Making low-sodium resin

Patent metadata

Field	Value
Publication number	US-11370852-B2
Application number	US-201816754590-A
Country	US
Kind code	B2
Filing date	Oct 8, 2018
Priority date	Oct 25, 2017
Publication date	Jun 28, 2022
Grant date	Jun 28, 2022

Abstract

Provided is method of treating a collection of resin beads (a) comprising the steps of (a) providing the collection of resin beads (a), wherein the resin beads (a) comprise one or more vinyl polymers having quaternary ammonium groups; wherein 90 mole % or more of the quaternary ammonium groups are each associated with a chloride anion; (b) bringing the collection of resin beads (a) into contact with an aqueous solution (b) comprising one or more dissolved (M)nXq to form a mixture (b), (c) separating water and compounds dissolved in the water from the mixture (b), to form resin beads (c) and waste solution (bw); (d) bringing resin beads (c) into contact with an aqueous solution (c) comprising dissolved (M3)(OH)p, to form a mixture (d).

First claim

The invention claimed is:

1. A method of treating a collection of resin beads (a) comprising the steps of
(a) providing the collection of resin beads (a),
wherein the resin beads (a) comprise one or more vinyl polymers having quaternary ammonium groups;
wherein 90 mole % or more of the quaternary ammonium groups are each associated with a chloride anion;

(b) bringing the collection of resin beads (a) into contact with an aqueous solution (b) comprising one or more dissolved (M) n X p to form a mixture (b),
wherein M is a cation of charge (+i) that contains no metal atom, alkali metal atom, or alkaline earth atom;
wherein X is an anion of charge (−j), wherein X is selected from the group consisting of carbonate, bicarbonate, dihydrogen phosphate, formate, acetate, and aminoacetate;
and wherein (n·i)=(p·j)

(c) separating water and compounds dissolved in the water from the mixture (b), to form resin beads (c) and waste solution (bw);
(d) bringing resin beads (c) into contact with an aqueous solution (c) comprising dissolved (M3)(OH) p , to form a mixture (d)
wherein M3 is a cation of charge (+k) that contains no metal atom, alkali metal atom, or alkaline earth atom;
and wherein p=k.

2. The method of claim 1 , comprising the additional step (e) of separating water and compounds dissolved in the water from the mixture (d), to form resin beads (e) and waste solution (ew).

3. The method of claim 2 , wherein the one or more vinyl polymers comprise one or more vinyl aromatic polymers.

4. The method of claim 3 , wherein the one or more vinyl aromatic polymers comprise polymerized units of structure (II)

wherein the two substituents on the aromatic ring may be in the ortho, meta, or para positions; wherein A ⊖ is an anion; wherein each of R 1 , R 2 , and R 3 is an organic group that contains at least one carbon atom and at least one hydrogen atom; and wherein the nitrogen atom in structure (II) is bonded to a carbon atom in each of R 1 , R 2 , and R 3 .

5. The method of claim 2 , wherein, after step (e), the sodium content of resin (e) is 100 ppb or less, by weight based on the total weight of resin (e).

6. The method of claim 1 , wherein M is ammonium, trialkyl ammonium, or a mixture thereof.

7. The method of claim 1 , wherein M is ammonium.

8. The method of claim 1 , wherein the one or more compounds M n X q comprise ammonium carbonate and ammonium bicarbonate.

Assignees

• Ddp Specialty Electronic Mat Us Inc
• Ddp Specialty Electronic Mat Us 8 Llc

Inventors

• Rohanna John C
• Tegen Marvin H
• Schultz Alfred K

Classifications

• C08F12/26

  Nitrogen · CPC title

• C08F6/008 Primary

  Treatment of solid polymer wetted by water or organic solvents, e.g. coagulum, filter cakes · CPC title

• C08J3/03

  in aqueous media · CPC title

• C08J2325/08

  Copolymers of styrene (C08J2329/08, C08J2335/06, C08J2355/02 take precedence) · CPC title

• C08J2325/18

  Homopolymers or copolymers of aromatic monomers containing elements other than carbon and hydrogen · CPC title