Photocurable composition and coating layer including cured product thereof

Patent metadata

Field	Value
Publication number	US-11339288-B2
Application number	US-201816762337-A
Country	US
Kind code	B2
Filing date	Nov 6, 2018
Priority date	Nov 10, 2017
Publication date	May 24, 2022
Grant date	May 24, 2022

Abstract

A photocurable composition is provided. The photocurable composition includes: a urethane acrylamide oligomer derived from a first urethane prepolymer having an isocyanate end group and a polar group-containing acrylamide; a urethane acrylate oligomer derived from a second urethane prepolymer having an isocyanate end group and a polar group-containing (meth)acrylate; and an amide group-containing acrylic polymer derived from acrylamide and a polar group-containing (meth)acrylate.

First claim

The invention claimed is:

1. A photocurable composition comprising:
a urethane acrylamide oligomer derived from a first urethane prepolymer having an isocyanate end group and a polar group-containing acrylamide;
a urethane acrylate oligomer derived from a second urethane prepolymer having an isocyanate end group and a polar group-containing (meth)acrylate; and
an amide group-containing acrylic polymer derived from an acrylamide and a polar group-containing (meth)acrylate, wherein a content of the amide group-containing acrylic polymer is 2 parts by weight or more and 9 parts by weight or less with respect to 100 parts by weight of the photocurable composition.

2. The photocurable composition of claim 1 , wherein the first urethane prepolymer is represented by the following Formula 1:
OCN-A B 1 -A n NCO  [Formula 1]

wherein,
A is derived from a diisocyanate-based compound,
B 1 is derived from a polycarbonate diol having a number average molecular weight of 200 g/mol to 700 g/mol, and
n is an integer from 1 to 10.

3. The photocurable composition of claim 1 , wherein the second urethane prepolymer is represented by the following Formula 2:
OCN-A B 2 -A n NCO  [Formula 2]

wherein,
A is derived from a diisocyanate-based compound,
B 2 is derived from a polycarbonate diol having a number average molecular weight of 1,000 g/mol to 3,000 g/mol, and
n is an integer from 3 to 10.

4. The photocurable composition of claim 1 , wherein a content of the urethane acrylamide oligomer is 10 parts by weight or more and 50 parts by weight or less with respect to 100 parts by weight of the photocurable composition.

5. The photocurable composition of claim 1 , wherein a content of the urethane acrylate oligomer is 10 parts by weight or more and 50 parts by weight or less with respect to 100 parts by weight of the photocurable composition.

6. The photocurable composition of claim 1 , wherein the urethane acrylamide oligomer has a weight average molecular weight of 2,000 g/mol or more and 5,000 g/mol or less.

7. The photocurable composition of claim 1 , wherein the urethane acrylate oligomer has a weight average molecular weight of 10,000 g/mol or more and 15,000 g/mol or less.

8. The photocurable composition of claim 1 , wherein the amide group-containing acrylic polymer has a weight average molecular weight of 5,000 g/mol or more and 10,000 g/mol or less.

9. The photocurable composition of claim 1 , further comprising an additive comprising at least one of a monomer for adjusting viscosity or a photoinitiator.

10. The photocurable composition of claim 9 , wherein a content of the monomer for adjusting viscosity is 20 parts by weight or more and 40 parts by weight or less with respect to 100 parts by weight of the photocurable composition.

11. A coating layer comprising a cured product of the photocurable composition according to claim 1 .

12. The coating layer of claim 11 , wherein an Erichsen cupping value of the coating layer, measured in an atmosphere of 85° C., 85 RH % for 72 hours in accordance with ISO 1520, is 10 mm or more.

13. The coating layer of claim 11 , wherein the coating layer is a decorative layer for a deco film.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Sang Hwan
• Lee Sle
• Kim Jang Soon
• Seo Kwang Su

Classifications

• C08L75/12 Primary

  from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group · CPC title

• C09D175/16 Primary

  having terminal carbon-to-carbon unsaturated bonds · CPC title

• C08G18/6225

  Polymers of esters of acrylic or methacrylic acid · CPC title

• C08L75/16

  having terminal carbon-to-carbon unsaturated bonds · CPC title

• C09D175/12

  from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group · CPC title