Rubber composition and transmission belt using same

Patent metadata

Field	Value
Publication number	US-11345805-B2
Application number	US-201916358550-A
Country	US
Kind code	B2
Filing date	Mar 19, 2019
Priority date	Sep 20, 2016
Publication date	May 31, 2022
Grant date	May 31, 2022

Abstract

A rubber composition contains a rubber component, polyparaphenylene terephthalamide short fibers, silica, and carbon black. The content of the silica is larger than the content of the carbon black.

First claim

What is claimed is:

1. A rubber composition comprising:
a rubber component, polyparaphenylene terephthalamide short fibers, silica, and carbon black,
a content of the polyparaphenylene terephthalamide short fibers with respect to 100 parts by mass of the rubber component is 10 parts by mass or more and 35 parts by mass or less,
a content of the silica with respect to 100 parts by mass of the rubber component is 40 parts by mass or more and 50 parts by mass or less,
a content of the carbon black with respect to 100 parts by mass of the rubber component is 15 parts by mass or more and 25 parts by mass or less, and
the content of the silica is larger than the content of the carbon black such that the ratio of the content of the silica to the content of the carbon black is 2.0 or more and 3.0 or less.

2. The rubber composition of claim 1 , wherein
a main part of the rubber component is ethylene-α-olefin elastomer, chloroprene rubber, chlorosulfonated polyethylene rubber, or hydrogenated acrylonitrile-butadiene rubber.

3. The rubber composition of claim 1 , wherein
the content of the polyparaphenylene terephthalamide short fibers with respect to 100 parts by mass of the rubber component is 20 parts by mass or less.

4. The rubber composition of claim 1 , wherein
a sum of the content of the silica and the content of the carbon black with respect to 100 parts by mass of the rubber component is 45 parts by mass or more and 70 parts by mass or less.

5. The rubber composition of claim 1 , wherein
a sum of the content of the polyparaphenylene terephthal amide short fibers and the content of the silica with respect to 100 parts by mass of the rubber component is 50 parts by mass or more and 60 parts by mass or less.

6. The rubber composition of claim 1 , wherein
a ratio of the content of the polyparaphenylene terephthalamide short fibers to the content of the silica is 0.10 or more and 0.40 or less.

7. The rubber composition of claim 1 , wherein
a sum of the content of the polyparaphenylene terephthalamide short fibers and the content of the carbon black with respect to 100 parts by mass of the rubber component is 18 parts by mass or more and 50 parts by mass or less.

8. The rubber composition of claim 1 , wherein
a ratio of the content of the polyparaphenylene terephthal amide short fibers to the content of the carbon black is 0.30 or more and 0.70 or less.

9. The rubber composition of claim 1 , wherein
the polyparaphenylene terephthal amide short fibers are fibrillated in the rubber composition.

10. The rubber composition of claim 1 , wherein
the content of the polyparaphenylene terephthalamide short fibers with respect to 100 parts by mass of the rubber component is about 10 parts by mass.

11. The rubber composition of claim 10 , wherein the silica is wet precipitated silica.

12. The rubber composition of claim 10 , wherein the silica includes specific surface area BET of from about 150 m 2 /g to about 200 m 2 /g.

13. The rubber composition of claim 10 , further comprising:
a content of softener with respect to 100 parts by mass of the rubber component is 5 parts by mass or more and 15 parts by mass or less;
a content of processing aid with respect to 100 parts by mass of the rubber component is 0.5 parts by mass or more and 1.5 parts by mass or less;
a content of vulcanization accelerator aid with respect to 100 parts by mass of the rubber component is 3 parts by mass or more and 7 parts by mass or less;
a content of vulcanization accelerator with respect to 100 parts by mass of the rubber component is 2 parts by mass or more and 6 parts by mass or less; and
a content of co-crosslinking agent with respect to 100 parts by mass of the rubber component is 4 parts by mass or more and 8 parts by mass or less.

14. The rubber composition of claim 13 , wherein:
the softener is a mineral oil, vegetable oil, or petroleum oil;
the processing aid is stearic acid, polyethylene wax, or a metal salt of a fatty acid;
the vulcanization accelerator aid is a metal oxide, metal carbonate, or a fatty acid;
the vulcanization accelerator is a sulfenamide, thiuram, or dithiocarbamate; and
the co-crosslinking agent is a bismaleimide, triallyl isocyanurate, 1,2-polybutadiene, unsaturated carboxylic acid metal salt, oxime, guanidine, or trimethylolpropane trimethacrylate.

15. The rubber composition of claim 1 , wherein the silica is wet precipitated silica.

16. The rubber composition of claim 1 , wherein the silica includes specific surface area BET of from about 150 m 2 /g to about 200 m 2 /g.

17. The rubber composition of claim 1 , further comprising:
a content of softener with respect to 100 parts by mass of the rubber component is 5 parts by mass or more and 15 parts by mass or less;
a content of processing aid with respect to 100 parts by mass of the rubber component is 0.5 parts by mass or more and 1.5 parts by mass or less;
a content of vulcanization accelerator aid with respect to 100 parts by mass of the rubber component is 3 parts by mass or more and 7 parts by mass or less;
a content of vulcanization accelerator with respect to 100 parts by mass of the rubber component is 2 parts by mass or more and 6 parts by mass or less; and
a content of co-crosslinking agent with respect to 100 parts by mass of the rubber component is 4 parts by mass or more and 8 parts by mass or less.

18. The rubber composition of claim 17 , wherein:
the softener is a mineral oil, vegetable oil, or petroleum oil;
the processing aid is stearic acid, polyethylene wax, or a metal salt of a fatty acid;
the vulcanization accelerator aid is a metal oxide, metal carbonate, or a fatty acid;
the vulcanization accelerator is a sulfenamide, thiuram, or dithiocarbamate; and
the co-crosslinking agent is a bismaleimide, triallyl isocyanurate, 1,2-polybutadiene, unsaturated carboxylic acid metal salt, oxime, guanidine, or trimethylolpropane trimethacrylate.

19. The rubber composition of claim 1 , further comprising a ratio of a storage normal modulus at 100° C. in a grain direction to a storage normal modulus at 100° C. in a cross-grain direction which is greater than a corresponding ratio in a rubber composition comprising aramid short fibers other than the polyparaphenylene terephthalamide short fibers.

20. A power transmission belt including a belt body at least a portion of which is made of the rubber composition of claim 1 .

Assignees

• Bando Chemical Ind

Inventors

• Matsuda Hisashi

Classifications

• C08K3/36

  Silica · CPC title

• F16G5/08

  with textile reinforcement · CPC title

• F16G5/20

  with a contact surface of special shape, e.g. toothed · CPC title

• C08L23/16 Primary

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

• F16G1/10

  with textile reinforcement · CPC title