Direct olefin reduction of thermally cracked hydrocarbon streams

Patent metadata

Field	Value
Publication number	US-11384293-B2
Application number	US-202016807880-A
Country	US
Kind code	B2
Filing date	Mar 3, 2020
Priority date	May 16, 2016
Publication date	Jul 12, 2022
Grant date	Jul 12, 2022

Abstract

A process that catalytically converts olefinic (Alkenes, typically liquid at standard temperature and pressure) material in thermally cracked streams to meet olefin content specifications for crude oil transport pipelines. A thermally cracked stream or portion of a thermally cracked stream is selectively reacted to reduce the olefin content within a reactor operating at specific, controlled conditions in the presence of a catalyst and the absence of supplemental hydrogen. The process catalyst is comprised of a blend of select catalyzing metals supported on an alumina, silica or shape selective zeolite substrate together with appropriate pore acidic components.

First claim

What is claimed is:

1. A process for producing an upgraded hydrocarbon product, comprising:
subjecting a heavy hydrocarbon stream to a thermal cracking treatment o produce an olefin-containing hydrocarbon stream and a cracked bitumen stream;
supplying the olefin-containing hydrocarbon stream to a catalytic reactor for contacting a catalyst material without the addition of supplemental hydrogen to convert olefins and produce a treated hydrocarbon stream with a reduced olefin content, the catalyst material comprising:
a support material; and
a catalytic metal material comprising:
an olefin cracking metal catalyst to crack olefins into smaller hydrocarbon components; and
a reforming metal catalyst for converting the smaller hydrocarbon components into longer-chain hydrocarbons by reaction pathways that include polymerization, cyclization and aromatization;

withdrawing the treated hydrocarbon stream from the catalytic reactor.

2. The process of claim 1 , wherein the heavy hydrocarbon stream is a bitumen stream.

3. The process of claim 2 , wherein the thermal cracking treatment is performed in a thermal cracking unit from which the olefin-containing hydrocarbon stream and the cracked heavy hydrocarbon stream are removed.

4. The process of claim 3 , further comprising combining at least a portion of the cracked heavy hydrocarbon stream and at least a portion of the treated hydrocarbon stream to form a combined hydrocarbon stream.

5. The process of claim 4 , further comprising cooling the treated hydrocarbon stream after withdrawal from the catalytic reactor, and separating the cooled treated hydrocarbon stream into a vapour stream and a liquid stream.

6. The process of claim 5 , wherein the liquid stream is combined with at least a portion of the cracked heavy hydrocarbon stream to form the combined hydrocarbon stream.

7. The process of claim 1 , further comprising adding a supplementary stream comprising low carbon number molecules to the olefin-containing hydrocarbon stream prior to supplying to the catalytic reactor.

8. The process of claim 7 , wherein the low carbon number molecules comprise olefins.

9. The process of claim 7 , wherein the low carbon number molecules comprise methane, ethane, ethylene, propane, propylene, butane or butylene or a combination thereof.

10. The process of claim 1 , wherein the catalytic reactor comprises a vessel sized for flows between liquid hourly space velocities of 0.1 h −1 and 2 h −1 .

11. The process of claim 1 , wherein the catalytic reactor is operated between atmospheric pressure and 70 bar.

12. The process of claim 11 , wherein the olefin cracking metal catalyst comprises silver and the reforming metal catalyst comprises gallium.

13. The process of claim 1 , wherein the catalytic reactor is operated between 70 bar and 140 bar.

14. The process of claim 13 , wherein the olefin cracking metal catalyst comprises silver and the reforming metal catalyst comprises platinum or palladium.

15. The process of claim 1 , wherein the catalytic reactor is operated at temperatures between 300° F. and 662° F.

16. The process of claim 1 , wherein the olefin-containing hydrocarbon stream is liquid phase when entering the catalytic reactor.

17. The process of claim 1 , wherein the catalytic reactor comprises:
a main catalytic bed comprising the catalyst material; and
an upstream pre-treatment unit configured to remove contaminants, the upstream pre-treatment unit comprising a catalytic bed or an absorbent bed and being configured to remove at least sulfur-based molecules that would have deleterious effects on the catalyst material.

18. The process of claim 1 , wherein the olefin cracking metal catalyst comprises at least one noble metal comprising silver.

19. The process of claim 18 , wherein the reforming metal catalyst comprises at least one platinum group metal or at least one post-transition metal, or a combination thereof.

20. The process of claim 19 , wherein the at least one platinum group metal is selected from the group consisting of palladium and platinum.

21. The process of claim 19 , wherein the at least one post-transition metal is gallium.

22. The process of claim 19 , wherein the support material has acidic activity.

23. The process of claim 19 , wherein the support material comprises alumina-based material, silica-based material or zeolite material or a combination thereof.

24. The process of claim 23 , wherein the support material is formed as an extruded structure.

25. The process of claim 19 , wherein the catalytic metal material is present in an amount of at least 0.1 wt % and less than 10 wt % on a total weight basis of the catalyst material.

26. The process of claim 1 , wherein conversion of the olefins in the catalytic reactor is at least 75 wt % based on the total amount of olefins in the olefin-containing hydrocarbon stream supplied into the catalytic reactor.

27. The process of claim 1 , wherein conversion of the olefins is performed without supplemental hydrogen donor compounds added to the catalytic reactor.

28. The process of claim 1 , wherein the catalytic reactor comprises:
an inlet to introduce the olefin-containing hydrocarbon stream;
a reactor body in fluid communication with the inlet to receive the olefin-containing hydrocarbon stream, the reactor body containing a flow distribution assembly and a fixed reactor bed comprising the catalyst material for flowing the olefin-containing hydrocarbon stream to contact the reactor bed;
temperature, pressure and flow control units to control process conditions imposed in the catalytic reactor;
an outlet in fluid communication with the reactor body for removal of the treated hydrocarbon stream.

29. A process for producing an upgraded bitumen product, comprising:
subjecting a bitumen stream to a cracking treatment to produce an olefin-containing hydrocarbon stream and a cracked bitumen stream;
supplying the olefin-containing hydrocarbon stream as a liquid to a catalytic reactor for contacting a catalyst material without the addition of supplemental hydrogen to convert olefins and produce a treated hydrocarbon stream with a reduced olefin content, the catalyst material comprising:
a support material; and
a catalytic metal material comprising:
an olefin cracking metal catalyst o crack olefins into smaller hydrocarbon components; and
a reforming metal catalyst for converting the smaller hydrocarbon components into longer-chain hydrocarbons by reaction pathways that include polymerization and aromatization;

withdrawing the treated hydrocarbon stream from the catalytic reactor;
separating the treated hydrocarbon stream to produce a vapour hydrocarbon stream and a liquid stream; and
combining at least a portion of the liquid stream and at least a portion of the cracked bitumen stream to produce the upgraded bitumen product.

Assignees

• Suncor Energy Inc

Inventors

• Corscadden Tom
• Ramesat Darius
• Guffey Frank David
• Liu Shunlan
• Diduch Greg

Classifications

• C10G53/02

  plural serial stages only · CPC title

• C10G2400/30

  Aromatics · CPC title

• C10G53/08

  including at least one sorption step · CPC title

• C10G29/04 Primary

  Metals, or metals deposited on a carrier · CPC title

• C10G35/04

  Catalytic reforming · CPC title