Optical film and liquid crystal display device comprising the same

Patent metadata

Field	Value
Publication number	US-11366359-B2
Application number	US-201816160464-A
Country	US
Kind code	B2
Filing date	Oct 15, 2018
Priority date	Oct 17, 2017
Publication date	Jun 21, 2022
Grant date	Jun 21, 2022

Abstract

Embodiments relate to an optical film and a liquid crystal display device comprising the same. More specifically, the embodiments relate to an optical film that is excellent in optical characteristics and has no polarization unevenness since it comprises a base layer that has a low in-plane retardation and a low thickness direction retardation and has an excellent adhesiveness by virtue of a proper level of surface tension, a process for preparing the same, and a liquid crystal display device comprising the same.

First claim

The invention claimed is:

1. An optical film, which comprises a base layer comprising a fluorine-based resin and an acrylic resin in a weight ratio of 1:10 to 1:20, wherein the base layer has an in-plane retardation (R o ) of 10 nm or less at a wavelength of 550 nm, a thickness direction retardation (R th ) of 50 nm or less at a wavelength of 550 nm, and a surface tension of 40 dynes/cm to 60 dynes/cm,
wherein the fluorine-based resin is at least one selected from the group consisting of an ethylene-tetrafluoroethylene (ETFE) copolymer, a polyvinylidene fluoride (PVDF) homopolymer or copolymer, a tetrafluoroethylene-hexafluoropropylene (FEP) copolymer, a tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride (THV) copolymer, and a polychlorotrifluoroethylene (PCTFE or PTFCE) copolymer,
wherein the fluorine-based resin has a viscosity of 100 to 2,500 Pa·s, as measured by a capillary flow meter under the conditions of a shear rate of 100 s −1 and 230° C., and
wherein the base layer has a ratio of stretching in the transverse direction to stretching in the longitudinal direction of 1.1 to 1.5:1, and
wherein the optical film further comprises a primer coating layer on at least one side of the base layer, and the primer coating layer comprises at least one selected from the group consisting of polyester, polyurethane, and polyacrylate resins.

2. The optical film of claim 1 , wherein the base layer has a thickness of 100 μm or less.

3. The optical film of claim 1 , wherein the acrylic resin is a homopolymer.

4. The optical film of claim 3 , wherein the acrylic resin is a poly (methyl methacrylate) (PMMA).

5. The optical film of claim 1 , wherein the base layer has an in-plane retardation (R o ) of 0.1 nm to 10 nm and a thickness direction retardation (R th ) of 1 nm to 40 nm, wherein the ratio of R th /R o is 0.1 to 40.

6. The optical film of claim 1 , wherein the base layer has a ratio of the thickness direction retardation to the thickness (R th /thickness) of 0 to 0.005.

7. The optical film of claim 1 , wherein the base layer has an in-plane retardation (R o ) of 3 nm or less under the condition of a light incident angle of −50° to 50°.

8. The optical film of claim 1 , wherein the difference between the maximum value and the minimum value of the in-plane retardation (R o ) of the base layer is 1.5 or less under the condition of a light incident angle of −50° to 50°.

9. The optical film of claim 1 , wherein the base layer has a haze of 0.1% to 1% after thermal treatment at 150° C. for 3 hours.

10. The optical film of claim 1 , wherein the base layer has a shrinkage of 1% or less in a longitudinal direction and in a transverse direction, respectively, after treatment at 85° C. for 24 hours.

11. The optical film of claim 1 , which is used as a protective film for a polarizer.

12. A liquid crystal display device, which comprises a backlight unit and a liquid crystal panel, wherein the liquid crystal panel comprises an upper polarizing plate, a liquid crystal cell, and a lower polarizing plate in sequence, the upper polarizing plate and the lower polarizing plate each comprise a polarizer and protective films for a polarizer disposed on both sides of the polarizer, and at least one of the protective films for a polarizer is an optical film according to claim 1 .

Assignees

• Skc Co Ltd

Inventors

• Heo Young Min
• Lee Sechul
• Yu Jung Won
• Lee Seungwon
• Lee Jung Kyu

Classifications

• G02B1/14

  Protective coatings, e.g. hard coatings · CPC title

• G02B1/10

  Optical coatings produced by application to, or surface treatment of, optical elements (G02B1/08 takes precedence) · CPC title

• C08J2475/04

  Polyurethanes · CPC title

• C08J2427/12

  containing fluorine atoms · CPC title

• C08J2333/12

  Homopolymers or copolymers of methyl methacrylate · CPC title