Battery electrode coatings applied by waterborne electrodeposition

Patent metadata

Field	Value
Publication number	US-11355741-B2
Application number	US-201816227320-A
Country	US
Kind code	B2
Filing date	Dec 20, 2018
Priority date	Dec 20, 2018
Publication date	Jun 7, 2022
Grant date	Jun 7, 2022

Abstract

The present invention is directed towards a method of coating a substrate comprising electrocoating an electrodepositable coating composition onto the substrate, the electrodepositable coating composition comprising a binder comprising a pH-dependent rheology modifier; an electrochemically active material and/or an electrically conductive agent; and an aqueous medium. Also disclosed are electrodepositable coating compositions, coated substrates and electrical storage devices.

First claim

We claim:

1. An electrodepositable coating composition comprising:
a binder comprising a film-forming polymer comprising functional groups and a crosslinking agent comprising functional groups reactive with the functional groups of the film-forming polymer, wherein the film-forming polymer comprises a pH-dependent rheology modifier comprising the residue of a crosslinking monomer and/or a monoethylenically unsaturated alkylated alkoxylate monomer;
an electrochemically active material and/or an electrically conductive agent; and
an aqueous medium,
wherein the pH-dependent rheology modifier comprises a crosslinked alkali-swellable rheology modifier comprising constitutional units comprising the residue of:
20 to 65% by weight of a monoethylenically unsaturated carboxylic acid;
20 to 80% by weight of a C1 to C6 alkyl (meth)acrylate monomer; and
0.1 to 3% by weight of a crosslinking monomer, based on the total weight of the crosslinked alkali-swellable rheology modifier.

2. The electrodepositable coating composition of claim 1 , wherein a composition of water and the alkali-swellable rheology modifier at 4.25% by weight of the total composition has an increase in viscosity of at least 500 cps over an increase in pH value of 3 pH units within the pH range of 3 to 12, as measured using a Brookfield viscometer using a #4 spindle and operated at 20 RPMs.

3. An electrodepositable coating com position comprising:
a binder comprising a film-forming polymer comprising functional groups and a crosslinking agent comprising functional groups reactive with the functional groups of the film-forming polymer, wherein the film-forming polymer comprises a pH-dependent rheology modifier comprising the residue of a crosslinking monomer and/or a monoethylenically unsaturated alkylated alkoxylate monomer;
an electrochemically active material and/or an electrically conductive agent; and
an aqueous medium,
wherein the pH-dependent rheology modifier comprises a hydrophobically modified alkali-swellable rheology modifier comprising constitutional units comprising the residue of:
2 to 70% by weight of a monoethylenically unsaturated carboxylic acid;
20 to 80% by weight of a C 1 to C 6 alkyl (meth)acrylate monomer; and
0.5 to 60% by weight of a monoethylenically unsaturated alkyl alkoxylate monomer, based on the total weight of the hydrophobically modified alkali-swellable rheology modifier.

4. An electrodepositable coating composition comprising:
a binder comprising a film-forming polymer comprising functional groups and a crosslinking agent comprising functional groups reactive with the functional groups of the film-forming polymer, wherein the film-forming polymer comprises a pH-dependent rheology modifier comprising the residue of a crosslinking monomer and/or a monoethylenically unsaturated alkylated alkoxylate monomer;
an electrochemically active material and/or an electrically conductive agent; and
an aqueous medium,
wherein the pH-dependent rheology modifier comprises an acid-swellable rheology modifier.

5. The electrodepositable coating composition of claim 1 , wherein the binder further comprises a non-fluorinated organic film-forming polymer different than the pH-dependent rheology modifier.

6. The electrodepositable coating composition of claim 5 , wherein the non- fluorinated organic film-forming polymer comprises polysaccharides, polyacrylates, polyethylene, polystyrene, polyvinyl alcohol, poly (methyl acrylate), poly (vinyl acetate), polyacrylonitrile, polyimide, polyurethane, polyvinyl butyral, polyvinyl pyrrolidone, styrene butadiene rubber, xanthan gum, or combinations thereof.

7. The electrodepositable coating composition of claim 1 , wherein the electrochemically active material comprises LiCoO 2 , LiNiO 2 , LiFePO 4 , LiFeCoPO 4 , LiCoPO 4 , LiMnO 2 , LiMn 2 O 4 , Li(NiMnCo)O 2 , Li(NiCoAl)O 2 , carbon-coated LiFePO 4 , sulfur, LiO 2 , FeF 2 and FeF 3 , Si, aluminum, tin, SnCo, Fe 3 O 4 , or combinations thereof.

8. The electrodepositable coating composition of claim 1 , wherein the electrochemically active material comprises graphite, lithium titanate, lithium vanadium phosphate, silicon, silicon compounds, tin, tin compounds, sulfur, sulfur compounds, lithium metal, graphene, or a combination thereof.

9. The electrodepositable coating composition of claim 1 , wherein the electrically conductive agent comprises conductive carbon black, carbon nanotubes, graphene, graphite, carbon fibers, fullerenes, and combinations thereof.

10. The electrodepositable coating composition of claim 1 , wherein the crosslinking agent comprises carbodiimide.

11. The electrodepositable coating composition of claim 1 , wherein the electrodepositable coating composition comprises:
(a) 0.1% to 10% by weight of the pH-dependent rheology modifier;
(b) 0.02% to 2% by weight of the crosslinking agent;
(c) 45% to 99% by weight of the electrochemically active material;
(d) optionally 0.5% to 20% by weight of an electrically conductive agent; and
(e) optionally 0.1% to 9.9% by weight of a non-fluorinated organic film-forming polymer; the % by weight based on the total solids weight of the electrodepositable composition.

12. The electrodepositable coating composition of claim 1 , wherein the electrodepositable coating composition has a volatile organic content of no more than 500 g/L.

13. The electrodepositable coating composition of claim 1 , wherein a coating produced on a substrate by electrocoating the electrodepositable coating composition of claim 1 has a 90° peel strength of at least 100 N/m at a mass loading of 2.15 mg/cm 2 , the 90° peel strength measured according to PEEL STRENGTH TEST METHOD.

14. The electrodepositable coating composition of claim 1 , wherein the electrodepositable coating composition is substantially free of fluoropolymer.

15. The electrodepositable coating composition of claim 1 , wherein the electrodepositable coating composition is substantially free of cellulose-based materials.

16. The electrodepositable coating composition of claim 1 , wherein the pH-dependent rheology modifier is substantially free of amide, glycidyl and hydroxyl groups.

17. The electrodepositable coating composition of claim 1 , wherein the pH-dependent rheology modifier is substantially free of the residue of constitutional units comprising aromatic vinyl monomers.

18. A method of coating a substrate comprising:
electrocoating the electrodepositable coating composition of claim 1 onto at least a portion of the substrate.

Assignees

• Ppg Ind Ohio Inc

Inventors

• Hellring Stuart D
• Oakes Landon J
• Olson Kurt G
• Landis Chad A
• Mohin Jacob W

Classifications

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/621

  Binders · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/131 Primary

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01G11/38

  Carbon pastes or blends; Binders or additives therein · CPC title