terminal of the poly(ethylene oxide) containing polymer; and (b) adding a lithium salt to the product of (a), wherein the poly(ethylene oxide) containing polymer is represented by formula 2 or formula 3 below: wherein n is a repeating unit of an integer of 10 to 120, and R is an alkyl chain having 1-4 carbon atoms. 10. The method of preparing the polymer electrolyte according to claim 9 , wherein in step (a), the phosphorus compound is added, wherein the phosphorus compound is a diethyl phosphonate compound or a phosphonic acid compound. 11. An all-solid state battery comprising: a positive electrode, a negative electrode and a solid polymer electrolyte interposed therebetween, wherein the solid polymer electrolyte is the polymer electrolyte of claim 1 .

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What does patent US11387489B2 cover?
A polymer electrolyte including a poly(ethylene oxide) (PEO) containing polymer; and a lithium salt, wherein a terminal of the poly(ethylene oxide) containing polymer is substituted with a sulfur compound functional group, a nitrogen compound functional group or a phosphorus compound functional group, and a method for preparing the same and a battery containing the same.
Who is the assignee on this patent?
Lg Chemical Ltd, Postech Acad Ind Found, Lg Energy Solution Ltd
What technology area does this patent fall under?
Primary CPC classification H01M10/0565. Mapped technology areas include Electricity.
When was this patent published?
Publication date Tue Jul 12 2022 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 5 related publications on this page (citations in our corpus or others sharing the same primary CPC).