Systems and processes integrating fluidized catalytic cracking with metathesis for producing olefins

Patent metadata

Field	Value
Publication number	US-11339332-B2
Application number	US-202016775677-A
Country	US
Kind code	B2
Filing date	Jan 29, 2020
Priority date	Jan 29, 2020
Publication date	May 24, 2022
Grant date	May 24, 2022

Abstract

Processes for producing olefins include introducing a hydrocarbon feed to a high-severity fluidized catalytic cracking system, contacting the hydrocarbon feed with a cracking catalyst under high-severity conditions in the high-severity fluidized catalytic cracking system to produce a cracking reaction effluent comprising butene, and passing at least a portion of the cracking reaction effluent, which includes at least butene, to a metathesis system. The processes further include contacting the portion of the cracking reaction effluent with a metathesis catalyst in the metathesis system, which causes at least a portion of the butene in the cracking C4 effluent to undergo a metathesis reaction to produce a metathesis reaction effluent comprising at least one of ethylene, propene, or both. The processes may further include separating a metathesis C5+ effluent from the metathesis reaction effluent and passing the metathesis C5+ effluent back to the high-severity fluidized catalytic cracking unit.

First claim

What is claimed is:

1. A process for producing olefins, the process comprising:
contacting a hydrocarbon feed with a cracking catalyst under high-severity conditions in a high-severity fluidized catalytic cracking system to produce a cracking reaction effluent comprising at least butenes, wherein the butenes comprises normal butenes and isobutene, where the high-severity conditions comprise a temperature of greater than or equal to 500° C.;
contacting a portion of the cracking reaction effluent with methanol in an MTBE reactor of an isobutene removal unit under reaction conditions sufficient to convert at least a portion of the isobutene in the portion of the cracking reaction effluent to methyl tert-butyl ether to produce an MTBE reactor effluent;
separating the MTBE reactor effluent into at least an MTBE-containing effluent and a metathesis feed, the metathesis feed comprising butene;
contacting the metathesis feed with a metathesis catalyst, where the contacting causes metathesis of at least a portion of the butenes in the metathesis feed to produce a metathesis reaction product comprising at least one of ethylene, propene, butenes, or combinations thereof; and
passing at least a portion of the MTBE-containing effluent back to the high-severity fluidized catalytic cracking system.

2. The process of claim 1 , in which the hydrocarbon feed comprises a naphtha, a gas condensate, or both.

3. The process of claim 1 , comprising:
separating the metathesis reaction product into a metathesis C5+ effluent, a metathesis C4 effluent, a metathesis propene effluent, and a metathesis ethylene effluent; and
after separating the metathesis reaction product, passing at least a portion of the metathesis C4 effluent back into contact with the metathesis catalyst, where contacting the metathesis C4 effluent with the metathesis catalyst causes further metathesis of at least a portion of the butenes in the metathesis C4 effluent to produce the metathesis reaction product.

4. The process of claim 3 , further comprising passing at least a portion of the metathesis ethylene effluent back into contact with the metathesis catalyst.

5. The process of claim 1 , further comprising separating the cracking reaction effluent into a cracking C4 effluent and at least one other effluent stream, where the cracking C4 effluent comprises the at least butenes, and the cracking C4 effluent is the portion of the cracking effluent contacted with methanol in the MTBE reactor.

6. The process of claim 1 , comprising separating the metathesis reaction effluent into a metathesis ethylene effluent, a metathesis propene effluent, a metathesis C4 effluent, and the metathesis C5+ effluent, and passing at least a portion of the metathesis C4 effluent back to the metathesis system or to the isobutene removal unit upstream of the metathesis system.

7. The process of claim 6 , comprising passing at least a portion of the metathesis C4 effluent back to the metathesis system and contacting the at least a portion of the metathesis C4 effluent with the metathesis catalyst, where contacting the at least a portion of the metathesis C4 effluent with the metathesis catalyst causes further metathesis of the butenes in the at least a portion of the metathesis C4 effluent to produce the metathesis reaction product.

8. The process of claim 6 , further comprising passing at least a portion of the metathesis ethylene effluent back to the metathesis system.

