Porous film and method for producing same

Patent metadata

Field	Value
Publication number	US-11344848-B2
Application number	US-202016936715-A
Country	US
Kind code	B2
Filing date	Jul 23, 2020
Priority date	Sep 4, 2015
Publication date	May 31, 2022
Grant date	May 31, 2022

Abstract

Provided are a porous film having excellent surface smoothness and a method for producing the same. The surface roughness of a porous film of polyvinylidene fluoride, polyethersulfone, polyimide and/or polyamide-imide is Ra 30,000 Å or less. The opening diameter of the porous film is preferably from 100 nm to 5000 nm. The method for producing a porous film preferably includes a step for kneading a varnish containing fine particles and at least one resin selected from the group consisting of polyvinylidene fluoride, polyether sulfone, polyamic acid, polyimide, polyamide-imide precursor, and polyamide-imide. The varnish preferably has a viscosity at 25° C. of 0.1-3 Pa·s, a solids fraction concentration of 10-50 mass %, and a fine particle average particle size of 10-5000 nm.

First claim

The invention claimed is:

1. A single layer porous film in a laminated body comprising the single layer porous film and a support or an electrode,
wherein the single layer porous film consists of:
a film selected from the group consisting of a polyvinylidene fluoride film, a polyethersulfone film, a polyimide film and a polyamide-imide film,
wherein the single layer porous film has a front surface and a rear surface, wherein the front and rear surfaces communicate with each other,
each of the front and rear surfaces has an opening portion, and the opening portions have a uniform diameter on the front and rear surfaces, and
the single layer porous film uniformly has continuous pores in the film, the continuous pores being formed of spherical pores that communicate with each other,
wherein the single layer porous film has a surface roughness Ra of 5000 Å or less, and
wherein the single layer porous film is laminated on the support or the electrode such that the surface roughness Ra of 5000 Å or less adheres the single layer porous film to the support or the electrode.

2. The single layer porous film in the laminated body according to claim 1 , wherein the opening portions have a diameter of 10 nm to 5000 nm.

3. The single layer porous film in the laminated body according to claim 1 , wherein
the opening portions have a diameter of 10 nm to 5000 nm, and
the single layer porous film has no waviness, wherein the waviness is defined as a recess portion that is deeper than a recess portion formed by the opening portions.

4. The single layer porous film in the laminated body according to claim 1 , wherein the surface roughness Ra is measured by spreading the single layer porous film on a substrate, heating the single layer porous film, and measuring the surface roughness of a surface of the single layer porous film opposite to a surface facing the substrate.

5. A film comprising a single layer porous film and a support,
wherein the single layer porous film consists of:
a film selected from the group consisting of a polyvinylidene fluoride film, a polyethersulfone film, a polyimide film and a polyamide-imide film,
wherein the single layer porous film has a front surface and a rear surface, wherein the front and rear surfaces communicate with each other,
each of the front and rear surfaces has an opening portion, and the opening portions have a uniform diameter on the front and rear surfaces, and
the single layer porous film uniformly has continuous pores in the film, the continuous pores being formed of spherical pores that communicate with each other,
wherein the single layer porous film has a surface roughness Ra of 5000 Å or less; and
wherein the single layer porous film is laminated on the support such that the surface roughness Ra of 5000 Å or less adheres the single layer porous film to the support.

6. The film according to claim 5 , wherein the opening portions have a diameter of 10 nm to 5000 nm.

7. The film according to claim 5 , wherein
the opening portions have a diameter of 10 nm to 5000 nm, and
the single layer porous film has no waviness, wherein the waviness is defined as a recess portion that is deeper than a recess portion formed by the opening portions.

8. The film according to claim 5 , wherein the surface roughness Ra is measured by spreading the single layer porous film on a substrate, heating the single layer porous film, and measuring the surface roughness of a surface of the single layer porous film opposite to a surface facing the substrate.

9. A battery comprising a separator,
wherein the separator comprises a single layer porous film and an electrode,
wherein the single layer porous film consists of:
a film selected from the group consisting of a polyvinylidene fluoride film, a polyethersulfone film, a polyimide film and a polyamide-imide film,
wherein the single layer porous film has a front surface and a rear surface, wherein the front and rear surfaces communicate with each other,
each of the front and rear surfaces has an opening portion, and the opening portions have a uniform diameter on the front and rear surfaces, and
the single layer porous film uniformly has continuous pores in the film, the continuous pores being formed of spherical pores that communicate with each other,
wherein the single layer porous film has a surface roughness Ra of 5000 Å or less; and
wherein the single layer porous film is laminated on the electrode such that the surface roughness Ra of 5000 Å or less adheres the single layer porous film to the electrode.

10. The battery according to claim 9 , wherein the opening portions have a diameter of 10 nm to 5000 nm.

11. The battery according to claim 9 , wherein
the opening portions have a diameter of 10 nm to 5000 nm, and
the single layer porous film has no waviness, wherein the waviness is defined as a recess portion that is deeper than a recess portion formed by the opening portions.

12. The battery according to claim 9 , wherein the surface roughness Ra is measured by spreading the single layer porous film on a substrate, heating the single layer porous film, and measuring the surface roughness of a surface of the single layer porous film opposite to a surface facing the substrate.

13. The single layer porous film in the laminated body according to claim 1 , wherein the opening portions have a diameter of 2000 nm to 5000 nm.

14. The film according to claim 5 , wherein the opening portions have a diameter of 2000 nm to 5000 nm.

15. The single layer porous film in the laminated body according to claim 1 , wherein the surface roughness Ra is 3069 Å to 5000 Å.

16. The film according to claim 5 , wherein the surface roughness Ra is 3069 Å to 5000 Å.

Assignees

• Tokyo Ohka Kogyo Co Ltd

Inventors

• Sugawara Tsukasa

Classifications

• H01M50/403

  Manufacturing processes of separators, membranes or diaphragms · CPC title

• H01M50/489

  Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties · CPC title

• H01M50/414

  Synthetic resins, e.g. thermoplastics or thermosetting resins · CPC title

• C08L81/06

  Polysulfones; Polyethersulfones · CPC title

• C08J2381/06

  Polysulfones; Polyethersulfones · CPC title