Hydrate formation promoter and use thereof in methane storage

Patent metadata

Field	Value
Publication number	US-11345869-B2
Application number	US-201916613127-A
Country	US
Kind code	B2
Filing date	Mar 26, 2019
Priority date	Dec 29, 2018
Publication date	May 31, 2022
Grant date	May 31, 2022

Abstract

A hydrate formation promoter and the use thereof in methane storage. The hydrate formation promoter is a mixed aqueous solution including cyclopentane, sodium dodecyl sulfate and water, wherein a volume fraction of the cyclopentane is 5% to 23.4% and a mass fraction of the sodium dodecyl sulfate is 0.01% to 0.08%. The hydrate formation promoter can realize effective and rapid formation of methane hydrate at approximate room temperature (25° C.), and can remain stable at higher temperatures.

First claim

What is claimed is:

1. A method for methane storage using a hydrate formation promoter, comprising adding the hydrate formation promoter into a reaction vessel, introducing methane to the reaction vessel at a temperature of 1° C.-25° C. and a pressure of 0-30 MPa to cause a hydrate formation reaction to occur to form methane hydrate and dissociating the methane hydrate in a methane hydrate dissociation device;
wherein the hydrate formation promoter is a mixed aqueous solution comprising cyclopentane, sodium dodecyl sulfate and water, wherein a volume fraction of the cyclopentane is 5% to 23.4% based on a total volume of the mixed aqueous solution, and a mass fraction of the sodium dodecyl sulfate is 0.01% to 0.08% based on a total mass of the mixed aqueous solution; and
wherein the methane hydrate dissociation device comprises a methane hydrate storage tank, a supersonic separation unit for separating the water, the cyclopentane and the methane, and a cyclopentane recovery tank;
the methane hydrate storage tank, the supersonic separation unit, and the cyclopentane recovery tank are connected in series;
dissociated methane in the methane hydrate storage tank is passed through the supersonic separation unit, wherein the water and the cyclopentane are condensed into a plurality of liquids and flow into the cyclopentane recovery tank for recycling, and methane gas is discharged; and
a cold energy is generated during the step of dissociating the methane hydrate, and the cold energy is applied to the supersonic separation unit in order to reduce an energy consumption.

2. The method of claim 1 , wherein the temperature is 10° C.-15° C. and the pressure is 3-5 MPa.

3. The method of claim 1 , wherein an amphiphilic polyurethane sponge material is used as a carrier of the hydrate formation promoter, wherein the amphiphilic polyurethane sponge material adsorbs the hydrate formation promoter.

Assignees

• Guangzhou Inst Energy Conversion Cas

Inventors

• Li Xiaosen
• Yu Yisong
• Chen Zhaoyang

Classifications

• C10L3/108 Primary

  Production of gas hydrates · CPC title

• C10L3/10

  Working-up natural gas or synthetic natural gas · CPC title

• B01D2257/7025

  Methane · CPC title

• C10L2290/06

  Heat exchange, direct or indirect · CPC title

• C10L2290/10

  Recycling of a stream within the process or apparatus to reuse elsewhere therein · CPC title