Rigid polyurethane foams suitable for use as panel insulation
US-2019322790-A1 · Oct 24, 2019 · US
US11359046B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11359046-B2 |
| Application number | US-201816019725-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 27, 2018 |
| Priority date | Jun 28, 2017 |
| Publication date | Jun 14, 2022 |
| Grant date | Jun 14, 2022 |
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An object of the present invention is to provide a polyurethane composition, in which reduction in the strength of the foam is suppressed when the foam has been greatly deformed. The present invention relates to a polyurethane composition comprising a base resin and a curing agent, wherein the base resin comprises a compound (A-1) comprising a polyalkylene skeleton comprising neither an aromatic skeleton nor an alicyclic skeleton, and having two or more functional groups having an active hydrogen atom, a compound (A-2) comprising an aromatic skeleton and/or alicyclic skeleton, and having two or more functional groups having an active hydrogen atom, a blowing agent (B), and an amine-based catalyst (C); a polyurethane foam therefrom; and a method for soundproofing and reinforcing a vehicle.
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What is claimed is: 1. A polyurethane composition comprising a base resin composition and a curing agent, wherein the base resin composition comprises a compound (A-1) comprising a polyalkylene skeleton comprising neither an aromatic skeleton nor an alicyclic skeleton, and having two or more functional groups independently selected from a hydroxyl group, a carboxyl group, an amino group, an imino group or a thiol group; at least two different compounds (A-2), each comprising structural units derived from a diamine compound having an aromatic skeleton and/or alicyclic skeleton and structural units derived from an epoxy group; a blowing agent (B); and an amine-based catalyst (C); wherein in each of the at least two different compounds (A-2), a ratio of a number of the structural units derived from the epoxy group to a number of the structural units derived from the diamine compound having the aromatic skeleton or alicyclic skeleton is less than or equal to 0.8, or 5 to 20. 2. The polyurethane composition according to claim 1 , wherein a content of the at least two different compounds (A-2) in the base resin composition is 3 to 50% by mass based on the total mass of the base resin composition. 3. The polyurethane composition according to claim 1 , wherein at least one functional group in the compound (A-1) is a hydroxyl group. 4. The polyurethane composition according to claim 1 , wherein the blowing agent (B) is water, and a content of the blowing agent (B) in the base resin composition is 0.1 to 2% by mass based on the total mass of the base resin composition. 5. The polyurethane composition according to claim 1 , wherein the curing agent contains an aromatic polyisocyanate. 6. A polyurethane foam comprising a cured product of the polyurethane composition as defined in claim 1 . 7. The polyurethane foam according to claim 6 , wherein a density of the polyurethane foam is 80 to 400 kg/m 3 . 8. A method for reinforcing and soundproofing a vehicle, comprising a step of injecting the polyurethane composition as defined in claim 1 into an inside of a closed cross section of a body member with a high pressure foaming machine, and forming a polyurethane foam inside the closed cross section of the body member. 9. A body member comprising the polyurethane foam as defined in claim 6 , the polyurethane foam being arranged inside the closed cross section of the body member. 10. A vehicle comprising the body member as defined in claim 9 . 11. The polyurethane composition according to claim 1 , wherein in each of the at least two different compounds (A-2), the ratio of a number of the structural units derived from the epoxy group to a number of the structural units derived from the diamine compound having the aromatic skeleton or alicyclic skeleton is 5 to 20. 12. The polyurethane composition according to claim 1 , wherein in each of the at least two different compounds (A-2), the ratio of a number of the structural units derived from the epoxy group to a number of the structural units derived from the diamine compound having the aromatic skeleton or alicyclic skeleton is 5 to 16.
Polyethers containing at least three hydroxy groups (C08G18/4833 - C08G18/5096 take precedence) · CPC title
containing alkylene polyphenyl groups · CPC title
≥50 and <150kg/m3 · CPC title
aromatic · CPC title
Reaction products of epoxy resins with at least equivalent amounts of amines · CPC title
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