Multi-layer substrates comprising sandwich layers and polyethylene

Patent metadata

Field	Value
Publication number	US-11364711-B2
Application number	US-201916710774-A
Country	US
Kind code	B2
Filing date	Dec 11, 2019
Priority date	Dec 21, 2018
Publication date	Jun 21, 2022
Grant date	Jun 21, 2022

Abstract

Multi-layer substrates comprising a top surface layer of pulp fibers, a bottom surface layer of pulp fibers, and a melted thermoplastic material layer between the pulp fiber layers, where the thermoplastic material comprises polyethylene or has a tan delta value of 0.2 to 0.4 within the temperature range of 100° F. to 350° F. The multi-layer substrate can include a cleaning composition loaded onto the multi-layer substrate, where a fluid pathway through the melted thermoplastic material allows the cleaning composition to travel from the top surface layer to the bottom surface layer. The multi-layer substrate may be void of chemical adhesives, where adhesion between the top surface layer and the thermoplastic layer, and between the bottom surface layer and the thermoplastic layer is instead provided by the thermoplastic material itself, which bonds to groups of fibers in the pulp fibers top and bottom surface layers that are in contact with the thermoplastic material as it melts.

First claim

The invention claimed is:

1. A multi-layer substrate comprising:
(a) a top surface layer consisting of: pulp fibers formed by one of the following processes: airlaid, wetlaid, carded webs, thermal bonded, through-air bonded, thermoformed, hydroentangled, or chemically bonded and any combinations thereof;
(b) a middle layer comprising a thermoplastic material comprising polyethylene;
(c) a bottom surface layer consisting of: pulp fibers formed by one of the following processes: airlaid, wetlaid, carded webs, thermal bonded, through-air bonded, thermoformed, hydroentangled, or chemically bonded and any combinations thereof; and
(d) a cleaning composition loaded onto said multi-layer substrate wherein a fluid pathway through the thermoplastic material allows the cleaning composition to travel from the top surface layer to the bottom surface layer;
(e) wherein the multi-layer substrate is void of any chemical adhesives, the thermoplastic material instead, when melted, bonding to groups of fibers in the top surface layer and the bottom surface layer that are in direct contact with the thermoplastic material as it melts and fractures, forming fluid pathways; and
(f) wherein the middle layer is melted from the polyethylene, wherein the polyethylene is initially in the form of a liquid impervious thin film, which becomes porous upon melting so as to provide the fluid pathway through which the cleaning composition is able to travel both from the top surface layer to the bottom surface layer and from the bottom surface layer to the top surface layer.

2. The multi-layer substrate of claim 1 , wherein the cleaning composition comprises a quaternary ammonium compound.

3. The multi-layer substrate of claim 2 , wherein at least 50% of a quaternary ammonium compound included in the cleaning composition loaded onto the multi-layer substrate is released from the multi-layer substrate to a surface being cleaned.

4. The multi-layer substrate of claim 1 , herein the cleaning composition comprises an organic acid.

5. The multi-layer substrate of claim 1 , wherein the top and bottom surface layers are wetlaid nonwoven materials selected from the following group: through-air-dried material, a press-dried tissue material, a DCT tissue material or a structured tissue material.

6. The multi-layer substrate of claim 1 , wherein the thermoplastic material of the middle layer is a film having a thickness from 0.01 mm to 0.05 mm.

7. The multi-layer substrate of claim 1 , wherein the multi-layer substrate includes:
(i) unbound regions where the thermoplastic material is not bound to the adjacent fibers of the top or bottom surface layer; and
(ii) bound regions where the thermoplastic material is bound to the adjacent fibers of both the top and bottom surface layer.

8. The multi-layer substrate of claim 7 , wherein the unbound regions correspond to raised texture features embossed in the top or bottom surface layer.

9. The multi-layer substrate of claim 8 , further comprising a gap associated with the unbound region in which the cleaning composition is stored.

10. The multi-layer substrate of claim 1 , wherein no adhesive is present between the thermoplastic material middle layer and the top and bottom surface layers, but rather the melted thermoplastic material directly bonds to groups of fibers in the top surface layer and the bottom surface layer, the melting and fracturing of the thermoplastic material forming an irregularly patterned bonded region between the thermoplastic material middle layer and the adjacent top and bottom surface layers.

11. A multi-layer substrate comprising:
(a) a top surface layer consisting of: pulp fibers formed by one of the following processes: airlaid, wetlaid, carded webs, thermal bonded, through-air bonded, thermoformed, hydroentangled, or chemically bonded and any combinations thereof;
(b) a middle layer comprising a thermoplastic material having a tan delta value of 0.2 to 0.4 within the temperature range of 100° F. to 350° F.;
(c) a bottom surface layer consisting of: pulp fibers formed by one of the following processes: airlaid, wetlaid, carded webs, thermal bonded, through-air bonded, thermoformed, hydroentangled, or chemically bonded and any combinations thereof; and
(d) a cleaning composition loaded onto said multi-layer substrate wherein a fluid pathway through the melted thermoplastic material allows the cleaning composition to travel from the top surface layer to the bottom surface layer;
(e) wherein the multi-layer substrate is void of any chemical adhesives, the thermoplastic material instead, when heated, bonding to groups of fibers in the top or bottom surface layer that are in direct contact with the middle layer comprising the thermoplastic material as it melts; and
(f) wherein the middle layer is melted from the thermoplastic material, wherein the thermoplastic material is initially in the form of a liquid impervious thin film, which becomes porous upon melting so as to provide the fluid pathway through which the cleaning composition is able to travel both from the top surface layer to the bottom surface layer and from the bottom surface layer to the top surface layer.

12. The multi-layer substrate of claim 11 , wherein the cleaning composition comprises a quaternary ammonium compound.

13. The multi-layer substrate of claim 12 , wherein at least 50% of a quaternary ammonium compound included in the cleaning composition loaded onto the multi-layer substrate is released from the multi-layer substrate to a surface being cleaned.

14. The multi-layer substrate of claim 11 , wherein the cleaning composition comprises an organic acid.

15. The multi-layer substrate of claim 11 , wherein the top surface layer is a wetlaid material selected from the following group: through-air-dried material, a press-dried tissue material, a DCT tissue material or a structured tissue material.

16. The multi-layer substrate of claim 11 , wherein the thermoplastic material of the middle layer is a film having a thickness from 0.01 mm to 0.05 mm.

17. The multi-layer substrate of claim 11 , wherein the thermoplastic material of the middle layer comprises polyethylene.

18. The multi-layer substrate of claim 11 , wherein the multi-layer substrate includes:
(i) unbound regions where the thermoplastic material is not bound to adjacent fibers of the top or bottom surface layer; and
(ii) bound regions where the thermoplastic material is bound to adjacent fibers of both the top and bottom surface layer.

19. The multi-layer substrate of claim 18 , wherein the unbound regions correspond to raised texture features embossed in the top or bottom surface layer.

20. The multi-layer substrate of claim 19 , further comprising a gap associated with the unbound region in which the cleaning composition is stored.

Assignees

• Clorox Co

Inventors

• Dani Nikhil P
• Hendrix Joerg
• Wood Scott A
• Chan Hubert
• Fritter Daniela N

Classifications

• B32B2555/02

  Diapers or napkins · CPC title

• B32B2307/554

  Wear resistance · CPC title

• B32B2307/54

  Yield strength; Tensile strength · CPC title

• B32B2307/30

  having particular thermal properties · CPC title

• B32B2262/06

  Vegetal fibres · CPC title