AZEOTROPE OR AZEOTROPE-LIKE COMPOSITIONS OF TRIFLUOROIDOMETHANE (CF3I) AND 1,1,1,3,3,3-HEXAFLUOROPROPANE (HFC-236fa)
US-2020114188-A1 · Apr 16, 2020 · US
US11344761B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11344761-B2 |
| Application number | US-201916571930-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 16, 2019 |
| Priority date | Oct 15, 2018 |
| Publication date | May 31, 2022 |
| Grant date | May 31, 2022 |
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The present disclosure provides azeotrope or azeotrope-like compositions including trifluoroiodomethane (CF 3 I) and 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca), and a method of forming an azeotrope or azeotrope-like composition comprising the step of combining 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and trifluoroiodomethane (CF 3 I) to form an azeotrope or azeotrope-like comprising 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and trifluoroiodomethane (CF 3 I) having a boiling point of about −24.46° C.±0.30° C. at a pressure of about 14.40 psia±0.30 psia.
Opening claim text (preview).
What is claimed is: 1. A composition comprising an azeotrope composition consisting essentially of from about 13 wt. % to about 42 wt. % 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and from about 58 wt. % to about 87 wt. % trifluoroiodomethane (CF 3 I), wherein the azeotrope composition has a boiling point of about −24.46° C.±0.30° C. at a pressure of about 14.40 psia±0.30 psia. 2. The composition of claim 1 , wherein the azeotrope composition consists essentially from about 18 wt. % to about 37 wt. % 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and from about 63 wt. % to about 82 wt. % trifluoroiodomethane (CF 3 I). 3. The composition of claim 1 , wherein the azeotrope composition consists essentially of from about 23 wt. % to about 24 wt. % 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and from about 76 wt. % to about 77 wt. % trifluoroiodomethane (CF 3 I). 4. The composition of claim 1 , wherein the azeotrope composition consists essentially of about 23.74 wt. % 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and about 76.26 wt. % trifluoroiodomethane (CF 3 I). 5. The composition of claim 1 , wherein the azeotrope composition consists of from about 13 wt. % to about 42 wt. % 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and from about 58 wt. % to about 87 wt. % trifluoroiodomethane (CF 3 I). 6. The composition of claim 1 , wherein the azeotrope composition consists of from about 18 wt. % to about 37 wt. % 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and from about 63 wt. % to about 82 wt. % trifluoroiodomethane (CF 3 I). 7. The composition of claim 1 , wherein the azeotrope composition consists of about 23.74 wt. % 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and about 76.26 wt. % trifluoroiodomethane (CF 3 I). 8. A method of forming an azeotrope composition comprising the step of combining 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and trifluoroiodomethane (CF 3 I) to form an azeotrope composition consisting essentially of from about 13 wt. % to about 42 wt. % 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and from about 58 wt. % to about 87 wt. % trifluoroiodomethane (CF 3 I) having a boiling point of about −24.46° C.±0.30° C. at a pressure of about 14.40 psia±0.30 psia. 9. The method of claim 8 , wherein the combining step comprises combining from about 18 wt. % to about 37 wt. % 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and from about 63 wt. % to about 82 wt. % trifluoroiodomethane (CF 3 I). 10. The method of claim 9 , wherein the combining step comprises combining about 23.74 wt. % 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and about 76.26 wt. % trifluoroiodomethane (CF 3 I). 11. A method of separating 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and trifluoroiodomethane (CF 3 I) from a primary composition comprising 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca), trifluoroiodomethane (CF 3 I) and at least one impurity, including the steps of: forming, within the primary composition, a secondary composition which is an azeotrope composition consisting essentially of from about 13 wt. % to about 42 wt. % 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca) and from about 58 wt. % to about 87 wt. % trifluoroiodomethane (CF 3 I) having a boiling point of about −24.46° C.±0.30° C. at a pressure of about 14.40 psia±0.30 psia; and separating the secondary composition from the primary composition and the at least one impurity.
Perhalogenated saturated hydrocarbons, e.g. F3C-CF3 · CPC title
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The mixture being azeotropic · CPC title
All components of a mixture being fluoro compounds · CPC title
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