Process for forming a yarn comprising bicomponent filaments

Patent metadata

Field	Value
Publication number	US-11339508-B2
Application number	US-202016777986-A
Country	US
Kind code	B2
Filing date	Jan 31, 2020
Priority date	Sep 1, 2016
Publication date	May 24, 2022
Grant date	May 24, 2022

Abstract

A yarn comprising a plurality of bicomponent filaments having a first region comprising a first polymer composition and a second region comprising a second polymer composition, each of the first and second regions being distinct in the bicomponent filaments; each bicomponent filament comprising 5 to 60 weight percent of the first polymer composition and 95 to 40 weight percent of the second polymer composition; wherein the first polymer composition comprises aramid polymer containing 0.5 to 20 weight percent discrete homogeneously dispersed carbon particles and the second polymer composition comprises modacrylic polymer being free of discrete carbon particles; the yarn having a total content of 0.1 to 5 weight percent discrete carbon particles.

First claim

What is claimed is:

1. A process for forming a yarn comprising bicomponent filaments, each of the filaments comprising a distinct sheath of a modacrylic polymer free of discrete carbon particles and a distinct core of an aramid polymer comprising discrete carbon particles homogeneously dispersed therein, with the sheath surrounding the core; the process comprising the steps of:
a) forming a first polymer solution containing aramid polymer in a solvent, the aramid polymer solution further comprising discrete carbon particles, and forming a second polymer solution of modacrylic polymer being free of carbon particles in the same or different solvent;
b) providing a spinneret assembly having separate inlets for the first polymer solution and the second polymer solution and a plurality of exit capillaries for spinning dope filaments;
c) forming a plurality of dope filaments having a sheath of the second polymer solution and a core of the first polymer solution by extruding through the exit capillaries a plurality of conjoined streams of the first and the second solutions into a spin cell, and
d) extracting solvent from the plurality of dope filaments to make a yarn of polymer filaments.

2. The process of claim 1 wherein the step d) of extracting solvent from the plurality of dope filaments to make a yarn includes the steps of:
i) contacting the dope filaments with heated gas in the spin cell to remove solvent from the dope filaments to form reduced solvent filaments;
ii) quenching the reduced solvent filaments with an aqueous liquid to cool the filaments, forming a yarn of polymer filaments; and
iii) further extracting solvent from the yarn of polymer filaments by washing and heating the yarn.

3. The process of claim 1 wherein the second polymer solution composition further comprises at least one masking pigment.

4. The process of claim 1 wherein the aramid polymer is poly(metaphenylene isophthalamide).

5. A process for forming a yarn comprising bicomponent filament having side-by-side structure, each of the filaments comprising particles a distinct first side of an aramid polymer comprising discrete carbon particles homogeneously dispersed therein and a distinct second side of a modacrylic polymer free of discrete carbon particles; the process comprising the steps of:
a) forming a first polymer solution containing aramid polymer in a solvent, the aramid polymer solution further comprising discrete carbon particles, and forming a second polymer solution of modacrylic polymer being free of discrete carbon particles, in the same or different solvent;
b) providing a spinneret assembly having separate inlets for the first polymer solution and the second polymer solution and a plurality of exit capillaries for spinning dope filaments;
c) forming a plurality of dope filaments having a first side of the first polymer solution and a second side of the second polymer solution in a side-by-side orientation by extruding through the exit capillaries a plurality of conjoined streams of the first and the second solutions into a spin cell, and
d) extracting solvent from the plurality of dope filaments to make a yarn of polymer filaments.

6. The process of claim 5 wherein the step d) of extracting solvent from the plurality of dope filaments to make a yarn includes the steps of:
i) contacting the dope filaments with heated gas in the spin cell to remove solvent from the dope filaments to form reduced solvent filaments;
ii) quenching the reduced solvent filaments with an aqueous liquid to cool the filaments, forming a yarn of polymer filaments; and
iii) further extracting solvent from the yarn of polymer filaments by washing and heating the yarn.

7. The process of claim 5 wherein the second polymer solution composition further comprises at least one masking pigment.

8. The process of claim 5 wherein the aramid polymer is poly(metaphenylene isophthalamide).

Assignees

• Dupont Safety & Construction Inc

Inventors

• Andersen Mark William
• Aronson Mark T
• Newton Christopher William
• Steinruck Thomas Wayne
• Wiseman B Lynne
• Zhu Reiyao

Classifications

• D02G3/441 Primary

  Yarns or threads with antistatic, conductive or radiation-shielding properties (electroconductive, anti-static or radiation-shielding filaments D01F1/09, D01F1/106; anti-static fabrics D03D15/533; conducting, insulating or anti-static layers for floor coverings D06N7/0042) · CPC title

• D02G3/047 Primary

  including aramid fibres · CPC title

• D01F6/605

  from aromatic polyamides · CPC title

• B29K2077/00

  Use of {PA, i.e.} polyamides, e.g. polyesteramides {or derivatives thereof}, as moulding material · CPC title

• A41D31/26

  Electrically protective, e.g. preventing static electricity or electric shock · CPC title