Xylene production processes and systems

Patent metadata

Field	Value
Publication number	US-11377399-B2
Application number	US-201816759866-A
Country	US
Kind code	B2
Filing date	Nov 15, 2018
Priority date	Dec 5, 2017
Publication date	Jul 5, 2022
Grant date	Jul 5, 2022

Abstract

A process and related system for producing para-xylene (PX). In an embodiment, the process includes (a) separating a feed stream comprising C6+ aromatic hydrocarbons into a toluene containing stream and a C8+ hydrocarbon containing stream and (b) contacting at least part of the toluene containing stream with a methylating agent in a methylation unit to convert toluene to xylenes and produce a methylated effluent stream. In addition, the process includes (c) recovering PX from the methylated effluent stream in (b) to produce a PX depleted stream and (d) transalkylating the PX depleted stream to produce a transalkylation effluent stream. The transalkylation effluent stream includes a higher concentration of toluene than the PX depleted stream. Further, the process includes (e) converting at least some ethylbenzene (EB) within the C8+ hydrocarbon containing stream into toluene and (f) flowing the toluene converted in (e) to the contacting in (b).

First claim

The invention claimed is:

1. A process for producing para-xylene (PX), the process comprising:
(a) separating a feed stream comprising C 6+ aromatic hydrocarbons into at least a toluene containing stream and a C 8+ hydrocarbon containing stream;
(b) contacting at least part of the toluene containing stream with a methylating agent in a methylation unit under conditions effective to convert toluene to xylenes and produce a methylated effluent stream;
(c) recovering PX from the methylated effluent stream in (b) to produce a PX depleted stream;
(d) transalkylating the PX depleted stream to produce a transalkylation effluent stream, wherein the transalkylation effluent stream includes a higher concentration of toluene than the PX depleted stream;
(e) converting at least 50 wt % of the ethylbenzene (EB) within the C 8+ hydrocarbon containing stream into toluene; and
(f) flowing the toluene converted in (e) to the contacting in (b).

2. The process of claim 1 , further comprising:
(g) separating from the transalkylation effluent stream a C 7 containing stream and a C 8+ hydrocarbon containing bottoms stream; and
(h) recycling the C 7 containing stream to at least one of the contacting in (b) or the transalkylation in (d).

3. The process of claim 2 , further comprising recycling the C 8+ hydrocarbon containing bottoms stream from (g) to the separating in (a).

4. The process of claim 2 , further comprising:
(i) separating a C 8 hydrocarbon containing stream and a C 9+ aromatic hydrocarbon-containing stream from the C 8+ hydrocarbon containing stream in (a);
(j) recycling the C 8+ hydrocarbon containing bottoms stream from (g) to the separating in (i).

5. The process of claim 4 , further comprising flowing the C 8 hydrocarbon containing stream from (i) to at least one of the recovering in (c) or the transalkylating in (d).

6. The process of claim 4 , further comprising:
(k) separating a C 9 and C 10 aromatic hydrocarbon containing stream from the C 9+ aromatic hydrocarbon containing stream from (i);
(l) flowing the C 9 and C 10 aromatic hydrocarbon containing stream from (k) to the transalkylating in (d).

7. The process of claim 6 , further comprising:
(m) separating a C 9+ hydrocarbon containing bottoms stream from the methylated effluent stream after (b) and before (c);
(n) flowing the C 9+ hydrocarbon-containing bottoms stream from (m) to the separating in (k).

8. The process of claim 1 , wherein the PX depleted stream comprises ortho-xylene (OX) and meta-xylene (MX) and wherein the PX depleted stream is not flowed through an isomerization reactor.

9. The process of claim 1 , further comprising providing a naphtha feedstock to a catalytic reformer to produce the feed stream before the separating in (a).

10. The process of claim 1 , wherein the separating in (a) further comprises separating a C 6− hydrocarbon containing stream from the feed stream.

