Multiphase metal foils as integrated metal anodes for non-aqueous batteries

Patent metadata

Field	Value
Publication number	US-11380886-B2
Application number	US-201816607942-A
Country	US
Kind code	B2
Filing date	Apr 30, 2018
Priority date	Apr 28, 2017
Publication date	Jul 5, 2022
Grant date	Jul 5, 2022

Abstract

Disclosed herein are multiphase metal anodes useful in non-aqueous batteries. The anodes include at least one active metal and at least one conductive metal.

First claim

What is claimed is:

1. An anode comprising:
an anode active material, wherein the anode active material is an integrated multiphase metallic foil, wherein the integrated multiphase metallic foil is a rolled foil and wherein the integrated multiphase metallic foil comprises:
a first metal phase comprising an active metal that alloys with an alkali metal or an alkaline earth metal at a first alloying potential; and
a second metal phase comprising a conductive metal that alloys with the alkali metal or the alkaline earth metal at a second alloying potential, wherein the first alloying potential is greater than the second alloying potential.

2. The anode of claim 1 , wherein the alkali metal is lithium or sodium and wherein the alkaline earth metal is magnesium or calcium.

3. The anode of claim 1 wherein the active metal is aluminum, silicon, zinc, gallium, silver, cadmium, indium, tin, antimony, gold, lead, bismuth, or magnesium.

4. The anode of claim 1 , wherein the conductive metal is nickel, aluminum, zinc, silicon, lead, germanium, bismuth, silver, cadmium, antimony, copper, or gold.

5. The anode of claim 1 , wherein the active metal is tin, wherein the alkali metal is lithium, and wherein the conductive metal is aluminum.

6. The anode of claim 1 , wherein the integrated multiphase metal foil is characterized by a weight ratio of the active metal to the conductive metal of from 1:10 to 10:1.

7. The anode of claim 1 , wherein the first metal phase or the second metal phase further comprises at least one additional element, different from the active metal and the conductive metal, selected from the group consisting of boron, carbon, aluminum, silicon, phosphorous, gallium, germanium, arsenic, indium, antimony, lead, tin, bismuth, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, yttrium, zirconium, niobium, molybdenum, technetium, ruthenium, rhodium, palladium, silver, cadmium, tungsten, osmium, iridium, platinum, gold, and combinations thereof.

8. The anode of claim 7 , wherein the at least one additional element is present in the integrated multiphase metal foil in an amount from 0.1-10% by weight.

9. The anode of claim 1 , wherein the integrated multiphase metallic foil comprises a eutectic alloy or hypoeutectic alloy of the active metal and the conductive metal.

10. The anode of claim 1 , wherein the integrated multiphase metallic foil comprises a cladded foil of the active metal and the conductive metal.

11. The anode of claim 1 , wherein the integrated multiphase metallic foil is an anisotropically cold-rolled foil.

12. The anode of claim 1 , wherein the integrated multiphase metallic foil has a thickness no greater than 0.05 mm.

13. The anode of claim 1 , wherein the integrated multiphase metallic foil has an average phase cross section in at least one spatial dimension of 20 microns or less, 10 microns or less, 8 microns or less, 6 microns or less, 5 microns or less, 4 microns or less, 3 microns or less, 2 microns or less, or 1 micron or less.

14. The anode of claim 1 , wherein the first metal phase further comprises lithium alloyed with the active metal.

15. The anode of claim 1 , wherein the first metal phase further comprises sodium alloyed with the active metal.

16. A lithiated anode, prepared by a process comprising applying a voltage to a multiphase metallic electrode in contact with a lithium-containing electrolyte,
wherein the multiphase metallic electrode comprises the anode of claim 1 ,
wherein, at the voltage, the active metal is preferentially alloyed with lithium.

17. An electrochemical cell comprising:
the anode of claim 1 ;
a cathode; and
an electrolyte.

18. The anode of claim 1 ,
wherein the anode does not include a separate current collector; or
wherein the anode further comprises an anode current collector in electrical contact with the anode active material.

19. A method of making an anode, comprising:
forming a mixed metal precursor comprising an active metal and a conductive metal, and
rolling the mixed metal precursor to a thickness no greater than 0.05 mm to generate an integrated multiphase metallic foil, wherein the integrated multiphase metallic foil is a rolled foil and wherein the integrated multiphase metallic foil comprises:
a first metal phase comprising an active metal that alloys with an alkali metal or an alkaline earth metal at a first alloying potential; and
a second metal phase comprising a conductive metal that alloys with the alkali earth metal or the alkaline earth metal at a second alloying potential, wherein the first alloying potential is greater than the second alloying potential.

20. The method claim 19 , wherein the mixed metal precursor is formed by combining the active metal and the conductive metal in a melted state, followed by cooling to give the mixed metal precursor.

Assignees

• Univ Texas

Inventors

• Manthiram Arumugam
• Kreder Iii Karl Joseph
• Heligman Brian Theodore

Classifications

• H01M4/045 Primary

  Electrochemical coating; Electrochemical impregnation · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/043

  involving compressing or compaction · CPC title

• H01M4/366

  as layered products · CPC title

• H01M4/134 Primary

  Electrodes based on metals, Si or alloys · CPC title