Composite fusion filament

Patent metadata

Field	Value
Publication number	US-11358328-B2
Application number	US-201916355186-A
Country	US
Kind code	B2
Filing date	Mar 15, 2019
Priority date	Mar 15, 2019
Publication date	Jun 14, 2022
Grant date	Jun 14, 2022

Abstract

A composite fusion filament is disclosed that includes a polymer encasement and one or more mesogenic reinforcement bodies contained within the polymer encasement. The polymer encasement is comprised of a thermoplastic polymer, which has a melting temperature, and each of the one or more mesogenic reinforcement bodies is comprised of a thermotropic liquid crystal polymer, which has a clearing temperature. The melting temperature of the thermoplastic polymer included in the polymer encasement is less than the clearing temperature of the thermotropic liquid crystal polymer included in the one or more mesogenic reinforcement bodies. Additionally, the thermotropic liquid crystal polymer of each mesogenic reinforcement body has a plurality of organized crystalline fibrils that are aligned lengthwise along a longitudinal axis of the polymer encasement. A method of using the composite fusion filament to form a bond with a substrate that includes a thermoplastic polymer is also disclosed.

First claim

The invention claimed is:

1. A composite fusion filament comprising:
a polymer encasement having a longitudinal axis along which a length of the composite fusion filament is defined, the polymer encasement being comprised of a thermoplastic polymer that has a melting temperature;
one or more mesogenic reinforcement bodies contained within the polymer encasement, the one or more mesogenic reinforcement bodies being comprised of a thermotropic liquid crystal polymer having organized crystalline fibrils exhibiting orientation alignment along the longitudinal axis by being aligned lengthwise along the longitudinal axis of the polymer encasement such that a director of the organized crystalline fibrils runs parallel to the longitudinal axis, the thermotropic liquid crystal polymer of the one or more mesogenic reinforcement bodies having a clearing temperature that is greater than the melting temperature of the thermoplastic polymer of the polymer encasement, the fibrils being axially and radially spaced apart from each other such that the fibrils are interleaved by which one or more fibrils overlaps with one or more other fibrils relative to the longitudinal axis.

2. The composite fusion filament set forth in claim 1 , wherein the melting temperature of the thermoplastic polymer is between 160° C. and 350° C., and the clearing temperature of the thermotropic liquid crystal polymer is between 250° C. and 400° C.

3. The composite fusion filament set forth in claim 1 , wherein the melting temperature of the thermoplastic polymer is between 240° C. and 280° C., and the clearing temperature of the thermotropic liquid crystal polymer is between 280° C. and 310° C.

4. The composite fusion filament set forth in claim 1 , wherein the thermoplastic polymer is an aliphatic polyamide or polyethylene terephthalate.

5. The composite fusion filament set forth in claim 1 , wherein the thermotropic liquid crystal polymer is poly(hydroxybenzoic acid) or poly(1,4-phenylene terephthalate).

6. The composite fusion filament set forth in claim 1 , wherein the thermotropic liquid crystal polymer is a co-polyester.

7. The composite fusion filament set forth in claim 6 , wherein the thermotropic liquid crystal polymer is poly(4,4′-dihyroxybiphenyl-co-terephthalic acid), poly(4,4′-dihydroxybiphenyl-co-terephthalic acid-co-isophthalic acid), poly(hydroxybenzoic acid-co-2-hydroxy-6-naphthoic acid), poly(ethylene terephthalate-co-hydroxybenzoic acid), or poly(p-acetoxybenzoic acid-co-ethylene terephthalate).

8. The composite fusion filament set forth in claim 1 , wherein the thermotropic liquid crystal polymer is a co-polyester-amide.

9. The composite fusion filament set forth in claim 8 , wherein the thermotropic liquid crystal polymer is poly(6-hydroxy-2-naphthoic acid-co-terephthalic acid-co-4 aminophenol).

