Catalyst for converting alkylaromatic hydrocarbon and preparation method thereof

Patent metadata

Field	Value
Publication number	US-11376574-B2
Application number	US-202017117358-A
Country	US
Kind code	B2
Filing date	Dec 10, 2020
Priority date	Dec 17, 2019
Publication date	Jul 5, 2022
Grant date	Jul 5, 2022

Abstract

Disclosed are a bifunctional catalyst and a preparation method therefor, the bifunctional catalyst being suitable to produce high-value aromatic hydrocarbons by subjecting alkylaromatic hydrocarbons to a disproportionation/transalkylation/dealkylation reaction while suppressing aromatic loss or subjecting C8 aromatic hydrocarbons to an isomerization reaction while suppressing xylene loss.

First claim

What is claimed is:

1. A method for producing C8 aromatics, the method comprising:
providing a feedstock containing benzene, toluene, and/or C9+ aromatics; and
forming a reaction product containing an increased amount of C8 aromatic hydrocarbons from the feedstock by at least one of disproportionation, transalkylation, and dealkylation reactions in the presence of a catalyst,
wherein the catalyst comprises:
(A) a mixed support comprising: (i) a first zeolite, which has a silica-alumina ratio (SAR) of 5 to 300 and a 10-membered ring pore structure, and/or a second zeolite, which has a silica-alumina ratio (SAR) of 5 to 300 and a 12-membered ring pore structure with a pore diameter of 6 to 9 Å; and (ii) a refractory inorganic oxide binder; and
(B) a first metal supported only on the refractory inorganic oxide binder in the mixed support and having hydrogenation activity,
wherein the first metal is at least one selected from the group consisting of platinum (Pt), tungsten (W), rhenium (Re), ruthenium (Ru), iridium (Jr), nickel (Ni), palladium (Pd), and molybdenum (Mo), wherein the amount of the first metal supported is in a range of 0.01 to 5 wt % on the basis of the weight of the mixed support, and
wherein the aromatic loss in the reaction product is 1 mol % or less.

2. The method of claim 1 , wherein the refractory inorganic oxide is at least one selected from the group consisting of alumina, silica, aluminum phosphate, titania, zirconia, bentonite, kaolin, clinoptilolite, and montmorillonite.

3. The method of claim 1 , wherein the first zeolite is at least one selected from the group consisting of ZSM-5, ZSM-11, ZSM-23, ZSM-48, ZSM-57, EU-2, TNU-9, and MCM-22, and the second zeolite is at least one selected from the group consisting of mordenite (MOR), beta-zeolite, ZSM-12, ZSM-10, and ZSM-18.

4. The method of claim 1 , wherein the first metal is at least one selected from the group consisting of platinum (Pt), rhenium (Re), and molybdenum (Mo).

5. The method of claim 1 , wherein the catalyst further comprises at least one second metal selected from the group consisting of tin (Sn) and lead (Pb), which is supported only on the refractory inorganic oxide binder of the mixed support, the amount of the second metal being in a range of 0.01 to 5 wt % on the basis of the weight of the mixed support.

6. The method of claim 5 , wherein the atomic ratio of the first metal:the second metal is in a range of 1:0.5 to 50.

7. The method of claim 1 , wherein the first metal is in a reduced form, a partially oxidized form, or a sulfide form.

8. The method of claim 1 , wherein the mixed support comprises, on the basis of the weight of the mixed support, 5 to 95 wt % of the first zeolite and 95 to 5 wt % of the refractory inorganic oxide binder.

9. The method of claim 1 , wherein the mixed support comprises, on the basis of the weight of the mixed support, 5 to 95 wt % of the second zeolite and 95 to 5 wt % of the refractory inorganic oxide binder.

10. The method of claim 1 , wherein the mixed support comprises, on the basis of the weight of the mixed support, 5 to 70 wt % of the first zeolite, 10 to 90 wt % of the second zeolite, and 1 to 70 wt % of the refractory inorganic oxide binder.

11. The method of claim 1 , wherein,
when the first metal is platinum, it is in a reduced form or a sulfide form,
when the first metal is rhenium, it is in a reduced form or a sulfide form, and
when the first metal is molybdenum, it is in a partially oxidized form or a sulfide form.

Assignees

• Sk Innovation Co Ltd

Inventors

• Lee Sang Il
• Lee Ji Hoon
• Cheon Young Eun

Classifications

• B01J29/18

  of the mordenite type · CPC title

• C07C2/66

  Catalytic processes · CPC title

• C07C5/274

  with inorganic acids; with salts or anhydrides of acids · CPC title

• B01J29/26

  containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium · CPC title

• B01J37/0009

  Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst · CPC title