Fluororubber composition and fluororubber crosslinked product

Patent metadata

Field	Value
Publication number	US-11384223-B2
Application number	US-201916702965-A
Country	US
Kind code	B2
Filing date	Dec 4, 2019
Priority date	Jun 6, 2017
Publication date	Jul 12, 2022
Grant date	Jul 12, 2022

Abstract

A fluororubber composition containing a ternary fluororubber polymer including vinylidene fluoride, perfluorovinyl ether and tetrafluoroethylene; a reaction product of silica-aluminum silicate with vinyl ethoxysilane; and hydrotalcite. The fluororubber composition does not substantially contain magnesium oxide and calcium hydroxide. The fluororubber composition contains 2 to 55 parts by weight of the reaction product of silica-aluminum silicate with vinyl ethoxysilane and 0.5 to 10 parts by weight of the hydrotalcite relative to 100 parts by weight of the ternary fluororubber polymer.

First claim

What is claimed is:

1. A fluororubber composition comprising: a ternary fluororubber polymer including vinylidene fluoride, perfluorovinyl ether and tetrafluoroethylene, the ternary fluororubber polymer has a fluoride content of 64 to 67% by weight; and a reaction product of silica-aluminum silicate with vinyl ethoxysilane, wherein the fluororubber composition does not substantially contain magnesium oxide and calcium hydroxide; and the fluororubber composition contains 10 to 60 parts by weight of the reaction product of silica-aluminum silicate with vinyl ethoxysilane relative to 100 parts by weight of the ternary fluororubber polymer.

2. A fluororubber composition comprising: a ternary fluororubber polymer including vinylidene fluoride, perfluorovinyl ether and tetrafluoroethylene, the ternary fluororubber polymer has a fluoride content of 64 to 67% by weight; a reaction product of silica-aluminum silicate with vinyl ethoxysilane; and hydrotalcite, wherein the fluororubber composition does not substantially contain magnesium oxide and calcium hydroxide; and the fluororubber composition contains 5 to 55 parts by weight of the reaction product of silica-aluminum silicate with vinyl ethoxysilane and 0.5 to 9 parts by weight of the hydrotalcite relative to 100 parts by weight of the ternary fluororubber polymer.

3. A fluororubber crosslinked product obtained by crosslinking the fluororubber composition according to claim 1 .

4. A fluororubber crosslinked product obtained by crosslinking the fluororubber composition according to claim 2 .

5. The fluororubber composition of claim 1 , wherein the fluororubber composition contains 10 to 30 parts by weight of the reaction product of silica-aluminum silicate with vinyl ethoxysilane relative to 100 parts by weight of the ternary fluororubber polymer.

6. The fluororubber composition of claim 2 , wherein the fluororubber composition contains 5 to 30 parts by weight of the reaction product of silica-aluminum silicate with vinyl ethoxysilane relative to 100 parts by weight of the ternary fluororubber polymer.

7. The fluororubber composition of claim 6 , wherein the fluororubber composition comprises 3 to 9 parts by weight of the hydrotalcite relative to 100 parts by weight of the ternary fluororubber polymer.

8. The fluororubber composition of claim 1 , wherein the fluororubber composition comprises a peroxide crosslinking agent and zinc oxide, where the zinc oxide being present at 0.1 parts by weight relative to 100 parts by weight of the ternary fluororubber polymer.

9. The fluororubber composition of claim 8 , wherein the peroxide crosslinking agent is present at 0.5 to 5 parts by weight relative to 100 parts by weight of the ternary fluororubber polymer.

10. The fluororubber composition of claim 1 , wherein the fluororubber composition comprises 0.1 parts by weight or less of a total content of magnesium oxide and calcium hydroxide relative to 100 parts by weight of the ternary fluororubber polymer.

11. The fluororubber composition of claim 2 , wherein the fluororubber composition comprises a peroxide crosslinking agent and zinc oxide, where the zinc oxide being present at 0.1 parts by weight relative to 100 parts by weight of the ternary fluororubber polymer.

12. The fluororubber composition of claim 11 , wherein the peroxide crosslinking agent is present at 0.5 to 5 parts by weight relative to 100 parts by weight of the ternary fluororubber polymer.

13. The fluororubber composition of claim 2 , wherein the fluororubber composition comprises 0.1 parts by weight or less of a total content of magnesium oxide and calcium hydroxide relative to 100 parts by weight of the ternary fluororubber polymer.

14. A fluororubber composition comprising:
a ternary fluororubber polymer including vinylidene fluoride, perfluorovinyl ether and tetrafluoroethylene, the ternary fluororubber polymer has a fluoride content of 64 to 67% by weight;
a reaction product of silica-aluminum silicate with vinyl ethoxysilane, the reaction product of silica-aluminum silicate with vinyl ethoxysilane is present at 10 to 30 parts by weight relative to 100 parts by weight of the ternary fluororubber polymer;
a peroxide crosslinking agent, the peroxide crosslinking agent is present at 0.5 to 5 parts by weight relative to 100 parts by weight of the ternary fluororubber polymer;
wherein the fluororubber composition has a total content of magnesium oxide and calcium hydroxide in the range of 0 to 0.1 parts by weight relative to 100 parts by weight of the ternary fluororubber polymer.

Assignees

• Nok Corp

Inventors

• Yoshida Suguru

Classifications

• C08J3/24

  Crosslinking, e.g. vulcanising, of macromolecules (mechanical aspects B29C35/00; crosslinking agents C08K) · CPC title

• C09J127/16 Primary

  Homopolymers or copolymers of vinylidene fluoride · CPC title

• C08K2003/2296

  of zinc · CPC title

• C08J3/203

  Solid polymers with solid and/or liquid additives · CPC title

• C08J2427/18

  Homopolymers or copolymers of tetrafluoroethylene · CPC title