Aqueous dispersion comprising a polymer-inorganic particles composite and method for preparing the same

Patent metadata

Field	Value
Publication number	US-11370870-B2
Application number	US-201816630950-A
Country	US
Kind code	B2
Filing date	Jul 9, 2018
Priority date	Jul 14, 2017
Publication date	Jun 28, 2022
Grant date	Jun 28, 2022

Abstract

The present disclosure refers to an aqueous dispersion comprising a polymer-inorganic particles composite and the method for preparing the same, wherein the polymer has ionic hydrophilic groups and hydrophobic long chain hydrocarbyl groups, and the polymer is covalently linked to said inorganic particles. The present disclosure also refers to powdered fillers obtained by drying the aqueous dispersion. The present disclosure further refers to a waterborne coating composition comprising the aqueous dispersion or the powdered fillers, as well as a coated article.

First claim

What is claimed is:

1. An aqueous dispersion comprising a polymer-inorganic particles composite, wherein the polymer has ionic hydrophilic groups and hydrophobic long chain hydrocarbyl groups, and the polymer is covalently linked to said inorganic particles, and the molar ratio of the ionic hydrophilic group to the hydrophobic long chain hydrocarbyl group is from 1000:1 to 100:1.

2. The aqueous dispersion according to claim 1 , wherein the ionic hydrophilic group comprises a potential anionic hydrophilic group, an anionic hydrophilic group, a potential cationic hydrophilic group, a cationic hydrophilic group or any combination thereof.

3. The aqueous dispersion according to claim 2 , wherein the ionic hydrophilic group comprises a carboxylic acid group or a salt thereof, a sulfuric acid group or a salt thereof, a phosphoric acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphite group or a salt thereof, a phosphonic acid group or a salt thereof, an amine group or a quaternary ammonium salt thereof, or any combination thereof.

4. The aqueous dispersion according to claim 3 , wherein the ionic hydrophilic group is derived from the group consisting of (meth)acrylic acid and a salt thereof, itaconic acid and a salt thereof, maleic acid and a salt thereof, fumaric acid and a salt thereof, crotonic acid and a salt thereof, (meth)acrylamide and a quaternary ammonium salt thereof, and any combination thereof.

5. The aqueous dispersion according to claim 1 , wherein the hydrophobic long chain hydrocarbyl group is derived from a C8-C30 alkyl (meth)acrylate.

6. The aqueous dispersion according to claim 1 , wherein the polymer is covalently bonded to the inorganic particle by a moiety containing —Si—O-linkage.

7. The aqueous dispersion according to claim 1 , wherein the inorganic particles comprise inorganic fibers.

8. The aqueous dispersion according to claim 1 , wherein the inorganic particles have an equivalent diameter of from 1 to 100 microns.

9. The aqueous dispersion according to claim 1 , wherein the amount of the inorganic particle is from 40 to 99.5 wt %, relative to the total weight of the inorganic particles and the polymer-forming monomer components.

10. The aqueous dispersion according to claim 1 , wherein the aqueous dispersion has a solid content by weight of from 50 to 90%.

11. The aqueous dispersion according to claim 1 , wherein the aqueous dispersion has a pH value of from 6 to 9.

12. A process for the preparation of an aqueous dispersion, comprising the steps of:
a) providing inorganic particles bearing one or more groups reactive with a monomer component;
b) reacting a polymer-forming monomer component with the inorganic particles bearing one or more groups reactive with a monomer component, to obtain a polymer-inorganic particles composite, wherein the polymer has ionic hydrophilic groups and hydrophobic long chain hydrocarbyl groups, and the molar ratio of the ionic hydrophilic group to the hydrophobic long chain hydrocarbyl group is from 1000:1 to 100:1, and the polymer is covalently linked to said inorganic particles;
c) adjusting the composite with a pH adjuster, to obtain the aqueous dispersion.

13. The process according to claim 12 , wherein the step of providing inorganic particles bearing one or more groups reactive with a monomer component comprises surface modifying the inorganic particles with a coupling agent bearing one or more groups reactive with a monomer component.

