Method related to heat transfer for exothermic reactions

Patent metadata

Field	Value
Publication number	US-11377598-B2
Application number	US-201917051460-A
Country	US
Kind code	B2
Filing date	Apr 25, 2019
Priority date	May 11, 2018
Publication date	Jul 5, 2022
Grant date	Jul 5, 2022

Abstract

Disclosed herein is a method of producing a product comprising C2-C5 hydrocarbons and C6-C18 hydrocarbons comprising the steps of: a) converting synthesis gas to the product comprising C2-C5 hydrocarbons and C6-C18 hydrocarbons in a first reactor; b) removing the product comprising C2-C5 hydrocarbons and C6-C18 hydrocarbons from the first reactor; c) reintroducing the C6-C18 hydrocarbons into the first reactor and/or introducing the C6-C18 hydrocarbons into a cooling jacket of the first reactor; and d) performing an exothermic reaction in the first reactor, thereby transferring heat from the exothermic reaction to the C6-C18 hydrocarbons, thereby storing heat in the C6-C18 hydrocarbons.

First claim

What is claimed is:

1. A method of producing a product comprising C2-C5 hydrocarbons and C6-C18 hydrocarbons comprising the steps of:
a) converting synthesis gas to the product comprising C2-C5 hydrocarbons and C6-C18 hydrocarbons in a first reactor;
b) removing the product comprising C2-C5 hydrocarbons and C6-C18 hydrocarbons from the first reactor;
c) reintroducing the C6-C18 hydrocarbons into the first reactor and/or introducing the C6-C18 hydrocarbons into a cooling jacket of the first reactor; and
d) performing an exothermic reaction in the first reactor, thereby transferring heat from the exothermic reaction to the C6-C18 hydrocarbons, thereby storing heat in the C6-C18 hydrocarbons;
wherein the transferring of heat from the exothermic reaction to the C6-C18 hydrocarbons causes a phase change of the C6-C18 hydrocarbons;
and wherein the syngas is contacted with a catalyst at a temperature of from and a pressure of 75 bar to less than 200 bar.

2. The method of claim 1 , wherein the syngas is contacted with a catalyst at a temperature of from 180° C. to 320° C. and a pressure of from 5 bar to 100.

3. The method of claim 1 , wherein the syngas is contacted with a catalyst at a temperature of 180° C. and a pressure of 100 bar to less than 200 bar.

4. The method of claim 1 , wherein the C6-C18 hydrocarbons are introduced into the cooling jacket of the first reactor.

5. The method of claim 1 , wherein the C6-C18 hydrocarbons are reintroduced into the first reactor with the reactants of the exothermic reaction.

6. The method of claim 1 , wherein the C6-C18 hydrocarbons are mixed with the reactants of the exothermic reaction; and
wherein the catalyst comprises Co and Mn, and each of promoter elements La, P, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Ti and Zr.

7. The method of claim 1 , wherein the catalyst comprises Co and Mn, and at least one promoter element selected form the group consisting of La, P, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Ti and Zr.

8. The method of claim 7 , wherein the promoter element is La.

9. The method of claim 7 , wherein the promoter element is P.

10. The method of claim 7 , wherein the promoter element is Cs.

11. The method of claim 7 , wherein the promoter element is Na.

12. The method of claim 7 , wherein the promoter element is K.

13. The method of claim 7 , wherein the promoter element is Rb.

14. The method of claim 7 , wherein the promoter element is Cs.

15. The method of claim 7 , wherein the promoter element is Mg.

16. The method of claim 7 , wherein the promoter element is Ca.

17. The method of claim 7 , wherein the promoter element is Sr.

18. The method of claim 7 , wherein the promoter element is Ba.

19. The method of claim 7 , wherein the promoter element is Zr.

20. A method of producing a product comprising C2-C5 hydrocarbons and C6-C18 hydrocarbons, the method consisting of the steps of:
a) converting synthesis gas to the product comprising C2-C5 hydrocarbons and C6-C18 hydrocarbons in a first reactor;
b) removing the product comprising C2-C5 hydrocarbons and C6-C18 hydrocarbons from the first reactor;
c) reintroducing the C6-C18 hydrocarbons into the first reactor and/or introducing the C6-C18 hydrocarbons into a cooling jacket of the first reactor; and
d) performing an exothermic reaction in the first reactor, thereby transferring heat from the exothermic reaction to the C6-C18 hydrocarbons, thereby storing heat in the C6-C18 hydrocarbons, wherein step a) comprises contacting synthesis gas with a catalyst comprising Mn;

wherein the transferring of heat from the exothermic reaction to the C6-C18 hydrocarbons causes a phase change of the C6-C18 hydrocarbons;
wherein the C6-C18 hydrocarbons are reintroduced into the first reactor;
wherein the C6-C18 hydrocarbons are introduced into the cooling jacket of the first reactor;
wherein the C6-C18 hydrocarbons are reintroduced into the first reactor with the reactants of the exothermic reaction.
wherein the C6-C18 hydrocarbons are mixed with the reactants of the exothermic reaction;
wherein the method further comprises after step d) performing an endothermic reaction in the first reactor, thereby transferring heat from the C6-C18 hydrocarbons with the stored heat to the endothermic reaction;
wherein the transferring of heat from the C6-C18 hydrocarbons with the stored heat to the endothermic reaction causes a phase change of the C6-C18 hydrocarbons;
wherein the method further comprises after step d) transferring the C6-C18 hydrocarbons with the stored heat from the first reactor to a second reactor and performing an endothermic reaction in the second reactor, thereby transferring heat from the C6-C18 hydrocarbons with the stored heat to the endothermic reaction;
wherein the method further comprises after the endothermic reaction, transferring the C6-C18 hydrocarbons from the second reactor back to the first reactor and performing an exothermic reaction in the first reactor, thereby transferring heat from the exothermic reaction to the C6-C18 hydrocarbons, thereby storing heat in the C6-C18 hydrocarbons;
wherein the C2-C5 hydrocarbons comprises C2-C5 olefins;
wherein the method further comprises separating the C2-C5 olefins from the C6-C18 hydrocarbons prior to step c);
wherein the exothermic reaction in step d) converts synthesis gas to C2-C5 hydrocarbons;
wherein step a) converts synthesis gas to C6-C18 hydrocarbons as by-products;
wherein the exothermic reaction in step d) selectively converts synthesis gas to C2-C5 olefins;
wherein step a) selectively converts synthesis gas to C2-C5 olefins;
wherein the method does not include the use of a salt-based product or a molten metal produce as a phase change material;
wherein the method is performed on an industrial and pilot scale;
wherein the syngas is contacted with a catalyst at a temperature of 180° C. and a pressure of syngas is contacted with a catalyst at a pressure of 100 bar to less than 200 bar;
wherein the catalyst comprises Co and Mn, and each of promoter elements La, P, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Ti and Zr; and
wherein the C6-C18 hydrocarbons comprise C6-C12 hydrocarbons.

Assignees

• Sabic Global Technologies Bv

Inventors

• Nawaz Zeeshan
• Karim Khalid
• Barochia Jayen

Classifications

• C10G2/332 Primary

  of the iron-group · CPC title

• C10G2300/4081

  Recycling aspects · CPC title

• C10G2/32 Primary

  with the use of catalysts · CPC title

• C07C1/042

  Temperature controlling devices; Heat exchangers · CPC title