Conductive fiber with polythiophene coating

Patent metadata

Field	Value
Publication number	US-11344241-B2
Application number	US-201816646287-A
Country	US
Kind code	B2
Filing date	Sep 13, 2018
Priority date	Sep 13, 2017
Publication date	May 31, 2022
Grant date	May 31, 2022

Abstract

This document discloses an electrically conductive fiber coated with polythiophene and a carbon material. Also disclosed is an article of manufacture incorporating the conductive fiber.

First claim

The invention claimed is:

1. A conductive fiber comprising a fiber core and a coating thereon, wherein the coating comprises a polythiophene and a conductive carbon material, wherein the polythiophene is regioregular poly(3-hexylthiophene), further wherein the ratio between the regioregular poly(3-hexylthiophene) and the carbon material is selected so that the conductive fiber has an electrical resistance of less than about 0.8 kohm/cm.

2. The conductive fiber of claim 1 , wherein the fiber core consists of a single filament fiber thread.

3. The conductive fiber of claim 1 , wherein the fiber core comprises a nonconductive synthetic or natural polymer.

4. The conductive fiber of claim 1 , wherein the fiber core consists essentially of cotton, nylon, silk, hemp, jute, flax, ramie, sisal, wool, or any combination thereof.

5. The conductive fiber of claim 1 , wherein the fiber core comprises a polymer selected from polylactic acids, polyglycolic acids, polylactide-co-glycolide copolymers, polytrimethylene carbonate, poly-(ε)-caprolactone, poly-dioxanone, polyhydroxyalkanoates, polyphosphasenes, polypropylene fumarates, polyanhydrides, polyorthoesters, polyimides, polyurethanes, polyurethaneureas, perfluoroalkoxy polymers, florinated ethylene/propylene copolymers, polyanhydride esters, polysaccharides, polyethylene-lactone copolymers, polyethylene-polyorthoester copolymers, hydrophilic vinyl polymers, phosphoryl cholines, hydroxamates, vinyl furanones, collagen, elastin, keratin, fibrin, and blends, copolymers, and homopolymers thereof.

6. The conductive fiber of claim 1 , wherein the conductive carbon material is selected from the group consisting of graphene, multi-wall carbon nanotubes, single-wall carbon nanotubes, carbon black, graphite powder, graphene oxide, fullerenes, and any combination thereof.

7. The conductive fiber of claim 1 , wherein the conductive carbon material consists essentially of single-wall carbon nanotubes.

8. The conductive fiber of claim 1 , wherein the fiber core comprises one or more second groups selected from the group consisting of hydroxyl, amine, amide carboxylic, thiol, perfluoroalkyl, phosphonic acid and sulfonic acid.

9. The conductive fiber of claim 1 , wherein the coating further comprises one or more conjugated polymers selected from the group consisting of poly(pyrrole), poly(aniline), poly(acetylene), poly(p-phenylene vinylene) (PPV), poly(3,4-ethylene dioxythiophene)-poly(styrene sulfonate) (PEDOT-PSS).

10. The conductive fiber of claim 1 , wherein the coating consists essentially of the regioregular poly(3-hexylthiophene) and the conductive carbon material.

11. The conductive fiber of claim 1 , having an average diameter ranging from about 1 to about 10,000 microns.

12. The conductive fiber of claim 1 , which is biocompatible and capable of delivering changes in electrical pulse and current.

13. An article of manufacture comprising the conductive fiber of claim 1 .

14. The article of manufacture of claim 13 , which is an implantable medical device.

15. The article of manufacture of claim 13 , which is an electrode.

16. The conductive fiber of claim 1 , wherein the polythiophene and the conductive carbon material are admixed with each other in the coating.

Assignees

• Allegheny Singer Res Institute
• Univ Oklahoma State

Inventors

• Averick Saadyah
• Whiting Donald M
• Richter Bertram
• Cheng Boyle
• Nelson Toby Larue

Classifications

• A61B5/268

  containing conductive polymers, e.g. PEDOT:PSS polymers · CPC title

• A61B5/265

  containing silver or silver chloride · CPC title

• A61B5/28

  for electrocardiography [ECG] · CPC title

• A61B5/254

  by clips · CPC title

• A61B5/263

  characterised by the electrode materials · CPC title