14. The process according to claim 12 , wherein the coupling agent comprises a silane coupling agent.

15. The process according to claim 12 , wherein the coupling agent comprises a silane compound having the formula:

in which
each X 1 is independently —Cl, —OCH 3 , —OCH 2 CH 3 , —OC 2 H 4 OCH 3 , —OSi(CH 3 ) 3 , or —OCOCH 3 ; and
Y 1 is an alkyl group substituted with an ethylenically unsaturated functional group.

16. The process according to claim 12 , wherein the coupling agent comprises a silane compound comprising γ-methacryloxypropyl trimethoxy silane.

17. The process according to claim 12 , wherein the coupling agent comprises an oligomeric silane having the formula:

wherein each of X 2 , X 3 and X 4 is independently —Cl, —OCH 3 , —OCH 2 CH 3 , —OC 2 H 4 OCH 3 , —OSi(CH 3 ) 3 , —OCOCH 3 , —H, —CH 3 , —C 2 H 5 , and —OH with the proviso that at least one of X 2 , X 3 and X 4 is not —H, —CH 3 , —C 2 H 5 , or —OH;
each of Y 2 , Y 3 and Y 4 is independently an alkyl group substituted with an ethylenically unsaturated functional group; and
each of m 1 , m 2 and m 3 independently is from 0 to 200, with the proviso that at least one of m 1 , m 2 and m 3 is not 0.

18. The process according to claim 12 , wherein the coupling agent is used in an amount of from 0.2 to 10 wt %, relative to the total weight of the inorganic particles.

19. The process according to claim 12 , wherein the polymer-forming monomer component having an ionic hydrophilic group comprises the monomers selected from the group consisting of: (meth)acrylic acid, itaconic acid, maleic acid, fumaric acid, crotonic acid, (meth)acrylamide, and any combination thereof.

20. The process according to claim 12 , wherein the polymer-forming monomer component having a hydrophobic long chain hydrocarbyl group comprises C8-C30 alkyl (meth)acrylate monomer.

21. The process according to claim 12 , wherein the amount of the inorganic particles is from 40 to 99.5 wt %, relative to the total weight of the inorganic particles and the polymer-forming monomer components.

22. The process according to claim 12 , wherein the pH adjuster comprises inorganic acids, organic acids, alkaline (earth) metal oxides, alkaline (earth) hydroxides, alkaline (earth) salts, ammonia, or any combination thereof.

23. The process according to claim 22 , the pH adjuster comprises HCl, H 2 SO 4 , H 3 PO 4 , HNO 3 , citric acid, succinic acid, malic acid, lactic acid, ammonia, NaOH, KOH, calcium carbonate, sodium carbonate, or any combination thereof.

24. Powdered fillers obtained by drying the aqueous dispersion according to claim 1 .

25. A waterborne coating composition, comprising the aqueous dispersion according to claim 1 .

26. The waterborne coating composition according to claim 25 , wherein the aqueous dispersion is present in an amount of from 1 to 30 wt %, relative to the total weight of the waterborne coating composition.

27. A coated article, comprising a substrate on which the aqueous dispersion according to claim 1 .

28. The coated article according to claim 27 , wherein the substrate comprises wood, wall, or metal.

Assignees

• Swimc Llc
• Guangdong Huarun Paints Co Ltd

Inventors

• Kai Weihua
• Duan Gang
• Zhao Xi
• Fan Shigang

Classifications

• C09D133/064

  containing anhydride, COOH or COOM groups, with M being metal or onium-cation · CPC title

• C08F292/00 Primary

  Macromolecular compounds obtained by polymerising monomers on to inorganic materials · CPC title

• C08K7/14

  Glass · CPC title

• C03C25/50

  Coatings containing organic materials only · CPC title

• C09D133/04 Primary

  Homopolymers or copolymers of esters {(C09D143/04 takes precedence)} · CPC title