Polymer composition containing polyalkylene carbonate resin and film using the same

Patent metadata

Field	Value
Publication number	US-11384199-B2
Application number	US-201816499564-A
Country	US
Kind code	B2
Filing date	Mar 29, 2018
Priority date	Mar 29, 2017
Publication date	Jul 12, 2022
Grant date	Jul 12, 2022

Abstract

The present invention relates to a polymer composition having improved processability by containing a polyalkylene carbonate resin and a film using the same.

First claim

The invention claimed is:

1. A polymer composition comprising:
3 to 40 wt % a polyalkylene carbonate resin;
30 to 40 wt % of a bio-sourced polyester resin; and
a residual amount of a polyketone resin.

2. The polymer composition of claim 1 , wherein the bio-sourced polyester resin is one or a mixture of two or more selected from the group consisting of polylactic acid, polybutylene succinate, polyhydroxybutyrate, polybutylene adipate terephthalate, and copolymers thereof.

3. The polymer composition of claim 1 , wherein the polyalkylene carbonate resin is C 2 -C 12 polyalkylene carbonate.

4. The polymer composition of claim 3 , wherein the polyalkylene carbonate resin is one or a mixture of two or more selected from the group consisting of polyethylene carbonate, polypropylene carbonate, polypentene carbonate, polyhexene carbonate, polyoctene carbonate, polycyclohexene carbonate, and copolymers thereof.

5. The polymer composition of claim 1 , wherein the polyketone resin is a linear alternating polyketone resin containing carbon monoxide and at least one kind of ethylenically unsaturated hydrocarbon.

6. The polymer composition of claim 1 , wherein the polyketone resin has a melting point of 175 to 300° C. and a melt mass-flow rate (MFR) of 1 to 30 g/10 min, the MFR being measured at 240° C. and 2.16 kg according to ASTM D1238.

7. The polymer composition of claim 1 , wherein a viscosity of the polymer composition satisfies the following Expressions 1 and 2:
A1>A2  [Expression 1]

in Expression 1, A1 is an initial viscosity of the polyketone resin measured at 240° C. and A2 is an initial viscosity of the polymer composition obtained by mixing the polyketone resin and the polyalkylene carbonate resin, the initial viscosity of the polymer composition being measured at 240° C., and
A1>A3  [Expression 2]

in Expression 2, A1 is an initial viscosity of the polyketone resin measured at 240° C. and A3 is an initial viscosity of the polymer composition obtained by mixing the polyketone resin and the polyalkylene carbonate resin, the initial viscosity of the polymer composition being measured after performing annealing at 240° C. for 10 minutes.

8. The polymer composition of claim 1 , wherein a pyrolysis temperature of the polymer composition defined as a temperature at which a weight reduction ratio of the polymer composition reaches 20% when measuring pyrolysis by a thermogravimetric analyzer satisfies the following Expression 3:
T1<T2  [Expression 3]

in Expression 3, T1 is a pyrolysis temperature of the polyalkylene carbonate resin and T2 is a pyrolysis temperature of the polymer composition obtained by mixing the polyketone resin and the polyalkylene carbonate resin.

9. The polymer composition of claim 8 , wherein T1 is lower than 300° C. and T2 is 300° C. or higher.

10. The polymer composition of claim 1 , wherein the polymer composition satisfies the following Expression 4:
P1<P2  [Expression 4]

in Expression 4, P1 is a torque range when extruding the polymer composition and P2 is a torque range when extruding the polyketone resin.

11. A molded product using the polymer composition of claim 1 .

12. The molded product of claim 11 , wherein the molded product is a film.

Assignees

• Sk Innovation Co Ltd

Inventors

• Hong Seung Gweon
• Kim Hye Lim
• Son Jae Myoung
• Lee Yun Kyun

Classifications

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title

• C08L73/00

  Compositions of macromolecular compounds obtained by reactions forming a linkage containing oxygen or oxygen and carbon in the main chain, not provided for in groups C08L59/00 - C08L71/00; Compositions of derivatives of such polymers · CPC title

• C08L2203/30

  used for thermoforming · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L2201/02

  Flame or fire retardant/resistant · CPC title