System and method for using ultramicroporous carbon for the selective removal of nitrate with capacitive deionization

Patent metadata

Field	Value
Publication number	US-11358883-B2
Application number	US-201916268154-A
Country	US
Kind code	B2
Filing date	Feb 5, 2019
Priority date	Feb 5, 2019
Publication date	Jun 14, 2022
Grant date	Jun 14, 2022

Abstract

The present disclosure relates to a flow through electrode, capacitive deionization (FTE-CDI) system which is able to adsorb nitrates from water being treated using the system. The system makes use of a pair of electrodes arranged generally parallel to one another, with a water permeable dielectric sandwiched between the electrodes. The electrodes receive a direct current voltage from an electrical circuit. At least one of the electrodes is formed from a carbon material having a hierarchical pore size distribution which includes a first plurality of pores having a width of no more than about 1 nm, and a second plurality of micro-sized pores. The micron-sized pores enable a flow of water to be pushed through the electrodes while the first plurality of pores form adsorption sites for nitrate molecules carried in the water flowing through the electrodes.

First claim

What is claimed is:

1. An ultramicroporous electrode for use in a flow through, capacitive deionization (FTE-CDI) system for adsorbing nitrate ions contained in water being fed into the electrode for treatment, the electrode comprising:
a carbon aerogel member having a hierarchical pore size distribution, the hierarchical pore size distribution including:
a first plurality of ultramicropores each having a shape forming a slit, and substantially all of the first plurality of ultramicropores being below 1 nm in width and forming a slit-like shape; and
a second plurality of pores distributed throughout the thickness of the carbon aerogel member and being sufficiently large to enable fluid flow paths to be formed through the carbon aerogel member, which enable a flow of water to be pushed through the carbon aerogel member;

the first plurality of ultramicropores configured to selectively capture nitrate ions carried in the water flowing through the carbon aerogel member; and
wherein the first plurality of ultramicropores collectively provide a total pore volume of approximately 0.3 cm 3 /g and collectively provide a total pore area of about 1084 m 2 /g when the first plurality of ultramicropores are substantially all below 1 nm in width.

2. The ultramicroporous electrode of claim 1 , wherein the first plurality of ultramicropores is distributed throughout the thickness of the carbon aerogel member.

3. The ultramicroporous electrode of claim 1 , wherein the second plurality of pores each comprise micron-sized pores.

4. The ultramicroporous electrode of claim 3 , wherein the second plurality of micron-sized pores are distributed throughout the thickness of the carbon aerogel member.

5. The ultramicroporous electrode of claim 4 , wherein the second plurality micron-sized pores enable the flow of water to be pushed through the entire thickness of the carbon aerogel.

6. The ultramicroporous electrode of claim 1 , wherein the first plurality of ultramicropores each form an adsorption site for capturing the nitrate ions.

7. An ultramicroporous electrode for use in a flow through, capacitive deionization (FTE-CDI) system for adsorbing nitrate ions contained in water being fed into the electrode for treatment, the electrode comprising:
a carbon aerogel member having a hierarchical pore size distribution, the hierarchical pore size distribution including:
a first plurality of ultramicropores each shaped as a slit and each having a width configured to selectively capture a nitrate ion, and the slits being distributed throughout a thickness of the carbon aerogel member, and each one of the first plurality of ultramicropores having a width of no more than about 1 nm, and wherein the first plurality of ultramicropores collectively provide a total pore volume of 0.3 cm 3 /gram and collectively provide a total pore area of 1084 m 2 /g; and
a second plurality of pores distributed throughout the thickness of the carbon aerogel member, and being sufficiently large to enable fluid flow paths to be formed through the entire thickness of the carbon aerogel member, which enable a flow of water to be pushed through the thickness of the carbon aerogel member; and

the first plurality of ultramicropores operating to form adsorption sites to selectively capture nitrate ions carried in the water flowing through the carbon aerogel member.

8. The ultramicroporous electrode of claim 7 , wherein the first plurality of ultramicropores are distributed throughout the carbon aerogel member.

9. The ultramicroporous electrode of claim 7 , wherein the second plurality of pores comprise pores on the order of microns in size.

10. The ultramicroporous electrode of claim 9 , wherein the micron-sized pores are distributed throughout the thickness of the carbon aerogel member.

Assignees

• L Livermore Nat Security Llc

Inventors

• Campbell Patrick
• Hernandez Maira Ceron
• Hawks Steven
• Loeb Colin
• Pham Tuan Anh
• Stadermann Michael

Classifications

• B01D61/428

  Membrane capacitive deionization · CPC title

• C02F1/4691 Primary

  Capacitive deionisation · CPC title

• C01P2006/40

  Electric properties · CPC title

• C01B32/336

  characterised by gaseous activating agents · CPC title

• C01B32/318

  characterised by the starting materials · CPC title