Aerosol-based high-temperature synthesis of materials

Patent metadata

Field	Value
Publication number	US-11358876-B2
Application number	US-201816604623-A
Country	US
Kind code	B2
Filing date	Apr 27, 2018
Priority date	Apr 28, 2017
Publication date	Jun 14, 2022
Grant date	Jun 14, 2022

Abstract

A material synthesis method may comprise: adding at least one liquid precursor solution to an atomizer device; generating by the atomizer device an aerosol comprising liquid droplets; transporting the aerosol to a reactive zone for evaporating one or more solvents from the aerosol; and collecting particles synthesized from at least evaporating the aerosol.

First claim

What is claimed is:

1. A material synthesis method, comprising:
adding at least one liquid precursor solution to an atomizer device;
injecting an atomizing gas flow into the atomizer device, wherein a first part of the atomizing gas is released beneath a surface of the liquid precursor solution and a second part of the atomizing gas is released above the surface of the liquid precursor solution;
generating by the atomizer device an aerosol with dual size modes comprising a sub-micron droplet mode and a micron droplet mode;
transporting the aerosol to a reactive zone for evaporating one or more solvents from the aerosol; and
collecting synthesized particles.

2. The method according to claim 1 , wherein:
the at least one liquid precursor solution comprises a metal salt dissolved or diluted in a solvent;
the metal salt comprises at least one of alkaline, transition, or lanthanide metals;
the solvent comprises at least one of water, metal alkoxide, or one or more hydrocarbon liquids; and
the median size of the synthesized particles increases with the molar concentration of the liquid precursor solution.

3. The method according to claim 1 , wherein the at least one liquid precursor solution has a dynamic viscosity of less than 0.2 Pas and a molar concentration of 0.001-2 mol/L.

4. The method according to claim 1 , wherein: the aerosol has a droplet diameter of 100-1000 nm in the sub-micron droplet mode and a droplet diameter of 1-100 μm in the micron droplet mode.

5. The method according to claim 1 , wherein:
the atomizing gas comprises at least one of an oxidizer gas, an inert gas, or a fuel gas; and
the atomizing gas flow has a pressure of 1-100 bar.

6. The method according to claim 1 , wherein, before transporting the aerosol to the reactive zone, the method further comprises:
transporting the aerosol to a preheating section; and
preheating the aerosol at a temperature between 50° C. and 500° C. for evaporating at least a portion of the one or more solvents from the aerosol for 0.1-10 seconds.

7. The method according to claim 6 , wherein:
energy for the preheating is provided by at least one of electrical heating, combustion heating, or heat exchange with a recirculated exhaust gas.

8. The method according to claim 1 , wherein:
the reactive zone comprises at least one of a flame, plasma, furnace, laser heating, or electric heating;
the reactive zone is at a temperature of 500-10000° C. and a pressure of 500 mbar-10 bar; and
transporting the aerosol to the reactive zone for evaporating one or more solvents from the aerosol comprises transporting the aerosol to the reactive zone for evaporating one or more solvents from the aerosol for 0.1-10 seconds.

9. The method according to claim 1 , wherein:
transporting the aerosol to the reactive zone comprises transporting the aerosol to the reactive zone without preheating; and
the synthesized particles are hollow-structured.

10. The method according to claim 1 , further comprising:
collecting the synthesized particles comprises collecting the synthesized particles from an exhaust stream of the reactive zone by membrane filtering, electrostatic collection, bag filtering, or cold trap.

11. The method according to claim 1 ,
the synthesized particles comprise a metal oxide, fluoride, sulphide, oxysulphide, silicate, nitrate or nitride; and
the synthesized particles comprise non-aggregated particles.

12. The method according to claim 1 , wherein the synthesized particles comprise particles selected from a group consisting of: monodisperse Li(Ni 0.33 Mn 0.33 Co 0.33 )O 2 particles with an average diameter between 5-100 nm, hollow-structured Li(Ni 0.33 Mn 0.33 Co 0.33 )O 2 particles, and polydisperse Li(Ni 0.33 Mn 0.33 Co 0.33 )O 2 particles with diameters between 5 nm-10 μm.

13. A material synthesis method, comprising:
adding a first precursor solution to an atomizer device to generate a first aerosol comprising first liquid droplets;
transporting the first aerosol to a reactive zone for evaporating one or more first solvents from the first aerosol to obtain first synthesized particles of a first size distribution;
adding a second precursor solution to the atomizer device to generate a second aerosol comprising second liquid droplets;
generating, by the atomizer device, the second aerosol with dual size modes comprising a sub-micron droplet mode and a micron droplet mode; and
transporting the second aerosol to the reactive zone for evaporating one or more second solvents from the second aerosol to obtain second synthesized particles of a second size distribution.

14. The method according to claim 13 , wherein:
the first and second precursor solutions comprise gasoline and water respectively.

15. The method according to claim 13 , wherein:
the first and second size distributions are selected from monodisperse and polydisperse distributions;
the monodisperse distribution is associated with an average diameter between 5-100 nm, and is obtained from corresponding liquid droplets that at least 99% by number of which have a diameter of less than 1 μm or an arithmetic mean diameter between 0.1 and 1 μm; and
the polydisperse distribution is associated with diameters between 5 nm-10 μm, and is obtained from corresponding liquid droplets that are sub-micron in diameter or 1-100 μm in diameter.

Assignees

• Univ Princeton

Inventors

• Ju Yiguang
• Mezhericher Maksym
• Abram Christopher

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• C01P2004/51

  Particles with a specific particle size distribution · CPC title

• C01P2004/03

  obtained by SEM · CPC title

• C01P2004/04

  obtained by TEM, STEM, STM or AFM · CPC title

• C01G53/50

  of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 · CPC title