10. The composite fusion filament set forth in claim 1 , wherein, when the composite fusion filament is sectioned perpendicular to the length of the filament, a ratio of a sectional surface area of the polymer encasement to a sectional surface area of the one or more mesogenic reinforcement bodies ranges from 0.1 to 20.

11. The composite fusion filament set forth in claim 1 , wherein the ratio of the sectional surface area of the polymer encasement to the sectional surface area of the one or more mesogenic reinforcement bodies ranges from 1 to 2.

12. The composite fusion filament set forth in claim 1 , wherein the polymer encasement has a thickness that ranges from 1.0 mm to 10.0 mm.

13. The composite fusion filament set forth in claim 1 , wherein the polymer encasement has an outer surface that defines an outer diameter of the composite fusion filament.

14. The composite fusion filament set forth in claim 1 , wherein the polymer encasement is an annular polymer shell, and wherein the one or more mesogenic reinforcement bodies is a single elongated liquid crystal polymer core that is surrounded circumferentially by the annular polymer shell and is coextensive in length with the annular polymer shell.

15. The composite fusion filament set forth in claim 1 , wherein the polymer encasement includes an annular polymer shell portion, and the one or more mesogenic reinforcement bodies is a series of elongated liquid crystal polymer cores that are in axial alignment along the longitudinal axis of the polymer encasement.

16. The composite fusion filament set forth in claim 1 , wherein the polymer encasement includes an annular polymer shell portion, and the one or more mesogenic reinforcement bodies is a plurality of continuous elongated liquid crystal polymer cores that are spaced apart within the polymer encasement and surrounded by the annular polymer shell portion of the polymer encasement, each of the plurality of continuous elongated liquid crystal polymer cores being coextensive in length with the polymer encasement.

17. The composite fusion filament set forth in claim 1 , wherein the polymer encasement includes an annular polymer shell portion, and the one or more mesogenic reinforcement bodies is multiple series of elongated liquid crystal polymer cores that are in axial alignment along the longitudinal axis of the polymer encasement.

18. A method of depositing a composite fusion filament, the method comprising:
feeding a composite fusion filament to a fusion deposition head that includes a liquefier and a nozzle, the composite fusion filament comprising a polymer encasement and one or more mesogenic reinforcement bodies contained within the polymer encasement, the polymer encasement having a longitudinal axis along which a length of the composite fusion filament is defined, the polymer encasement being comprised of a thermoplastic polymer having a melting temperature, and the one or more mesogenic reinforcement bodies being comprised of a thermotropic liquid crystal polymer having organized crystalline fibrils exhibiting orientation alignment along the longitudinal axis by being aligned lengthwise along the longitudinal axis of the polymer encasement such that a director of the organized crystalline fibrils runs parallel to the longitudinal axis, the thermotropic liquid crystal polymer having a clearing temperature that is greater than the melting temperature of the thermoplastic polymer, the fibrils being axially and radially spaced apart from each other such that the fibrils are interleaved by which one or more fibrils overlaps with one or more other fibrils relative to the longitudinal axis;
heating the composite fusion filament in the liquefier to a processing temperature that is above the melting temperature of the thermoplastic polymer of the polymer encasement yet below the clearing temperature of the thermotropic liquid crystal polymer of the one or more mesogenic reinforcement bodies;
depositing the composite fusion filament onto a substrate comprising a thermoplastic polymer that is compatible with the thermoplastic polymer of the polymer encasement of the composite fusion filament; and
allowing a deposited molten form of the polymer encasement of the composite fusion filament and a melted contact portion of the thermoplastic polymer of the substrate to harden into a polymer bond.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Okonski David A
• Gergely Ryan
• Carlson Blair E
• Rodgers William R

Classifications

• B33Y70/10 Primary

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• B29K2267/04

  Polyesters derived from hydroxycarboxylic acids · CPC title

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• C08J2477/00

  Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers · CPC title