Method and installation for determining an improved mineralogical composition of a rock sample

Patent metadata

Field	Value
Publication number	US-11340207-B2
Application number	US-201816103254-A
Country	US
Kind code	B2
Filing date	Aug 14, 2018
Priority date	Aug 16, 2017
Publication date	May 24, 2022
Grant date	May 24, 2022

Abstract

A method for determining a mineralogical composition of a geological formation sample includes measuring a mineralogical composition of the sample and measuring an elemental composition of the sample. The mineralogical composition is processed to compute a predicted elemental composition of the sample based on known elemental compositions of predetermined minerals. The measured mineralogical composition is corrected to obtain a corrected mineralogical composition which is in turn processed to compute a corresponding corrected predicted elemental composition of the sample. The measured elemental composition is compared with the predicted elemental compositions to obtain error indicators. The error indicators are compared and evaluated to selected and output one of the measured or corrected measured mineralogical compositions.

First claim

The invention claimed is:

1. A method for determining a mineralogical composition of geological formation sample, the method comprising:
(a) acquiring a rock sample from a geological formation;
(b) measuring a mineralogical composition of the sample using a first measurement, the mineralogical composition being indicative of relative amounts of a set of predetermined minerals in the sample;
(c) measuring an elemental composition of the sample using a second measurement, the elemental composition being indicative of relative amounts of predetermined chemical elements in the sample;
(d) processing said measured mineralogical composition to compute a predicted elemental composition of the sample, said processing based on known elemental compositions of each of the predetermined minerals;
(e) comparing said measured elemental composition and the predicted elemental composition to determine a first error indicator;
(f) correcting the measured mineralogical composition to obtain a corrected mineralogical composition of the sample and processing the corrected mineralogical composition to compute a corresponding corrected predicted elemental composition of the sample;
(g) comparing said measured elemental composition and the corrected predicted elemental composition to determine a second error indicator;
(h) comparing the first error indicator and the second error indicator; and
(i) outputting the measured mineralogical composition when the second error indicator is greater than the first error indicator in (h) or the corrected mineralogical composition when the second error indicator is less than the first error indicator in (h).

2. The method according to claim 1 , wherein the rock sample is a drill cutting collected at a shale shaker of a surface installation of a rig.

3. The method according to claim 1 , wherein the second measurement comprises an X-Ray Diffraction Fluorescence (XRF) measurement.

4. The method according to claim 1 , wherein the first measurement comprises a Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) measurement or an X-Ray Diffraction (XRD) measurement.

5. The method of claim 1 , wherein said correcting in (f) comprises at least one of the following: (i) adjusting an amount of at least one mineral within a family of minerals while a total amount of minerals in the family remains constant, (ii) correcting a total amount of at least a family of minerals within a system including at least two families of minerals while relative amounts of each individual mineral with the family remains constant, or (iii) adding an amount of at least one additional mineral distinct from the predetermined minerals while relative amounts of each of the predetermined minerals within the set remains constant.

6. The method according to claim 5 , wherein the family of minerals is selected from at least one of the following three types of mineral families: a Carbonate family comprising calcite and/or dolomite, a Quartz and Feldspar family, comprising quartz, Na-Feldspar and/or K-Feldspar, or a Clay/Mica family comprising Illite, chlorite, kaolinite and/or smectite.

7. The method according to claim 6 , wherein said correcting in (f) comprises said adjusting in (i) for each of the Carbonate family, the Quartz and Feldspar family, and/or the Clays/Micas family.

8. The method according to claim 6 , wherein said correcting in (f) comprises said correcting in (ii) for each of said systems of two families selected from the Carbonate family, the Quartz and Feldspar family, and/or the Clay/Mica family.

9. The method according to claim 8 , wherein said correcting in (f) comprises said correcting in (ii) after said adjusting in (i) has been performed for each of the families.

10. The method according to claim 9 wherein said correcting in (f) further comprises said adding in (iii) after said correcting in (ii), wherein said adding is performed for each of pyrite, anhydrite, and siderite.

11. The method according to claim 5 , wherein the additional mineral comprises at least one of pyrite, anhydrite, or siderite.

12. The method of claim 1 , wherein:
(f) further comprises iteratively correcting the measured mineralogical composition to obtain other corrected mineralogical compositions of the sample and processing the other corrected mineralogical compositions to compute corresponding other predicted elemental compositions of the sample;
(g) further comprises comparing the other predicted elemental compositions with said measured elemental composition to determine corresponding other error indicators;
(h) further comprises comparing the other error indicators; and
(i) further comprises outputting one of the other corrected mineralogical compositions which has an error indicator having a lowest value.

13. The method according to claim 12 , wherein said iteratively correcting is performed until a convergence of said other corrected mineralogical compositions is achieved.

14. The method according to claim 12 , wherein said iteratively correcting comprises adding or removing a predetermined amount of a mineral to a previously corrected amount of the mineral, and wherein the previously corrected amount is selected when a value of the error indicator reaches a local extremum for the previously corrected amount.

15. A method for determining a mineralogical composition of geological formation sample, the method comprising:
(a) acquiring a rock sample from a geological formation;
(b) measuring a mineralogical composition of the sample using a first measurement, the mineralogical composition being indicative of relative amounts of a set of predetermined minerals in the sample;
(c) measuring an elemental composition of the sample using a second measurement, the elemental composition being indicative of relative amounts of predetermined chemical elements in the sample;
(d) processing said measured mineralogical composition to compute a predicted elemental composition of the sample, said processing based on known elemental compositions of each of the predetermined minerals;
(e) iteratively correcting the measured mineralogical composition of the sample to obtain corrected mineralogical compositions and corrected predicted elemental compositions of the sample;
(f) comparing the corrected predicted elemental compositions of the sample and said measured elemental composition of the sample to compute corresponding error indicators; and
(g) evaluating the error indicators to select and output one of the corrected mineralogical compositions.

16. The method of claim 15 , wherein:
said iteratively correcting in (e) comprises at least one of the following: (i) adjusting an amount of at least one mineral within a family of minerals while a total amount of minerals in the family remains constant, (ii) correcting a total amount of at least a family of minerals within a system including at least two families of minerals while relative amounts of each individual mineral with the family remains constant, or (iii) adding an amount of at least one additional mineral distinct from the predetermined minerals while relative amounts of each of the predetermined minerals within the set remains constant.

17. The method of claim 16 , wherein said iteratively correcting in (e) comprises first said adjusting in (i), followed by said correcting in (ii), and then said adding in (iii).

18. The method of claim 17 , wherein said families of minerals are selected from at least one of the following three types of mineral families: a Carbonate family comprising calcite and/or dolomite, a

Assignees

• Geoservices Equipements
• Schlumberger Technology Corp

Inventors

• Rocher Yohann
• Ammar Mahdi

Classifications

• G01N2223/616

  earth materials · CPC title

• G01N23/223

  by irradiating the sample with X-rays or gamma-rays and by measuring X-ray fluorescence · CPC title

• G01N2223/076

  X-ray fluorescence · CPC title

• G01N23/2206

  Combination of two or more measurements, at least one measurement being that of secondary emission, e.g. combination of secondary electron [SE] measurement and back-scattered electron [BSE] measurement · CPC title

• G01N2223/306

  computer control · CPC title