11. The process of claim 10 , further comprising:
(o) flowing the toluene containing stream from (a) to the contacting in (c) directly after the separating in (a).

12. The process of claim 11 , further comprising:
(p) extracting non-aromatics from the C 6− hydrocarbon containing stream to produce a toluene containing aromatic stream;
(q) separating a benzene stream and a toluene stream from the toluene containing aromatic stream; and
(r) supplying the toluene stream to the contacting in (b).

13. The process of claim 12 , further comprising flowing the benzene stream from (q) to the transalkylating in (d).

14. A system for producing para-xylene (PX), the system comprising:
a catalytic reformer configured to produce a reformate stream comprising C 6+ aromatic hydrocarbons from a naphtha feedstock;
a first separation system downstream of the catalytic reformer, wherein the first separation system is configured to separate the reformate stream into at least a toluene containing stream and a C 8+ hydrocarbon containing stream;
a de-methylation unit configured to receive the C 8+ hydrocarbon containing stream and convert at least 50 wt % of the ethylbenzene (EB) within the C 8+ hydrocarbon containing stream into toluene;
a toluene methylation unit downstream of the first separation system and the de-methylation unit, wherein the toluene methylation unit is configured to receive the toluene containing stream and toluene converted from EB in the de-methylation unit, and to react toluene with a methylating agent to produce xylenes that are emitted from the toluene methylation unit as a methylated effluent stream;
a second separation system downstream of the toluene methylation unit, wherein the second separation system is configured to recover PX from the methylated effluent stream and produce a PX depleted stream; and
a transalkylation unit downstream of the second separation system, wherein the transalkylation unit is configured to transalkylate the PX depleted stream and produce a transalkylation effluent stream that has a higher concentration of toluene than the PX depleted stream.

15. The system of claim 14 , further comprising a third separation system downstream of the transalkylation unit, wherein the third separation system is configured to separate the transalkylation effluent stream into a C 7 hydrocarbon containing stream and a C 8+ hydrocarbon containing bottoms stream;
wherein the C 7 hydrocarbon containing stream is in direct fluid communication with an upstream side of at least one of the toluene methylation unit or an upstream side of the transalkylation unit.

16. The system of claim 15 , further comprising a fourth separation system configured to receive the C 8+ hydrocarbon containing stream from the first separation system, wherein the fourth separation system is configured to separate a C 8 hydrocarbon containing stream and a C 9+ aromatic hydrocarbon containing stream from the C 8+ hydrocarbon-containing stream.

17. The system of claim 16 , wherein the C 8 hydrocarbon containing stream is in direct fluid communication with the second separation system.

18. The system of claim 17 , wherein the C 8+ hydrocarbon containing bottoms stream from the third separation system is in direct fluid communication with an upstream side of at least one of the first separation system or an upstream side of the fourth separation system.

19. The system of claim 14 , further comprising an extraction section in direct fluid communication with the toluene containing stream, wherein the extraction section is configured to remove non-aromatics from the toluene containing stream and produce a toluene containing aromatic stream.

20. The system of claim 19 , further comprising a fifth separation system downstream of the extraction section, wherein the fifth separation system is configured to separate a toluene stream and a benzene stream from the toluene containing aromatic stream;
wherein the toluene stream is in direct fluid communication with the upstream side of the toluene methylation unit; and
wherein the benzene stream is in direct fluid communication with the upstream side of the transalkylation unit.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Molinier Michel
• Nair Hari
• Weigel Scott J
• Salciccioli Michael
• Levin Doron

Classifications

• C07C4/08

  by splitting-off an aliphatic or cycloaliphatic part from the molecule · CPC title

• C10G2300/104

  Light gasoline having a boiling range of about 20 - 100 °C · CPC title

• C07C7/13

  by molecular-sieve technique · CPC title

• C07C7/005

  Processes comprising at least two steps in series · CPC title

• C07C4/18

  Catalytic processes · CPC title