Laser induced graphene coated optical fibers

Patent metadata

Field	Value
Publication number	US-11384604-B2
Application number	US-202017018524-A
Country	US
Kind code	B2
Filing date	Sep 11, 2020
Priority date	Sep 30, 2016
Publication date	Jul 12, 2022
Grant date	Jul 12, 2022

Abstract

Optical fiber having a graphene coating, a method to apply a graphene coating onto an optical fiber, and a fiber optic cable having a graphene coating are disclosed. A first carbon based coating is applied to an optical fiber along a longitudinal axis of the optical fiber. A laser beam is focused at the first carbon based coating. A first surface of the first carbon based coating is photothermally converted into a first layer of graphene.

First claim

We claim:

1. A method to apply a graphene coating onto an optical fiber, the method comprising:
applying a first carbon based coating to an optical fiber along a longitudinal axis of the optical fiber;
focusing a laser beam at the first carbon based coating;
photothermally converting a first surface of the first carbon based coating into a first layer of graphene; and
forming a plurality of electrical components on the first layer of graphene.

2. The method of claim 1 , wherein photothermally converting the first surface of the first carbon based coating into the first layer of graphene comprises converting carbon atoms of the first carbon based coating from having an sp3 hybridization to an sp2 hybridization.

3. The method of claim 1 , further comprising:
applying a second carbon based coating to the optical fiber along the longitudinal axis of the optical fiber; and
photothermally converting a first surface of a second carbon based coating into a second layer of graphene,
wherein the second layer of graphene is positioned in between an optical core component of the optical fiber and the first layer of graphene.

4. The method of claim 1 , further comprising:
photothermally converting the first surface of the first carbon based coating into a graphene electrode pattern; and
forming at least one of positive electrode and at least one of negative electrode from the graphene electrode pattern,
wherein the plurality of electrical components are formed from the at least one positive and the at least one negative graphene electrode.

5. The method of claim 4 , further comprising:
forming a power source from the plurality of electrical components,
wherein the power source supplies power to a downhole tool.

6. The method of claim 4 , further comprising:
forming a sensor component from the plurality of electrical components,
wherein the sensor component provides measurements of a downhole environment.

7. The method of claim 6 , wherein the sensor component is operable to measure at least one of a pressure, temperature, resistivity, electromagnetic field strength and direction, acoustic field strength, radioactive flux, water content, and pH of the downhole environment.

8. The method of claim 1 , further comprising treating the first layer of graphene with a charged chemical to form a microsupercapacitor on the first layer of graphene.

9. The method of claim 8 , further comprising selecting the charged chemical from at least one of manganese dioxide, ferric oxyhydroxide, polyaniline, and poly(vinyl alcohol).

10. The method of claim 1 , further comprising combining the first layer of graphene with at least one of MoS2, hexagonal boron nitride, and transition metal dichalcogenides to form at least one of the plurality of electrical components.

11. The method of claim 1 , further comprising disposing a preformed electrical component onto the first layer of graphene.

12. The method of claim 1 , further comprising applying an intermediary layer around the optical fiber.

13. The method of claim 12 , further comprising:
applying second carbon based coating to the intermediary layer along the longitudinal axis of the optical fiber;
focusing the laser beam at the second carbon based coating; and
photothermally converting a first surface of the second carbon based coating into a second layer of graphene.

14. The method of claim 12 , wherein the intermediary layer is applied to the optical fiber before first carbon based coating to the optical fiber.

15. A method to apply a graphene coating onto an optical fiber, the method comprising:
applying a first carbon based coating to an optical fiber along a longitudinal axis of the optical fiber;
focusing a laser beam at a first carbon based coating of the optical fiber;
photochemically converting a first surface of the first carbon based coating into a first layer of graphene; and
forming a plurality of electrical components on the first layer of graphene.

16. The method of claim 15 , further comprising:
applying a second carbon based coating to the optical fiber along the longitudinal axis of the optical fiber; and
photochemically converting a first surface of a second carbon based coating into a second layer of graphene,
wherein the second layer of graphene is positioned in between an optical core component of the optical fiber and the first layer of graphene.

17. The method of claim 15 , further comprising disposing a preformed electrical component onto the first layer of graphene.

18. The method of claim 15 , further comprising applying an intermediary layer around the optical fiber.

Assignees

• Halliburton Energy Services Inc

Inventors

• Bhongale Satyan Gopal
• Stark Daniel Joshua
• Samson Etienne
• Gao Li

Classifications

• E21B47/00

  Survey of boreholes or wells (monitoring pressure or flow of drilling fluid E21B21/08) · CPC title

• E21B17/003 Primary

  with electrically conducting or insulating means (E21B17/028 and E21B17/023 take precedence) · CPC title

• G02B6/443

  Protective covering · CPC title

• G02B6/02395 Primary

  Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture (G02B6/02052, G02B6/02057, G02B6/024, G02B6/032, G02B6/105, G02B6/14 take precedence; coating on fibre gratings G02B6/02104; multilayer core or cladding G02B6/036; reinforcing splice joints G02B6/2558; optical cables, i.e. comprising protective structures external to the protective coating such as a jacket or plural coated optical fibres G02B6/44; coating of glass to obtain optical fibres C03C25/104) · CPC title

• G02B6/4479

  Manufacturing methods of optical cables · CPC title