Slurry composition including binder containing reaction product of epoxy functional polymer and acid functional polymer for lithium ion electrical storage devices

Patent metadata

Field	Value
Publication number	US-11374223-B2
Application number	US-201715638448-A
Country	US
Kind code	B2
Filing date	Jun 30, 2017
Priority date	Jun 30, 2017
Publication date	Jun 28, 2022
Grant date	Jun 28, 2022

Abstract

The present invention is directed to a lithium ion battery electrode slurry composition comprising: (a) an electrochemically active material capable of lithium intercalation and deintercalation; (b) a binder dispersed in an aqueous or organic medium and comprising a reaction product of a reaction mixture comprising one or more epoxy functional polymer(s) and one or more acid functional acrylic polymer(s); and (c) an electrically conductive agent. The present invention also provides an electrode comprising: (a) an electrical current collector; and (b) a cured film formed on the electrical current collector. The cured film is deposited from the slurry composition described above. Electrical storage devices prepared from the electrode are also provided.

First claim

The invention claimed is:

1. A lithium ion battery electrode slurry composition comprising:
(a) an electrochemically active lithium compound capable of lithium intercalation and deintercalation;
(b) a binder dispersed in an aqueous medium and comprising a reaction product of a reaction mixture comprising one or more epoxy functional polymer(s) and one or more acid functional acrylic polymer(s), wherein the reaction product comprises at least 70% by weight of one or more epoxy functional polymer(s) and up to 30% by weight of the one or more acid functional acrylic polymer(s), wherein the percentages by weight are based on the total weight of the reaction product; and
(c) an electrically conductive agent,
wherein the lithium ion battery electrode slurry composition is a lithium ion battery positive electrode slurry composition.

2. The electrode slurry composition of claim 1 , further comprising a thickener.

3. The electrode slurry composition of claim 1 , further comprising an organic solvent.

4. The electrode slurry composition of claim 1 , wherein the electrochemically active lithium compound (a) comprises LiCoO 2 , LiNiO 2 , LiFePO 4 , LiCoPO 4 , LiMnO 2 , LiMn 2 O 4 , Li(NiMnCo)O 2 , Li(NiCoAl)O 2 , carbon-coated LiFePO 4 , or a mixture or combination of any of the foregoing.

5. The electrode slurry composition of claim 1 , wherein the electrically conductive agent (c) comprises graphite, acetylene black, furnace black, graphene or a mixture or combination of any of the foregoing.

6. The electrode slurry composition of claim 1 , wherein the slurry is essentially free of N-methyl-2-pyrrolidone.

7. The electrode slurry composition of claim 1 , wherein the electrochemically active lithium compound (a) is present in amounts of 70 to 98 percent by weight; the binder (b) is present in amounts of 1 to 10 percent by weight and the electrically conductive agent (c) is present in amounts of 1 to 20 percent by weight, the percentages by weight being based on the total weight of solids in the slurry.

8. The electrode slurry composition of claim 1 , wherein the binder (b) is essentially free of a polyvinylidene fluoride polymer.

9. The electrode slurry composition of claim 1 , wherein the epoxy functional polymer has an epoxy equivalent weight of 3500-11000.

10. The electrode slurry composition of claim 1 , wherein the acid functional acrylic polymer has a calculated acid value in the range of 20-150.

11. The electrode slurry composition of claim 1 , wherein the binder (b) further comprises a crosslinking agent.

12. The electrode slurry composition of claim 11 , wherein the crosslinking agent comprises an aminoplast, a polycarbodiimide, a polyepoxide or a mixture or combination of any of the foregoing.

13. An electrode comprising:
(a) an electrical current collector; and
(b) a cured film formed on the electrical current collector, wherein the film is deposited from a slurry composition compromising:
(i) an electrochemically active lithium compound capable of lithium intercalation and deintercalation;
(ii) a binder dispersed in an aqueous medium and comprising a reaction product of a reaction mixture comprising one or more epoxy functional polymer(s) and one or more acid functional acrylic polymer(s), wherein the reaction product comprises at least 70% by weight of one or more epoxy functional polymer(s) and up to 30% by weight of the one or more acid functional acrylic polymer(s), based on the total weight of the reaction product; and
(iii) an electrically conductive agent,
wherein the electrode is a positive electrode.

14. The electrode of claim 13 , wherein the electrical current collector (a) comprises copper or aluminum in the form of a mesh, sheet or foil.

15. The electrode of claim 13 , wherein the electrically conductive agent (iii) comprises graphite, acetylene black, furnace black, graphene or a mixture or combination of any of the foregoing.

16. The electrode of claim 13 , wherein the slurry composition further comprises a thickener.

17. The electrode of claim 16 , wherein the thickener comprises a carboxymethylcellulose.

18. An electrical storage device comprising:
(a) the electrode of claim 13 ,
(b) a counter electrode, and
(c) an electrolyte.

19. The electrical storage device of claim 18 , wherein the electrolyte (c) comprises a lithium salt dissolved in a solvent.

20. The electrical storage device of claim 19 , wherein the lithium salt is dissolved in an organic carbonate.

Assignees

• Ppg Ind Ohio Inc

Inventors

• Daughenbaugh Randy E
• Swarup Shanti
• HELLRING Stuart
• Chasser Anthony

Classifications

• H01M4/622 Primary

  being polymers · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M4/382

  Lithium (H01M4/405 takes precedence) · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title