Dihydrocarbyl-silyl-bridged-substituted cyclopentadienyl metallocene complexes for olefin polymerization

Patent metadata

Field	Value
Publication number	US-11352386-B2
Application number	US-201816500663-A
Country	US
Kind code	B2
Filing date	Apr 4, 2018
Priority date	Apr 4, 2017
Publication date	Jun 7, 2022
Grant date	Jun 7, 2022

Abstract

The invention relates to a metallocene complex according to formula (I), wherein R1 is selected from C2-C10 alkyl, preferably C3-C10 alkyl, C6-C20 aryl, C7-C20 aralkyl groups, wherein R2 is selected from H, C1-C10 alkyl, and wherein R3, R4, R5 and R6 are independently selected from H, C1-C10 alkyl, C6-C20 aryl, or C7-C20 aralkyl groups and wherein R3 and R4, R4 and R5, or R5 and R6 can be connected to form a ring structure wherein M is selected from Ti, Zr and Hf, X is an anionic ligand to M. The invention also relates to a catalyst comprising the reaction product of the metallocene complex and a cocatalyst. Further the invention relates to a (co)polymerization process of olefinic monomers.

First claim

The invention claimed is:

1. Metallocene complex according to formula I,

wherein R1 is isopropyl, wherein R2 and R3 are each independently is-selected from H, methyl, ethyl, n-propyl, iso-propyl, n-butyl, t-butyl, or cyclohexyl, and wherein R4, R5 and R6 are independently selected from H, methyl, ethyl, n-propyl, iso-propyl, n-butyl, t-butyl, cyclohexyl, benzyl, phenyl, 3,5-dimethyl-1-phenyl, 3,5-diethyl-1-phenyl, 3,5-diisopropyl-1-phenyl, or 3,5-ditertiairbutyl-1-phenyl, and wherein R4 and R5, or R5 and R6 are optionally connected to form a ring structure, wherein each R10 is a C1-C4 alkyl group,
wherein M is selected from Ti, Zr and Hf, X is an anionic ligand to M.

2. A metallocene complex according to formula (II):

wherein R2 is selected from H and C1-C10 alkyl groups, R3 is H or C1-C10 alkyl, and R3, R4, R5 and R6 are independently selected from H, C1-C10 alkyl, and C6-C20 aryl, and wherein R4 and R5, or R5 and R6 are optionally connected to form a ring structure, M is Ti, Zr, or Hf, X is an anionic ligand to M, z is the number of X groups and equals the valence of M minus 2, and
wherein R7 and R8 are C1-C10 alkyl groups.

3. A metallocene complex according to formula (III)

wherein R1 is isopropyl, R2 is H, R3 is H, R4-R6 are chosen from H, a methyl group, or a phenyl group, M is Ti, Zr, or Hf, X is an anionic ligand to M, and z is the number of X groups and equals the valence of M minus 2.

4. A catalyst comprising the metallocene complex according to claim 3 and a cocatalyst.

5. The catalyst according to claim 4 , wherein the cocatalyst includes aluminium- or boron-containing cocatalysts.

6. A process for the preparation of olefin polymers, the method comprising polymerizing one or more olefins in the presence of a cocatalyst and the metallocene complex according to claim 3 , wherein the metallocene complex optionally is immobilized on a support.

7. The process according to claim 6 , wherein a mixture of ethylene and at least one other α-olefin of 3 or more carbon atoms is polymerized.

8. The metallocene complex according to claim 1 , wherein each R10 is a methyl group.

9. The metallocene complex according to claim 3 , wherein M is zirconium.

10. The metallocene complex according to claim 3 , wherein X is a methyl group or Cl.

11. The metallocene complex according to claim 3 , wherein R4-R6 are H.

12. The metallocene complex according to claim 11 , wherein M is zirconium.

13. The metallocene complex according to claim 11 , wherein X is a methyl group or Cl.

14. The metallocene complex according to claim 3 , wherein M is zirconium or hafnium.

15. The metallocene complex according to claim 3 , wherein X is a methyl group, Cl, Br or I.

Assignees

• Sabic Global Technologies Bv

Inventors

• Friederichs Nicolaas Hendrika
• Vittoria Antonio
• Cipullo Roberta
• Busico Vincenzo
• Borisov Ilya
• Guzeev Bogdan A
• Mladentsev Dmitry Y
• Sharikov Mikhail I
• Uborsky Dmitry
• Voskoboynikov Alexander
• Coen Hendriksen

Classifications

• C08F4/65927

  two cyclopentadienyl rings being mutually bridged · CPC title

• C07F17/00 Primary

  Metallocenes · CPC title

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title