Liquid bicontinuous stabilized assemblies by interfacial jamming of nanoparticles

Patent metadata

Field	Value
Publication number	US-11345786-B2
Application number	US-201916428536-A
Country	US
Kind code	B2
Filing date	May 31, 2019
Priority date	Jun 12, 2018
Publication date	May 31, 2022
Grant date	May 31, 2022

Abstract

A method for preparing a stabilized assembly includes combining a first liquid phase including nanoparticles and a second, immiscible liquid phase, dissolving in the second phase a first end-functionalized polymer having a first molecular weight, and a second end-functionalized polymer having a second molecular weight, wherein the second molecular weight is greater than the first molecular weight, applying a shearing external deformation field to increase the surface area of the first phase to create a new interface, wherein the nanoparticle surfactants form a disordered, jammed assembly at the new interface, and releasing the shearing external deformation field. The polymer and the nanoparticles can interact at an interface through ligand interactions to form nanoparticle surfactants and upon releasing the external deformation field the jammed assembly at the new interface traps the first phase in a deformed state having the first liquid phase and the second liquid phase as interpenetrating domains.

First claim

The invention claimed is:

1. A method for preparing a stabilized assembly, the method comprising,
combining a first liquid phase comprising water and a second liquid organic phase, wherein
the first phase and the second phase are immiscible,
the first phase comprises nanoparticles,
the second phase comprises a first end-functionalized polymer having a first molecular weight and a second end-functionalized polymer having a second molecular weight, wherein the first and second end-functionalized polymers can be the same or different, and wherein the first molecular weight is 500 to 1,500 grams per mole and the second molecular weight is 2,000 to 4,000 grams per mole, and
the first and second end-functionalized polymers and the nanoparticles can interact at an interface through ligand interactions to form nanoparticle surfactants;

applying a shearing external deformation field to create a new interface between the first liquid phase and the second liquid phase, wherein the nanoparticle surfactants form a disordered, jammed assembly at the new interface; and
releasing the shearing external deformation field;
wherein upon releasing the external deformation field the jammed assembly at the new interface traps the first liquid phase and the second liquid phase in a deformed state comprising extended interpenetrating domains of the first liquid phase and the second liquid phase as a bijel.

2. The method of claim 1 , wherein applying the shearing external deformation field is by vortex mixing.

3. The method of claim 1 , wherein the nanoparticles are metal, metal oxide, dielectric, semiconducting, inorganic, organic, hybrid structures, or a combination thereof, and wherein the nanoparticles have one or more dimensions of less than or equal to 100 nanometers.

4. The method of claim 1 , wherein the nanoparticles comprise carboxylated polystyrene, carboxylated-silica nanoparticles, or a combination thereof.

5. The method of claim 1 , wherein the first and the second end-functionalized polymer each comprise an amine-functionalized polystyrene, an amine-functionalized polydimethylsiloxane, or a combination thereof.

6. The method of claim 1 , wherein the new interface is a continuous interface.

7. The method of claim 1 , wherein
the nanoparticles comprise carboxylated polystyrene;
the first and second end-functionalized polymer each comprise amine-functionalized polydimethylsiloxane;
the first molecular weight is 750 to 1,500 grams per mole; and
the second molecular weight is 2,500 to 3,500 grams per mole.

8. The method of claim 1 , wherein
the nanoparticles comprise carboxylated silica;
the first and second end-functionalized polymer each comprise amine-functionalized polystyrene;
the first molecular weight is 750 to 1,500 grams per mole; and
the second molecular weight is 2,500 to 3,500 grams per mole.

9. A stabilized assembly prepared by the method of claim 1 .

10. A liquid bicontinuous stabilized assembly, comprising
a first continuous liquid phase comprising water and a second continuous liquid organic phase, wherein the second liquid phase is immiscible with the first phase; and
nanoparticle surfactants assembled at a continuous interface of the first and second continuous liquid phases;
wherein the nanoparticle surfactants comprise nanoparticles, a first end-functionalized polymer having a first molecular weight, and a second end-functionalized polymer having a second molecular weight, wherein the first and second end-functionalized polymers can be the same or different, and wherein the first molecular weight is 500 to 1,500 grams per mole and the second molecular weight is 2,000 to 4,000 grams per mole, and wherein the nanoparticles can interact with the first and second end-functionalized polymers through ligand interactions;
wherein the liquid bicontinuous stabilized assembly is stabilized by a disordered, jammed layer of the nanoparticle surfactants at the continuous interface of the first and second continuous liquid phases; and
wherein the liquid bicontinuous stabilized assembly comprises extended interpenetrating domains of the first continuous liquid phase and the second continuous liquid phase as a bijel.

11. The stabilized assembly of claim 10 , wherein the ligand interactions comprise high affinity or low affinity site-specific interactions, non-bonded electrostatic interactions, ionic bonds, hydrogen bonds, coordination bonds, or a combination thereof.

12. The stabilized assembly of claim 10 , wherein the nanoparticles are metal, metal oxide, dielectric, semiconducting, inorganic, organic, hybrid structures, or a combination thereof, and wherein the nanoparticles have one or more dimensions of less than or equal to 100 nanometers.

13. The stabilized assembly of claim 10 , wherein the nanoparticles comprise carboxylated polystyrene nanoparticles, carboxylated-silica nanoparticles, or a combination thereof.

14. The stabilized assembly of claim 10 , wherein the first and the second end-functionalized polymer each comprise an amine-functionalized polystyrene, an amine-functionalized polydimethylsiloxane, or a combination thereof.

15. The stabilized assembly of claim 10 , wherein
the nanoparticles comprise carboxylated polystyrene;
the first and second end-functionalized polymer each comprise amine-functionalized polydimethylsiloxane;
the first molecular weight is 750 to 1,500 grams per mole; and
the second molecular weight is 2,500 to 3,500 grams per mole.

16. The stabilized assembly of claim 10 , wherein
the nanoparticles comprise carboxylated silica;
the first and second end-functionalized polymer each comprise amine-functionalized polystyrene;
the first molecular weight is 750 to 1,500 grams per mole; and
the second molecular weight is 2,500 to 3,500 grams per mole.

Assignees

• Univ Massachusetts
• Univ California

Inventors

• Huang Caili
• Forth Joseph William
• Helms Brett Anthony
• Russell Thomas P

Classifications

• C08J2483/08

  containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen · CPC title

• C08F8/30

  Introducing nitrogen atoms or nitrogen-containing groups · CPC title

• B01F23/4105

  Methods of emulsifying · CPC title

• C08G77/26

  nitrogen-containing groups · CPC title

• C08F212/08

  Styrene · CPC title