Ammonia manufacturing apparatus and ammonia manufacturing method

Patent metadata

Field	Value
Publication number	US-11370668-B2
Application number	US-202017276479-A
Country	US
Kind code	B2
Filing date	May 1, 2020
Priority date	May 1, 2020
Publication date	Jun 28, 2022
Grant date	Jun 28, 2022

Abstract

Included are: a raw material component storage unit that stores the raw material component supplied to the ammonia synthesis unit; a high-pressure raw material component storage unit that stores the raw material component at a pressure higher than a pressure at which the raw material component is stored in the raw material component storage unit; and a surplus electric power processing unit including a high-pressure raw material component transfer unit that boosts and transfers the raw material component from the raw material component storage unit to the high-pressure raw material component storage unit, and an expander that converts pressure energy of the raw material component supplied from the high-pressure raw material component storage unit into motive power to generate power.

First claim

The invention claimed is:

1. An ammonia manufacturing apparatus comprising:
a hydrogen generation unit that generates hydrogen by electrolysis of water;
an ammonia synthesis unit that synthesizes ammonia by a reaction between hydrogen and nitrogen using hydrogen generated in the hydrogen generation unit; and
a nitrogen supply unit that supplies nitrogen to the ammonia synthesis unit, and
further comprising:
a first surplus electric power processing unit,
the first surplus electric power processing unit including:
a first raw material component storage unit that stores hydrogen generated in the hydrogen generation unit supplied to the ammonia synthesis unit;
a first high-pressure raw material component storage unit that stores the hydrogen at a pressure higher than a pressure at which the hydrogen is stored in the first raw material component storage unit;
a first high-pressure raw material component transfer unit that increases the pressure of the hydrogen from the first raw material component storage unit and transfers the hydrogen from the first raw material component storage unit to the first high-pressure raw material component storage unit; and
a first expander that converts pressure energy of the hydrogen supplied from the first high-pressure raw material component storage unit into motive power to generate power,
wherein
a first power source using renewable energy is used as a power source for the electrolysis in the hydrogen generation unit, and at least one selected from the group consisting of surplus electric power of the first power source and surplus electric power of a second power source different from the first power source is used as a motive power source for the first high-pressure raw material component transfer unit.

2. The ammonia manufacturing apparatus according to claim 1 , wherein the motive power source for the first high-pressure raw material component transfer unit is surplus electric power of the first power source.

3. The ammonia manufacturing apparatus according to claim 1 , wherein
the nitrogen supply unit includes a liquid nitrogen manufacturing unit that manufactures liquid nitrogen from air.

4. The ammonia manufacturing apparatus according to claim 1 , wherein variable renewable energy selected from solar power generation, wind power generation, solar thermal power generation, and ocean power generation is used as at least one of the first power source and the second power source.

5. The ammonia manufacturing apparatus according to claim 1 , further comprising a power generation facility serving as the first power source.

6. The ammonia manufacturing apparatus according to claim 5 , wherein rated power generation output of the power generation facility is larger than electric power consumption of the electrolysis in the hydrogen generation unit.

7. The ammonia manufacturing apparatus according to claim 5 , wherein first electric power consumption, which is a part of electric power consumption of the electrolysis in the hydrogen generation unit, is derived from a power source other than the first power source, second electric power consumption, which is a balance of the electric power consumption of the electrolysis in the hydrogen generation unit, is derived from the first power source, and rated power generation output of the power generation facility is larger than the second electric power consumption.

8. The ammonia manufacturing apparatus according to claim 1 , wherein electric power generated by the first expander is supplied to any one of the hydrogen generation unit, the nitrogen supply unit, the ammonia synthesis unit and the first surplus electric power processing unit.

9. An ammonia manufacturing method comprising:
a hydrogen generation step of generating hydrogen by electrolysis of water;
an ammonia synthesis step of synthesizing ammonia by a reaction between hydrogen and nitrogen using hydrogen generated in the hydrogen generation step; and
a nitrogen supply step of supplying nitrogen to the ammonia synthesis step, and
further comprising:
a first surplus electric power processing unit for the hydrogen generated in the hydrogen generation step,
the first surplus electric power processing unit including:
a first raw material component storage unit that stores hydrogen generated in the hydrogen generation step supplied to the ammonia synthesis step;
a first high-pressure raw material component storage unit that stores the hydrogen at a pressure higher than a pressure at which the hydrogen is stored in the first raw material component storage unit;
a first high-pressure raw material component transfer unit that increases the pressure of the hydrogen from the first raw material component storage unit and transfers the hydrogen from the first raw material component storage unit to the first high-pressure raw material component storage unit; and
a first expander that converts pressure energy of the hydrogen supplied from the first high-pressure raw material component storage unit into motive power to generate power;
and
using a first power source using renewable energy as a power source for the electrolysis in the hydrogen generation step and using at least one selected from the group consisting of surplus electric power of the first power source and surplus electric power of a second power source different from the first power source as a motive power source for the first high-pressure raw material component transfer unit.

10. The ammonia manufacturing method according to claim 9 , wherein the motive power source for the first high-pressure raw material component transfer unit is the surplus electric power of the first power source.

11. The ammonia manufacturing method according to claim 9 , wherein at least a part of the hydrogen after the pressure energy of the hydrogen is converted into motive power by the first expander is supplied to the ammonia synthesis step.

12. The ammonia manufacturing method according to claim 9 , wherein at least a part of the hydrogen after the pressure energy of the hydrogen is converted into motive power by the first expander is stored in the first raw material component storage unit.

13. The ammonia manufacturing method according to claim 9 , wherein electric power generated by the first expander is consumed by any one of the hydrogen generation step, the nitrogen supply step, the ammonia synthesis step and the first surplus electric power processing unit.

Assignees

• Jgc Corp

Inventors

• Fujimoto Sho
• Fujimura Yasushi
• Kai Mototaka
• Hoshino Yuki

Classifications

• Y02E60/32

  Hydrogen storage · CPC title

• C01C1/0417

  characterised by the synthesis reactor, e.g. arrangement of catalyst beds and heat exchangers in the reactor · CPC title

• C25B1/04

  by electrolysis of water · CPC title

• C01C1/0447 Primary

  Apparatus other than synthesis reactors · CPC title

• Y02P20/133

  Renewable energy sources, e.g. sunlight · CPC title