Oxygen regulated fuel cell

Patent metadata

Field	Value
Publication number	US-11380923-B2
Application number	US-201514857654-A
Country	US
Kind code	B2
Filing date	Sep 17, 2015
Priority date	Sep 17, 2015
Publication date	Jul 5, 2022
Grant date	Jul 5, 2022

Abstract

A device includes a container having a top plate containing an array of oxygen limiting pinholes and a chamber to hold a chemical hydride fuel, a fuel cell proton exchange membrane electrode assembly supported within the container between the top plate and the chamber, a first gas diffusion layer supported between the fuel cell proton exchange membrane electrode assembly and the top plate, and a second gas diffusion layer supported between the fuel cell proton exchange membrane electrode assembly and the chamber.

First claim

The invention claimed is:

1. A device restricting oxygen and water vapor comprising:
a container having a top plate containing an array of pinholes and a chamber to hold a chemical hydride fuel, each of the pinholes providing a direct oxygen diffusion path between ambient atmosphere and the container; and
a fuel cell membrane electrode assembly supported within the container between the top plate and the chamber, wherein:
a number of pinholes and a diameter of pinholes provide a total cross-sectional area, and the total cross-sectional area and a thickness of pinholes are selected to limit oxygen supplied from the ambient atmosphere to a cathode of the fuel cell membrane electrode assembly to limit an average power generated by the fuel cell membrane electrode assembly;
the number of pinholes, the diameter of pinholes, and the thickness of pinholes restrict water vapor recovered from ambient atmosphere such that oxygen is the primary regulator of electricity generated by the fuel cell membrane electrode assembly;
a first, gas diffusion layer supported between the fuel cell membrane electrode assembly and the top plate, the first gas diffusion layer abutting the top plate to minimize the direct oxygen diffusion path between the first gas diffusion layer and ambient atmosphere; and
a second gas diffusion layer supported between the fuel cell membrane electrode assembly and the chamber.

2. The device of claim 1 wherein each pinhole within the array of pinholes includes a pinhole diameter of 3 mils to limit oxygen supplied to the cathode of the fuel cell membrane electrode assembly.

3. The device of claim 1 wherein a number of the pinholes is selected to provide a total pinhole cross-sectional area corresponding to an average power of a selected load.

4. The device of claim 1 wherein:
each of the pinholes is connected through a corresponding ambient opening of larger diameter to provide the direct oxygen diffusion path between ambient atmosphere and the first gas diffusion layer to obtain exposure to oxygen and water vapor; and
each opening within the array of ambient openings includes an outer hole diameter that is larger than each pinhole diameter within the array of pinholes that prevents fouling of an oxygen path through each opening and each pinhole.

5. The device of claim 1 wherein the pinholes are configured to regulate oxygen provided to the cathode of the fuel cell membrane electrode assembly to control electricity generated without regulation of water vapor.

6. The device of claim 1 and further comprising a perforated support plate supported by the container between the second gas diffusion layer and the chamber.

7. The device of claim 1 and further comprising a hydrogen pressure relief valve supported by the container in the chamber.

8. The device of claim 1 wherein the chamber comprises a chemical hydride fuel separated from the fuel cell membrane electrode assembly by a particulate filter.

9. The device of claim 1 wherein the fuel cell membrane electrode assembly comprises an anode layer adjacent the second gas diffusion layer and a cathode layer adjacent the first gas diffusion layer.

10. The device of claim 1 wherein the fuel cell membrane electrode assembly comprises the cathode layer adjacent the first gas diffusion layer such that the pinholes provide a limited supply of oxygen to the cathode layer through the first gas diffusion layer.

11. A device comprising:
a container having a top plate containing an array of pinholes and a chamber to hold a chemical hydride fuel, each of the pinholes providing a direct oxygen diffusion path between ambient atmosphere and the container; and
a fuel cell membrane electrode assembly supported within the container between the top plate and the chamber positioned to receive oxygen from the pinholes and hydrogen from the chamber, wherein:
a number of pinholes and a diameter of pinholes provide a total cross-sectional area, and the total cross-sectional area and a thickness of pinholes are selected to oxygen supplied from the ambient atmosphere to the fuel cell membrane electrode assembly to limit an average power generated by the fuel cell membrane electrode assembly;
the number of pinholes, the diameter of pinholes, and the thickness of pinholes restrict water vapor recovered from ambient atmosphere such that oxygen is the primary regulator of electricity generated by the fuel cell membrane electrode assembly; and
a first gas diffusion layer supported between the fuel cell membrane electrode assembly and the top plate, the first gas diffusion layer abutting the top plate to minimize the direct oxygen diffusion path between the first gas diffusion layer and ambient atmosphere.

12. The device of claim 11 wherein each pinhole within the array of pinholes includes a pinhole diameter of 3 mils to limit oxygen supplied to a cathode of the fuel cell membrane electrode assembly.

13. The device of claim 11 wherein a number of the pinholes is selected to provide a total pinhole cross-sectional area corresponding to an average power of a selected load.

14. The device of claim 13 wherein:
each of the pinholes is connected through a corresponding ambient opening of larger diameter to provide the direct oxygen diffusion path between ambient atmosphere and the first gas diffusion layer to obtain exposure to oxygen and water vapor; and
each opening within the array of ambient openings includes an outer hole diameter that is larger than each pinhole diameter within the array of pinholes that prevents fouling of the direct oxygen diffusion path through each opening and each pinhole.

15. The device of claim 11 wherein the pinholes are configured to regulate oxygen provided to a cathode of the fuel cell membrane electrode assembly to control electricity generated without regulation of water vapor.

16. The device of claim 11 wherein the chamber comprises a chemical hydride fuel separated from the membrane electrode assembly by a particulate filter.

17. The device of claim 11 wherein the membrane electrode assembly comprises a cathode layer adjacent the pinholes that provide a limited supply of oxygen to the cathode layer through the first gas diffusion layer.

18. A method comprising:
exposing a cathode of a fuel cell membrane electrode assembly to a limited supply of oxygen via one or more pinholes in a power generator container, wherein:
a number of pinholes and a diameter of pinholes provide a total cross-sectional area, and the total cross-sectional area and a thickness of pinholes are selected to limit oxygen supplied from the ambient atmosphere to the cathode to limit an average power generated by the fuel cell membrane electrode assembly;
the number of pinholes, the diameter of pinholes, and the thickness of pinholes restrict water vapor recovered from ambient atmosphere such that oxygen is the primary regulator of electricity generated by the fuel cell membrane electrode assembly;
providing hydrogen to an anode of the fuel cell membrane electrode assembly from a chamber containing a chemical hydride;
reacting the oxygen and hydrogen to produce electricity and water vapor; and
providing the produced water vapor to the chemical hydride to cause the chemical hydride to generate more hydrogen.

19. The method of claim 18 wherein a number of the one or more pinholes is selected to provide a total pinhole cross-sectional area to provide an amount of oxygen to cause the fuel cell membrane electrode assembly to provide a selected average energy for consumption by a load.

Assignees

• Intelligent Energy Ltd

Inventors

• Eickhoff Steven J
• Klein Jeffrey Michael
• Wiebesick Jason

Classifications

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title

• H01M8/1007

  with both reactants being gaseous or vaporised (H01M8/12 takes precedence) · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• H01M8/04089

  of gaseous reactants · CPC title

• H01M8/04104

  Regulation of differential pressures · CPC title