9. A process for producing olefins, the process comprising:
introducing a hydrocarbon feed to a high-severity fluidized catalytic cracking system;
contacting the hydrocarbon feed with a cracking catalyst under high-severity conditions in the high-severity fluidized catalytic cracking system to produce a cracking reaction effluent comprising butenes, wherein the butenes comprise normal butenes and isobutene, where the high-severity conditions comprise a temperature of greater than or equal to 500° C., a residence time of less than or equal to 3 seconds, and a weight ratio of the cracking catalyst to hydrocarbon of 5:1;
contacting a portion of the cracking reaction effluent with methanol in an MTBE reactor of an isobutene removal unit under reaction conditions sufficient to convert at least a portion of the isobutene in the portion of the cracking reaction effluent to methyl tert-butyl ether to produce an MTBE reactor effluent;
separating the MTBE reactor effluent into at least an MTBE-containing effluent and a metathesis feed;
passing the metathesis feed to a metathesis system, the at least a portion of the cracking reaction effluent comprising a cracking C4 effluent that includes at least butene;
contacting the metathesis feed with a metathesis catalyst in the metathesis system, where the contacting causes at least a portion of the butenes in the metathesis feed to undergo a metathesis reaction to produce a metathesis reaction effluent comprising at least one of ethylene, propene, or both; and
passing at least a portion of the MTBE-containing effluent back to the high-severity fluidized catalytic cracking system.

10. The process of claim 9 , in which the hydrocarbon feed comprises a naphtha, a gas condensate, or both.

11. The process of claim 9 , further comprising separating the cracking reaction effluent into a cracking C4 effluent and at least one other effluent stream, where the cracking C4 effluent comprises the butenes, and the cracking C4 effluent is the portion of the cracking reaction effluent contacted with methanol in the MTBE reactor.

12. A process for producing olefins, the process comprising:
contacting a hydrocarbon feed with a cracking catalyst under high-severity conditions to produce a cracking reaction effluent comprising at least butenes, where the high-severity conditions comprise a temperature of greater than or equal to 500° C., a residence time of less than 3 seconds, and a cracking catalyst to hydrocarbon weight ratio of greater than 5:1;
contacting at least a portion of the cracking reaction effluent with a metathesis catalyst, where the contacting causes metathesis of at least a portion of the butenes in the portion of the cracking reaction effluent to produce a metathesis reaction product;
separating the metathesis reaction product into a metathesis C5+ effluent and at least one olefin-containing effluent, the olefin-containing effluent comprising at least one of ethylene, propene, butenes, or combinations thereof;
contacting the metathesis C5+ effluent with the cracking catalyst and the hydrocarbon feed under high-severity conditions to produce the cracking reaction effluent,
in which the cracking reaction effluent further comprises isobutene and the process further comprises removing isobutene from at least a portion of the cracking reaction effluent to produce a metathesis feed,
in which removing isobutene comprises:
contacting the at least a portion of the cracking reaction effluent with methanol under reaction conditions sufficient to convert at least a portion of the isobutene in the portion of the cracking reaction effluent to methyl tert-butyl ether to produce an MTBE reactor effluent comprising the methyl tert-butyl ether; and
separating the MTBE reactor effluent into at least an MTBE-containing effluent comprising the methyl tert-butyl ether and a metathesis feed comprising butene, where the metathesis feed is the at least a portion of the cracking reaction effluent contacted with the metathesis catalyst, and

in which, the process further comprises contacting the MTBE-containing effluent with the cracking catalyst under high-severity conditions, where the contacting causes at least a portion of the methyl tert-butyl ether in the MTBE-cont

Assignees

• Saudi Arabian Oil Co

Inventors

• Shaikh Sohel K
• Abudawoud Raed H
• Zhang Zhonglin
• Khokhar Munir D
• Aljumah Furqan

Classifications

• C10G2300/1096

  Aromatics or polyaromatics · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title

• C10G2300/4081

  Recycling aspects · CPC title

• C07C41/06

  by addition of organic compounds only · CPC title

• C07C4/06

  Catalytic processes {(C07C4/025 takes precedence)} · CPC title