Methods for operating polyethylene reactor systems
US-2024392119-A1 · Nov 28, 2024 · US
US11339277B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11339277-B2 |
| Application number | US-201716463613-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 23, 2017 |
| Priority date | Nov 24, 2016 |
| Publication date | May 24, 2022 |
| Grant date | May 24, 2022 |
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A polymer composition comprising a blend of two or more high density polyethylenes: (A) a first high density polyethylene having a density of at least 940 kg/m3 and an MFR2 of 0.25 g/10 min or less; and (B) a second high density polyethylene having a density of at least 940 kg/m3 and an MFR2 of 1.0 g/10 min to 20 g/10 min; wherein said polymer composition has an MFR2 of 0.25 to 15 g/10 min and wherein the components (A) and (B) combined form at least 91 wt % of said polymer composition.
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The invention claimed is: 1. A polymer composition comprising: a blend of two or more high density polyethylenes comprising: a first high density polyethylene having a density of at least 940 kg/m 3 and an MFR 2 of 0.25 g/10 min or less; and a second high density polyethylene having a density of at least 940 kg/m 3 and an MFR 2 of from 1.0 g/10 min to 20 g/10 min, and wherein the second high density polyethylene is multimodal and comprises from 30 to 70 wt % of a lower Mw component and from 70 to 30 wt % of a higher Mw component; wherein said polymer composition has an MFR 2 of from 0.25 to 15 g/10 min, and wherein the first high density polyethylene and the second high density polyethylene combined form at least 91 wt % of said polymer composition. 2. The polymer composition as claimed in claim 1 , wherein the first high density polyethylene is multimodal. 3. The polymer composition as claimed in claim 1 , wherein the polymer composition comprises less than 5 wt % of polypropylene. 4. The polymer composition as claimed in claim 1 , wherein the first high density polyethylene forms from 10 to 70 wt % of the polymer composition and the second high density polyethylene forms from 30 to 90 wt % of the polymer composition. 5. The polymer composition as claimed in claim 1 , wherein the density of the first high density polyethylene is from 945 to 965 kg/m 3 . 6. The polymer composition as claimed in claim 1 , wherein the MFR 5 of the first high density polyethylene is from 0.1 to 0.9 g/10 min. 7. The polymer composition as claimed in claim 1 , wherein the density of the second high density polyethylene is from 955 to 965 kg/m 3 . 8. The polymer composition as claimed in claim 1 , wherein the MFR 2 of the second high density polyethylene is from 2.0 to 10.0 g/10 min. 9. The polymer composition as claimed in claim 1 , wherein the density of the polymer composition is from 950 to 965 kg/m 3 . 10. The polymer composition as claimed in claim 1 , wherein the MFR 2 of the polymer composition is from 0.4 to 6.0 g/10 min. 11. The polymer composition as claimed in claim 1 , wherein the polymer composition further comprises from 0.2 to 9.0 wt % of a carbon black product. 12. The polymer composition as claimed in claim 1 , wherein the polymer composition comprises: from 10 to 70 wt % of the first high density polyethylene; from 30 to 90 wt % of the second high density polyethylene; from 0 to 5 wt % additives; and from 0 to 9 wt % of a carbon black product. 13. The polymer composition as claimed in claim 1 , wherein the MFR 2 according to ISO 1133 of the second high density polyethylene (HDPE) is from 2.0 to 8.0 g/10 min. 14. An article comprising the polymer composition as claimed in claim 1 . 15. The article as claimed in claim 14 , wherein said article is a pallet. 16. A pallet consisting of the polymer composition as claimed in claim 1 . 17. A process for the preparation of an article as claimed in claim 14 , the process comprising blending the first high density polyethylene and the second high density polyethylene to form the polymer composition and moulding the polymer composition to prepare said article. 18. A method of use of the polymer composition as claimed in claim 1 , the method comprising using the polymer composition in the manufacture of an article. 19. The method of use according to claim 18 , wherein said article is a pallet. 20. A pallet comprising a polymer composition, the polymer composition comprising: a blend of two or more high density polyethylenes comprising: a first high density polyethylene having a density of at least 940 kg/m 3 and an MFR 2 of 0.25 g/10 min or less; and a second high density polyethylene having a density of at least 940 kg/m 3 and an MFR 2 of from 1.0 g/10 min to 20 g/10 min, and wherein the second high density polyethylene is multimodal and comprises from 30 to 70 wt % of a lower Mw component and from 70 to 30 wt % of a higher Mw component; wherein said polymer composition has an MFR 2 of from 0.25 to 15 g/10 min, and wherein the first high density polyethylene and the second high density polyethylene combined form at least 91 wt % of said polymer composition.
HDPE · CPC title
Polyethylene · CPC title
containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title
Carbon · CPC title
PP, i.e. polypropylene · CPC title
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