Dispersion powder composition containing vinyl alcohol copolymerisate

Patent metadata

Field	Value
Publication number	US-11339228-B2
Application number	US-201716633761-A
Country	US
Kind code	B2
Filing date	Jul 24, 2017
Priority date	Jul 24, 2017
Publication date	May 24, 2022
Grant date	May 24, 2022

Abstract

Water-redispersible polymer powders with improved characteristics in building materials are prepared using a drying aid which is a polyvinyl alcohol copolymer also containing vinyl ester monomers and specific comonomers.

First claim

The invention claimed is:

1. A water-redispersible polymer powder composition, comprising:
particles of a base polymer, and
at least one vinyl alcohol copolymer,
the water-redispersible polymer powder obtained through the free-radical polymerization in an aqueous medium of one or more ethylenically-unsaturated monomers to form base polymer particles in the presence of a protective colloid and/or emulsifier followed by drying the resulting aqueous polymer dispersion after addition of a protective colloid as a drying aid, wherein
the drying is carried out with a protective colloid of one or more vinyl alcohol copolymers comprising a) 80 to 99 mol % of vinyl alcohol monomer units, b) 0.5 to 10 mol % of monomer units derived from vinyl esters of unbranched or branched alkyl carboxylic acids having 3 to 18 carbon atoms, c) 0.5 to 10 mol % of monomer units derived from ethylenically-unsaturated monomers having one or more functional groups selected from the group consisting of carboxylic acid moieties, sulfonic acid moieties, quaternized amine moieties, phosphoric acid moieties, salts thereof, and mixtures thereof, and d) 0 to 5 mol % of vinyl acetate monomer units, wherein the values in mol % in each case add up to 100 mol %.

2. The water-redispersible polymer powder composition of claim 1 , wherein the vinyl alcohol copolymer includes monomer units b) derived from a vinyl ester of α-branched monocarboxylic acids having 9 to 10 carbon atoms.

3. The water-redispersible polymer powder composition of claim 2 , wherein the vinyl alcohol copolymer includes monomer units c) derived from vinylsulfonic acid, 2-acrylamido-2-methylpropanesulfonic acid, and salts thereof.

4. The water-redispersible polymer powder composition of claim 1 , wherein the vinyl alcohol copolymer includes d) 1 to 4 mol % of vinyl acetate monomer units.

5. The water-redispersible polymer powder composition of claim 1 , wherein a silica sol is added to the aqueous polymer dispersion before or during drying.

6. A process for producing a water-redispersible polymer powder composition comprising polymerizing one or more ethylenically-unsaturated monomers by free-radical polymerization in an aqueous medium in the presence of protective colloid and/or emulsifier, and drying the resulting aqueous polymer dispersion after addition of protective colloid as a drying aid, wherein
drying is carried out using as a drying aid protective colloid one or more vinyl alcohol copolymers comprising a) 80 to 99 mol % of vinyl alcohol monomer units, b) 0.5 to 10 mol % of monomer units derived from vinyl esters of unbranched or branched alkyl carboxylic acids having 3 to 18 carbon atoms, c) 0.5 to 10 mol % of monomer units derived from ethylenically-unsaturated monomers having one or more functional groups selected from the group consisting of carboxylic acid moiety, sulfonic acid moiety, quaternized amine moiety, phosphoric acid moiety, and salts thereof, and d) 0 to 5 mol % of vinyl acetate monomer units, wherein the values in mol % in each case add up to 100 mol %.

7. A mineral binder-containing building composition, comprising at least one water-redispersible polymer power composition of claim 1 .

8. The mineral binder-containing building composition of claim 7 , which is a sealing slurry, building adhesive, render, spackling compound, floor-filling compound, leveling compound, jointing mortar, repair mortar or crack-bridging render.

9. In a coating composition for paper and/or textile, the improvement comprising employing a water-redispersible polymer powder composition of claim 1 .

10. In a process wherein sand is consolidated through the use of a polymer powder binder composition, the improvement comprising:
employing as at least one binder, a water-redispersible polymer powder composition of claim 1 .

