High activity reforming catalyst formulation and process for low temperature steam reforming of hydrocarbons to produce hydrogen

Patent metadata

Field	Value
Publication number	US-11358128-B2
Application number	US-201916730257-A
Country	US
Kind code	B2
Filing date	Dec 30, 2019
Priority date	Dec 30, 2019
Publication date	Jun 14, 2022
Grant date	Jun 14, 2022

Abstract

A method for producing a hydrogen rich gas from a heavy hydrocarbon feed comprising the steps of introducing the hydrocarbon feed to a reactor, the reactor comprising a low temperature reforming catalyst, the low temperature reforming catalyst comprising an amount of praseodymium, 12 wt % nickel, and an aluminum oxide component, contacting the low temperature reforming catalyst with the hydrocarbon feed in the reactor, wherein the reactor operates at a temperature between 500° C. and 600° C., wherein the reactor operates at a pressure between 3 bar and 40 bar, and producing the hydrogen rich gas over the low temperature reforming catalyst, wherein the hydrogen rich gas comprises hydrogen.

First claim

That which is claimed is:

1. A method for producing a hydrogen rich gas from a hydrocarbon feed, the method comprising the steps of:
preparing a low temperature reforming catalyst comprising the steps of:
impregnating a dried alumina powder with a praseodymium nitrate solution to produce a precursor containing the amount of praseodymium;
drying the precursor at 250° C. for 8 hours to produce a dried precursor;
increasing a temperature of the dried precursor to 450° C. at a rate of 5° C./min;
calcining the dried precursor in air at 450° C. for at least 4 hours to produce a calcined precursor;
reducing a temperature of the calcined precursor;
impregnating the calcined precursor with Ni(NO 3 ) 3 .6H 2 0 solution to produce a nickel impregnated precursor;
drying the nickel impregnated precursor at a temperature of 60° C. for at least 1 hour;
subjecting the nickel impregnated precursor to ammonia vapors for 10 minutes;
increasing a temperature of the nickel impregnated precursor to 250° C. at a rate of 2° C./min;
drying the nickel impregnated precursor at 250° C. for at least 1 hour to produce a dried catalyst;
calcining the dried catalyst in air at 450° C. for about 2 hours to produce a calcined catalyst; and

reducing a temperature of the calcined catalyst to room temperature in a desiccator to produce the low temperature reforming catalyst, where the dessicator is configured to desiccate the calcined catalyst to produce particles of the low temperature reforming catalyst;

introducing the hydrocarbon feed to a reactor, the reactor comprising the low temperature reforming catalyst, the low temperature reforming catalyst comprising:
an amount of praseodymium,
12 wt % nickel, and
an aluminum oxide component;

introducing a steam feed to the reactor, wherein the steam feed comprises steam, wherein a ratio of steam to carbon is in the range between 2.8 and 4.2;
contacting the low temperature reforming catalyst with the hydrocarbon feed in the reactor, wherein the reactor operates at a temperature between 500° C. and 600° C., wherein the reactor operates at a pressure between 3 bar and 40 bar; and
producing the hydrogen rich gas over the low temperature reforming catalyst, wherein the hydrogen rich gas comprises hydrogen.

2. The method of claim 1 , wherein the amount of praseodymium is present in an amount between 1 wt % and 9 wt %.

3. The method of claim 1 , wherein the amount of praseodymium is 3 wt %.

4. The method of claim 1 , wherein the hydrocarbon feed comprises methane.

5. The method of claim 1 , wherein the hydrogen rich gas comprises an additional gas selected from the group consisting of carbon dioxide, carbon monoxide, methane, nitrogen, and combinations of the same.

6. The method of claim 1 , further comprising reducing the low temperature reforming catalyst before contacting the low temperature reforming catalyst with the hydrocarbon feed, comprising the step of:
introducing a reducing gas to the reactor for at least 8 hours, wherein the reducing gas comprises hydrogen and nitrogen.

7. The method of claim 1 , further comprising the step of sieving the particles of the low temperature reforming catalyst to obtain particles in the range between 0.1 mm and 1 mm.

8. The method of claim 1 , wherein a conversion of the hydrocarbon feed to hydrogen is greater than 50%.

9. The method of claim 1 , wherein the hydrogen rich gas is a fuel for a vehicle.

10. The method of claim 1 , wherein an amount of hydrogen in the hydrogen rich gas is in the range between 45 mol % and 75 mol %.

11. The method of claim 1 , wherein the reactor is an impregnated membrane reactor, wherein the impregnated membrane reactor comprises a hydrogen selective membrane impregnated with the low temperature reforming catalyst.

Assignees

• Saudi Arabian Oil Co
• Univ King Fahd Pet & Minerals

Inventors

• Ahmed Shakeel
• Harale Aadesh
• Albuali Mohammed
• Lee Kunho
• Katikaneni Sai P
• Draze Mohammed

Classifications

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J37/0236

  Drying, e.g. preparing a suspension, adding a soluble salt and drying · CPC title

• Y02P20/141

  Feedstock · CPC title

• B01J37/088

  Decomposition of a metal salt · CPC title