System and method for monitoring a reactor system using optical fiber based sensors

Patent metadata

Field	Value
Publication number	US-11380918-B2
Application number	US-201515501443-A
Country	US
Kind code	B2
Filing date	Aug 20, 2015
Priority date	Aug 20, 2014
Publication date	Jul 5, 2022
Grant date	Jul 5, 2022

Abstract

A method of monitoring operation of a reactor system includes causing a chemical reaction to occur within an assembly of the reactor system, and measuring a chemical composition of one or more reactants of the chemical reaction with spatial resolution at a plurality of points along a path within the assembly using a sensor system structured to implement distributed sensing. The sensor system includes an optical fiber sensing member provided at least partially within the assembly, wherein the optical fiber sensing member comprises a functionalized optical fiber based sensor device structured to exhibit a change in one or more optical properties in response to changes in the chemical composition of the one or more reactants.

First claim

What is claimed is:

1. A solid oxide fuel cell system, comprising:
a solid oxide fuel cell stack including a number of solid oxide fuel cells, wherein each of the solid oxide fuel cells is structured to operate at a high temperature ranging from 500° C. to 1000° C.; and
a sensor system structured to measure at least one of (i) a chemical composition of one or more reactants in a gas stream flowing through the solid oxide fuel stack, or (ii) a temperature of the gas stream flowing through the solid oxide fuel stack, the sensor system including an optical fiber sensing member including a monolithic in-fiber sensing element positioned inside one or more of the solid oxide fuel cells, wherein the monolithic in-fiber sensing element is structured to exhibit a change in one or more optical properties in response to changes in at least one of (a) the chemical composition of the one or more reactants and (b) the temperature of the gas stream, and wherein the monolithic in-fiber sensing element is structured to provide stable sensing at high temperatures ranging from 500° C. to 1000° C.;
wherein the sensor system is structured to implement distributed sensing along the gas stream at a plurality of sensing locations along the monolithic in-fiber sensing element using a scattering based interrogation approach and without employing a plurality of in-fiber optic components in a core of the optical fiber sensing member such that the sensor system is configured to measure at least one of (i) the chemical composition of the one or more reactants with spatial resolution at the plurality of sensing locations, and (ii) the temperature of the gas stream with spatial resolution at the plurality of sensing locations.

2. The solid oxide fuel cell system according to claim 1 , wherein the sensor system is structured to measure the chemical composition of the one or more reactants in the gas stream.

3. The solid oxide fuel according to claim 1 , wherein the sensor system is structured to measure the temperature of the gas stream.

4. The solid oxide fuel cell system according to claim 1 , wherein the sensor system is structured to measure the chemical composition of the one or more reactants in the gas stream and the temperature of the gas stream.

5. The solid oxide fuel cell system according to claim 1 , wherein the scattering based interrogation approach is a back scattering based interrogation approach.

6. The solid oxide fuel cell system according to claim 1 , wherein the gas stream is an anode stream within the solid oxide fuel cell stack or a cathode stream within the solid oxide fuel cell stack.

7. The solid oxide fuel cell system according to claim 1 , wherein the optical fiber sensing member includes an optical fiber member provided within a packaging assembly.

8. The solid oxide fuel cell system according to claim 7 , wherein the packaging assembly comprises a tubing member.

9. The solid oxide fuel cell system according to claim 8 , wherein the tubing member comprises a first tubing member provided within a second tubing member.

10. The solid oxide fuel cell system according to claim 9 , wherein the first tubing member is an alumina tubing member and the second tubing member is a nickel tubing member.

11. The solid oxide fuel cell system according to claim 8 , wherein the tubing member includes a plurality of openings along a length thereof to enable gas to pass through the tubing member.

12. The solid oxide fuel cell system according to claim 7 , wherein one of the solid oxide fuel cells includes an electrically conductive interconnect member having a plurality of passageways for permitting gas flow, wherein one of the passageways includes a groove provided in a surface of the conductive interconnect member, wherein a portion of the packaging assembly is received within the groove.

13. The solid oxide fuel cell system according to claim 7 , wherein one of the solid oxide fuel cells includes an electrically conductive interconnect member, wherein at least a portion of the packaging assembly is embedded within the electrically conductive interconnect member.

14. The solid oxide fuel cell system according to claim 1 , further comprising one or more shim plates provided between a first conductive interconnect and a ceramic member of one of the solid oxide fuel cells, and wherein the optical fiber sensing member is provided between the first conductive interconnect and the ceramic member.

15. A method of monitoring operation of a solid oxide fuel cell system comprising:
providing a gas stream to a solid oxide fuel cell stack of the solid oxide fuel system, the solid oxide fuel cell stack including a number of solid oxide fuel cells, wherein each of the solid oxide fuel cells is structured to operate at a high temperature ranging from 500° C. to 1000° C., the solid oxide fuel stack having an optical fiber sensing member at least partially provided therein, wherein optical fiber sensing member includes a monolithic in-fiber sensing element positioned inside one or more of the solid oxide fuel cells, wherein the monolithic in-fiber sensing element is structured to provide stable sensing at high temperatures ranging from 500° C. to 1000° C.; and
measuring at high temperatures ranging from 500° C. to 1000° C. and at a plurality of sensing locations along the monolithic in-fiber sensing element using a scattering based interrogation approach and without employing a plurality of in-fiber optic components in a core of the optical fiber sensing member at least one of: (i) a chemical composition of one or more reactants in the gas stream with spatial resolution at the plurality of sensing locations, and (ii) a temperature of the gas stream or a solid oxide fuel cell of the solid oxide fuel cell system with spatial resolution at the plurality of sensing locations, wherein the monolithic in-fiber sensing element is structured to exhibit a change in one or more optical properties in response to changes in at least one of (a) the chemical composition of the one or more reactants, and (b) the temperature of the gas stream.

16. The method according to claim 15 , wherein the sensor system is structured to measure the chemical composition of the one or more reactants in the gas stream.

17. The method according to claim 15 , wherein the sensor system is structured to measure the temperature of the gas stream.

18. The method according to claim 15 , wherein the sensor system is structured to measure the chemical composition of the one or more reactants in the gas stream and the temperature of the gas stream.

Assignees

• Univ Of Pittsburgh—Of The Commonwealth System Of Higher Education
• Us Energy

Inventors

• Chen Peng K
• Poole Jacob Lorenzi
• Ohodnicki Paul R
• Brown Thomas D
• Gerdes Kirk R
• Buric Michael P

Classifications

• Y02E60/50

  Fuel cells · CPC title

• H01M8/02

  Details (electrodes H01M4/86 - H01M4/98) · CPC title

• H01M8/04447 Primary

  of anode reactants at the inlet or inside the fuel cell · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/04335

  of cathode reactants at the inlet or inside the fuel cell · CPC title