Entry sheet for drilling and method for drilling processing using same

Patent metadata

Field	Value
Publication number	US-11383307-B2
Application number	US-201615756899-A
Country	US
Kind code	B2
Filing date	Aug 31, 2016
Priority date	Sep 2, 2015
Publication date	Jul 12, 2022
Grant date	Jul 12, 2022

Abstract

An entry sheet for drilling comprising: a metallic foil; and a layer of a resin composition on at least one surface of the metallic foil, the resin composition comprising a polyolefin resin (A) and a water-soluble resin (B), wherein a content of the polyolefin resin (A) is 25 parts by mass or more and 50 parts by mass or less based on 100 parts by mass of the total of the polyolefin resin (A) and the water-soluble resin (B), a content of the water-soluble resin (B) is 50 parts by mass or more and 75 parts by mass or less based on 100 parts by mass of the total of the polyolefin resin (A) and the water-soluble resin (B), and the water-soluble resin (B) comprises a high-molecular-weight water-soluble resin (B-1) having a weight average molecular weight of 2×105 or higher and 1.5×106 or lower.

First claim

The invention claimed is:

1. An entry sheet for drilling comprising:
a metallic foil; and
a layer of a resin composition on at least one surface of the metallic foil, the resin composition comprising a polyolefin resin (A) and a water-soluble resin (B), wherein
a content of the polyolefin resin (A) is 25 parts by mass or more and 50 parts by mass or less based on 100 parts by mass of a total of the polyolefin resin (A) and the water-soluble resin (B),
a content of the water-soluble resin (B) is 50 parts by mass or more and 75 parts by mass or less based on 100 parts by mass of the total of the polyolefin resin (A) and the water-soluble resin (B), and
the water-soluble resin (B) comprises a high-molecular-weight water-soluble resin (B-1) having a weight average molecular weight of 2×10 5 or higher and 1.5×10 6 or lower,
a content of the high-molecular-weight water-soluble resin (B-1) is 2.5 parts by mass or more and 40 parts by mass or less based on 100 parts by mass of the total of the polyolefin resin (A) and the water-soluble resin (B),
wherein the water-soluble resin (B) comprises a low-molecular-weight water-soluble resin (B-2) having a weight average molecular weight of 1×10 3 or higher and 7×10 3 or lower.

2. The entry sheet for drilling according to claim 1 , wherein the polyolefin resin (A) comprises an olefin-(meth)acrylic acid copolymer having a constituent unit derived from an olefin and a constituent unit derived from acrylic acid and/or methacrylic acid.

3. The entry sheet for drilling according to claim 2 , wherein the constituent unit derived from the olefin comprises a constituent unit derived from ethylene.

4. The entry sheet for drilling according to claim 2 , wherein the olefin-(meth)acrylic acid copolymer is an ethylene-(meth)acrylic acid block copolymer having a structure represented by the following formula (1):

wherein R 1 , R 2 , and R 3 each independently represent a hydrogen atom or a methyl group, and m and n each independently represent an integer of 1 or more.

5. The entry sheet for drilling according to claim 2 , wherein a content of the constituent unit derived from the olefin in the olefin-(meth)acrylic acid copolymer is 60 to 99 mol % based on 100 mol % of a total of the constituent unit derived from an olefin and the constituent unit derived from acrylic acid and/or methacrylic acid.

6. The entry sheet for drilling according to claim 1 , wherein the polyolefin resin (A) has a weight average molecular weight of 5×10 3 or higher and 1×10 5 or lower.

7. The entry sheet for drilling according to claim 1 , wherein the water-soluble resin (B) comprises one or more selected from the group consisting of polyethylene oxide; polypropylene oxide; polyvinylpyrrolidone; cellulose derivatives; polyethylene glycol; polypropylene glycol; polytetramethylene glycol; monoether compounds of polyoxyethylene; polyoxyethylene monostearate; polyoxyethylene sorbitan monostearate; polyglycerin monostearate compounds; a polyethylene oxide-polypropylene oxide copolymer; and derivatives thereof.

8. The entry sheet for drilling according to claim 1 , wherein the layer of the resin composition has a thickness of 0.02 to 0.3 mm.

9. The entry sheet for drilling according to claim 1 , wherein the metallic foil has a thickness of 0.05 to 0.5 mm.

10. A method for drilling processing, the method comprising forming a hole in a laminated board or a multi-layer board using the entry sheet for drilling according to claim 1 .

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Kamei Takayuki
• Matsuyama Yousuke
• Ogashiwa Takaaki

Classifications

• C10M2207/289

  containing free hydroxy groups · CPC title

• C10N2020/04

  Molecular weight; Molecular weight distribution · CPC title

• C10M2209/103

  Polyethers, i.e. containing di- or higher polyoxyalkylene groups · CPC title

• H05K3/0047 Primary

  Drilling of holes · CPC title

• C10M111/04

  at least one of them being a macromolecular organic compound · CPC title