11. The water-redispersible polymer powder composition of claim 1 , wherein the vinyl alcohol copolymers comprise:
a) 85 to 97 mol %, of vinyl alcohol monomer units,
b) 1 to 8 mol %, of monomer units derived from vinyl esters of unbranched or branched alkyl carboxylic acids having 3 to 18 carbon atoms,
c) 1 to 8 mol %, of monomer units derived from ethylenically-unsaturated monomers having one or more functional groups selected from the group consisting of carboxylic acid moiety, sulfonic acid moiety, quaternized amine moiety, phosphoric acid moiety, and salts thereof, and
d) 1 to 4 mol %, of vinyl acetate monomer units, wherein the values in mol % in each case add up to 100 mol %.

12. The water-redispersible polymer powder composition of claim 1 , wherein the vinyl alcohol copolymers comprise:
a) 85 to 97 mol %, of vinyl alcohol monomer units,
b) 1 to 8 mol %, of monomer units derived from vinyl esters of a-branched monocarboxylic acid acids having 5 to 13 carbon atoms,
c) 1 to 8 mol %, of monomer units derived from one or more monomers selected from the group consisting of acrylic acid and methacrylic acid, maleic acid, maleic acid anhydride, crotonic acid, vinylsulfonic acid, sulfopropyl (meth)acrylate, 2-acrylamido-2-methylpropanesulfonic acid and methallyl sulfonic acid, 1-allyloxy-2-hydroxysulfonic acid, 3-sulfopropyl acrylate, 3-sulfopropyl methacrylate, bis(3-sulfopropyl) itaconate and salts thereof, and
d) 1 to 4 mol %, of vinyl acetate monomer units, wherein the values in mol % in each case add up to 100 mol %.

13. The water-redispersible polymer powder composition of claim 1 , wherein the vinyl alcohol copolymers comprise:
a) 85 to 97 mol %, of vinyl alcohol monomer units,
b) 1 to 8 mol %, of monomer units derived from vinyl esters of a-branched monocarboxylic acids having 9 to 10 carbon atoms,
c) 1 to 8 mol %, of monomer units derived from one or more monomers selected from the group consisting of vinylsulfonic acid, 2-acrylamido-2-methylpropanesulfonic acid, and salts thereof, and
d) 1 to 4 mol %, of vinyl acetate monomer units, wherein the values in mol % in each case add up to 100 mol %.

14. The water-redispersible polymer powder composition of claim 1 , wherein one or more of the vinyl alcohol copolymers are applied only as drying aid and not in the polymerization.

15. The water-redispersible polymer powder composition of claim 1 , wherein the vinyl alcohol copolymers are applied in a total amount of 0.1 to 20% by weight, based on the total weight of the polymeric constituents of the aqueous dispersion of the base polymer.

16. The water-redispersible polymer powder composition of claim 1 , wherein the vinyl alcohol copolymers are applied in a total amount of 1 to 7% by weight, based on the total weight of the polymeric constituents of the aqueous dispersion of the base polymer.

17. The water-redispersible polymer composition of claim 1 , wherein the base polymer particles are particles of an ethylene and vinyl acetate copolymer or a vinyl acetate homopolymer.

18. The water-redispersible polymer composition of claim 1 , wherein the base polymer particles are copolymers of vinyl acetate with one or more of vinyl chloride and ethylene.

Assignees

• Wacker Chemie Ag

Inventors

• Hashemzadeh Abdulmajid
• Brandmueller Peter
• Dobler Walter
• Herold Hardy

Classifications

• C04B2111/70

  Grouts, e.g. injection mixtures for cables for prestressed concrete · CPC title

• C04B2111/00672

  Pointing or jointing materials · CPC title

• C08F220/585

  and containing other heteroatoms, e.g. 2-acrylamido-2-methylpropane sulfonic acid [AMPS] · CPC title

• C04B26/04

  obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C08F2/24 Primary

  with the aid of emulsifying agents · CPC title