Catalyst for hydrogenation of carbonyl compound and alcohol production method

Patent metadata

Field	Value
Publication number	US-11352309-B2
Application number	US-202117237232-A
Country	US
Kind code	B2
Filing date	Apr 22, 2021
Priority date	Mar 8, 2017
Publication date	Jun 7, 2022
Grant date	Jun 7, 2022

Abstract

Provided is a catalyst including a metal component including a first component that is rhenium and one or more second components selected from the group consisting of silicon, gallium, germanium, and indium and a carrier on which the metal component is supported, the carrier including an oxide of a metal belonging to Group 4 of the periodic table. Also provided is an alcohol production method in which a carbonyl compound is treated using the above catalyst. It is possible to produce an alcohol by a hydrogenation reaction of a carbonyl compound with high selectivity and high efficiency while reducing side reactions.

First claim

The invention claimed is:

1. An alcohol production method in which an alcohol is produced from a carbonyl compound, the method comprising producing an alcohol by contacting a carbonyl compound with a catalyst, the catalyst comprising a metal component comprising a first component that is rhenium and one or more second components selected from the group consisting of silicon, gallium, germanium, and indium, and a carrier on which the metal component is supported, a mass ratio of elements that are the second components to the rhenium element being in a range of 0.1 to 10.

2. The alcohol production method according to claim 1 , wherein the second components of the catalyst comprise germanium.

3. The alcohol production method according to claim 1 ,
wherein the metal component further comprises a third component, which is a metallic element belonging to Groups 8 to 10 of the periodic table, the metallic element being other than iron or nickel,
wherein a mass ratio of the metallic element to the rhenium element included in the catalyst is less than 0.2.

4. The alcohol production method according to claim 3 , wherein the metallic element comprises ruthenium.

5. The alcohol production method according to claim 1 , wherein the carrier is a carbonaceous carrier or a carrier comprising an oxide of a metal belonging to Group 4 of the periodic table.

6. The alcohol production method according to claim 1 , wherein the catalyst is a catalyst prepared by a method comprising attaching the metal component to a carrier comprising a sulfate ion.

7. The alcohol production method according to claim 6 , wherein the sulfate ion content in the carrier is 0.01% by mass to 10% by mass of the mass of the carrier.

8. The alcohol production method according to claim 6 , wherein the sulfate ion content in the catalyst is 0.01% by mass to 10% by mass of the mass of the catalyst.

9. The alcohol production method according to claim 1 , wherein a sulfate ion content in the catalyst is 0.01% by mass to 10% by mass of the mass of the catalyst.

10. A method of hydrogenating a carbonyl compound to a corresponding alcohol, the method comprising:
producing the corresponding alcohol by contacting the carbonyl compound with a catalyst, the catalyst comprising a metal component comprising a first component that is rhenium and one or more second components selected from the group consisting of silicon, gallium, germanium, and indium, and a carrier on which the metal component is supported, a mass ratio of elements that are the second components to the rhenium element being in a range of 0.1 to 10.

11. The method according to claim 10 , wherein the carbonyl compound is at least one selected from the group consisting of a carboxylic acid, a carboxylic acid ester, a carboxylic anhydride, and an aldehyde.

12. The method according to claim 10 , wherein the carbonyl compound is a polyvalent carboxylic acid, and the corresponding alcohol is a hydroxycarboxylic acid or a polyhydric alcohol.

13. The method according to claim 10 , wherein carrier comprises titanium oxide and/or zirconium oxide.

14. The method according to claim 10 , wherein the catalyst is prepared by a method comprising attaching the metal component to the carrier, wherein the carrier further comprises a sulfate ion.

15. The method according to claim 14 , wherein the sulfate ion content in the carrier is 0.01% by mass to 10% by mass of the mass of the carrier.

16. The method according to claim 14 , wherein the sulfate ion content in the catalyst is 0.01% by mass to 10% by mass of the mass of the catalyst.

17. The method according to claim 10 , wherein the method provides a molar ratio of a defunctionalized by-product to the corresponding alcohol of less than 0.060.

18. The method according to claim 17 , wherein the molar ratio of the defunctionalized by-product to the corresponding alcohol is from 0.004 to 0.039.

Assignees

• Mitsubishi Chem Corp

Inventors

• Matsuo Takeshi
• Yoshikawa Yumiko
• Aoshima Takayuki

Classifications

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• B01J23/36 Primary

  Rhenium · CPC title

• B01J21/063

  Titanium; Oxides or hydroxides thereof · CPC title

• B01J21/066

  Zirconium or hafnium; Oxides or hydroxides thereof · CPC title

• B01J23/8896

  Rhenium · CPC title