Process for upgrading natural gas liquids from shale gas without front-end demethanizer

Patent metadata

Field	Value
Publication number	US-11339104-B2
Application number	US-202016831993-A
Country	US
Kind code	B2
Filing date	Mar 27, 2020
Priority date	Mar 29, 2019
Publication date	May 24, 2022
Grant date	May 24, 2022

Abstract

Processes and systems for upgrading natural gas liquids. At least a portion of the natural gas liquid components in a shale gas stream can be dehydrogenated to their corresponding olefin derivatives prior to separating any methane from the liquids. Further processing subsequent to dehydrogenation could include various separations, oligomerizing olefins produced in the dehydrogenation step, recovering desired products, etc. The order of the processing steps subsequent to dehydrogenation could be adjusted in various cases.

First claim

What is claimed is:

1. A process for upgrading natural gas liquid (NGL) components, comprising:
providing a hydrocarbon gas comprising at least 50 mol % methane and one or more other alkanes;
at least partially dehydrogenating the hydrocarbon gas to produce a dehydrogenation effluent comprising the methane, hydrogen, one or more alkenes, and one or more unconverted other alkanes;
separating the methane from the dehydrogenation effluent; and then
recovering the one or more alkenes.

2. The process of claim 1 , wherein the separated methane contains at least a portion of the hydrogen formed during dehydrogenation of the hydrocarbon gas.

3. The process of claim 2 , further comprising separating at least a portion of the hydrogen from the separated methane to provide a hydrogen-rich stream.

4. The process of claim 1 , further comprising separating the one or more unconverted other alkanes from the dehydrogenated effluent and recycling the separated one or more unconverted other alkanes to the hydrocarbon gas.

5. The process of claim 1 , wherein the at least partially dehydrogenating the hydrocarbon gas takes place in a reactor comprising one or more catalyst beds to catalytically convert the alkanes to their respective alkene derivatives.

6. The process of claim 1 , further comprising at least partially oligomerizing the one or more alkenes in the dehydrogenation effluent to provide an oligomerization effluent comprising the one or more unconverted other alkanes and one or more C4 to C26 oligomers.

7. A process for upgrading natural gas liquid (NGL) components, comprising:
providing a hydrocarbon gas feed comprising acid gas, water, methane and one or more other alkanes;
removing at least a portion of the acid gas and water to provide a treated gas having concentrations of acid gas and water within a desired range for downstream processing;
at least partially dehydrogenating the treated gas to produce a dehydrogenation effluent comprising the methane, hydrogen, one or more alkenes, and one or more unconverted other alkanes;
separating methane from the dehydrogenation effluent; and then
recovering the one or more alkenes.

8. The process of claim 7 , wherein the separated methane contains at least a portion of the hydrogen formed during dehydrogenation of the hydrocarbon gas.

9. The process of claim 8 , further comprising separating at least a portion of the hydrogen from the separated methane to provide a hydrogen-rich stream.

10. The process of claim 9 , further comprising separating the one or more unconverted other alkanes from the dehydrogenated effluent and recycling the separated one or more alkanes to the treated gas.

11. The process of claim 7 , wherein at least partially dehydrogenating the treated gas takes place in a reactor comprising one or more catalyst beds to catalytically convert the alkanes to their respective alkene derivatives.

12. The process of claim 7 , wherein the one or more other alkanes comprise one or more natural gas liquids.

13. A process for upgrading natural gas liquid (NGL) components, comprising:
providing a hydrocarbon gas comprising at least 50 mol % methane and one or more natural gas liquids comprising C 2+ hydrocarbons;
at least partially dehydrogenating the one or more natural gas liquids in the hydrocarbon gas to provide a dehydrogenation effluent comprising the methane, hydrogen, one or more C2+ olefins, and one or more unconverted other alkanes;
at least partially oligomerizing the one or more C 2+ olefins in the dehydrogenation effluent to provide an oligomerization effluent comprising the methane, the one or more unconverted other alkanes and C 4 to C 26 oligomers; and then
separating the methane from the oligomers.

14. The process of claim 13 , further comprising at least partially separating hydrogen from the dehydrogenation effluent prior to at least partially oligomerizing the one or more C 2+ olefins.

15. The process of claim 13 , further comprising separating the one or more unconverted other alkanes from the methane and recycling the separated one or more unconverted other alkanes to the hydrocarbon gas.

16. The process of claim 13 , further comprising recovering the oligomers as a liquid hydrocarbon product.

17. The process of claim 13 , further comprising at least partially separating hydrogen from the methane.

18. The process of claim 13 , further comprising separating the one or more unconverted other alkanes from the oligomers.

19. The process of claim 18 , further comprising recycling the separated one or more alkanes to the hydrocarbon gas.

20. The process of claim 13 , wherein the hydrocarbon gas is derived from shale gas or the hydrocarbon gas is a sweet and dry natural gas.

Assignees

• Purdue Research Foundation

Inventors

• Agrawal Rakesh
• Li Yiru

Classifications

• C07C2/06

  of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C07C5/333 Primary

  Catalytic processes · CPC title

• C10G5/00

  Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas · CPC title

• C10G2300/1025

  Natural gas · CPC title

• C10G50/00

  Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation · CPC title