Dielectric separator for fuel cell stack assembly and manufacturing method thereof

Patent metadata

Field	Value
Publication number	US-11374232-B2
Application number	US-202117244098-A
Country	US
Kind code	B2
Filing date	Apr 29, 2021
Priority date	May 5, 2020
Publication date	Jun 28, 2022
Grant date	Jun 28, 2022

Abstract

A fuel cell column includes first and second fuel cell stacks, a fuel manifold disposed between the first and second fuel cell stacks and configured to provide fuel to the first and second fuel cell stacks, and first and second dielectric separators located between the fuel manifold and the respective first and second fuel cell stacks, and configured to electrically isolate the respective first and second fuel cell stacks from the fuel manifold. The first and second dielectric separators each include a top layer of a ceramic material, a bottom layer of the ceramic material, a middle layer disposed between the top and bottom layers and including a material having a lower density and a higher dielectric strength than the ceramic material, and glass or glass ceramic seals which connect the middle layer to the top and bottom layers.

First claim

What is claimed is:

1. A fuel cell column comprising:
first and second fuel cell stacks;
a fuel manifold disposed between the first and second fuel cell stacks and configured to provide fuel to the first and second fuel cell stacks; and
first and second dielectric separators located between the fuel manifold and the respective first and second fuel cell stacks, and configured to electrically isolate the respective first and second fuel cell stacks from the fuel manifold, the first and second dielectric separators each comprising:
a top layer comprising a ceramic material;
a bottom layer comprising the ceramic material;
a middle layer disposed between the top and bottom layers and comprising a material having a lower density and a higher dielectric strength than the ceramic material; and
glass or glass ceramic seals which connect the middle layer to the top and bottom layers.

2. The fuel cell column of claim 1 , further comprising fuel holes formed in opposing sides of each of the first and the second dielectric separators and comprising concentric through holes formed in the top, middle, and bottom layers of each of the first and the second dielectric separators, wherein the seals comprise ring seals disposed on top and bottom surfaces of the middle layer and surrounding the fuel holes in each of the first and the second dielectric separators.

3. The fuel cell column of claim 2 , further comprising edge seals extending along opposing edges of the top and bottom surfaces of the middle layer and comprising a glass material.

4. The fuel cell column of claim 1 , wherein the middle layer comprises a ceramic fabric.

5. The fuel cell column of claim 1 , wherein the middle layer comprises a ceramic matrix composite.

6. The fuel cell column of claim 1 , wherein:
a surface area to volume ratio of the middle layer is greater than a surface area to volume ratio of the top and bottom layers; and
the ceramic material comprises alumina, zirconia, or yttria stabilized zirconia (YSZ).

7. The fuel cell column of claim 1 , wherein a major constituent of the top, middle, and bottom layers is the same.

8. The fuel cell column of claim 7 , wherein the major constituent is alumina or zirconia.

9. The fuel cell column of claim 2 , wherein each of the first and the second dielectric separator further comprises:
a first additional layer of the ceramic fabric or ceramic matrix composite material disposed on top of the top layer;
a second additional layer of the ceramic material disposed on top of the first additional layer; and
additional ring seals disposed on top and bottom surfaces of the first additional layer, surrounding through holes of the first additional layer, and comprising a glass or glass ceramic material.

10. The fuel cell column of claim 1 , further comprising an electrically conductive jumper bypassing the fuel manifold and the first and the second dielectric separators, the electrically conductive jumper configured to conduct electricity between the first and second fuel cell stacks.

11. The fuel cell column of claim 2 , wherein the fuel holes are fluidly connected to fuel holes of the fuel manifold and fuel holes of the first and second fuel cell stacks.

12. The fuel cell column of claim 1 , further comprising electrically conductive fuel rails connecting the fuel manifold to an adjacent fuel manifold in the fuel cell column.

13. The fuel cell column of claim 12 , wherein the electrically conductive fuel rails comprise metal or metal alloy bellows tubes connected to straight metal or metal alloy tubes.

14. A fuel cell column comprising:
first and second fuel cell stacks;
a fuel manifold disposed between the first and second fuel cell stacks and configured to provide fuel to the first and second fuel cell stacks; and
first and second dielectric separators located between the fuel manifold and the respective first and second fuel cell stacks, and configured to electrically isolate the respective first and second fuel cell stacks from the fuel manifold, the first and second dielectric separators each comprising:
a peripheral frame;
internal supports disposed inside of the frame and configured to support the peripheral frame; and
fuel holes and internal openings at least partially defined by the peripheral frame and internal supports.

15. The fuel cell column of claim 14 , wherein the separators each comprise relief cuts formed in at least one of the frame or the internal supports.

16. A fuel cell column comprising:
first and second fuel cell stacks;
a fuel manifold disposed between the first and second fuel cell stacks and configured to provide fuel to the first and second fuel cell stacks; and
first and second dielectric separators located between the fuel manifold and the respective first and second fuel cell stacks, and configured to electrically isolate the respective first and second fuel cell stacks from the fuel manifold, the first and second dielectric separators each comprising:
a top layer comprising a ceramic material;
a bottom layer comprising the ceramic material;
at least one protrusion which offsets the top layer from the bottom layer such that an air gap is located between the top layer and the bottom layer; and
glass or glass ceramic seals which connect the top layer to the bottom layer.

17. A method of forming a dielectric separator, the method comprising:
forming an assembly comprising a middle layer comprising a dielectric material, a top layer comprising a green ceramic material, a bottom layer comprising the green ceramic material, and a glass or glass ceramic seal material disposed between the middle layer and each of the top and bottom layers;
sintering the assembly to densify the top and bottom layers and reflow the glass or glass ceramic seal material; and
cutting the sintered assembly to form the dielectric separator.

18. The method of claim 17 , further comprising placing the dielectric separator into a fuel cell column between a fuel manifold and a fuel cell stack.

19. The method of claim 17 , wherein a major constituent of the top, middle, and bottom layers is the same.

20. The method of claim 19 , wherein the middle layer comprises a ceramic fabric or a ceramic matrix composite.

Assignees

• Bloom Energy Corp

Inventors

• Patel Siddharth
• Petrucha Michael
• Basharain Adrian
• Fung Victor
• Perry Martin
• El Batawi Emad
• Edmonston David

Classifications

• H01M8/0282

  Inorganic material · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/2432

  Grouping of unit cells of planar configuration · CPC title

• H01M8/249

  comprising two or more groupings of fuel cells, e.g. modular assemblies · CPC title

• H01M8/2485 Primary

  Arrangements for sealing external manifolds; Arrangements for mounting external manifolds around a stack · CPC title