Method for manufacturing sulfur tetrafluoride
US-2019375636-A1 · Dec 12, 2019 · US
US11339052B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11339052-B2 |
| Application number | US-201716472395-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 13, 2017 |
| Priority date | Dec 26, 2016 |
| Publication date | May 24, 2022 |
| Grant date | May 24, 2022 |
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An object of this invention is to provide a simple method for producing sulfur tetrafluoride. The object is achieved by a method for producing sulfur tetrafluoride, comprising step A of reacting a fluorinated halogen compound with sulfur chloride, the fluorinated halogen compound being represented by formula: XFn, wherein X is chlorine, bromine, or iodine; and n is a natural number of 1 to 5.
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The invention claimed is: 1. A method for producing sulfur tetrafluoride, comprising reacting a fluorinated halogen compound with sulfur chloride, wherein the fluorinated halogen compound is IF 5 , BrF 3 , or a combination thereof. 2. The method according to claim 1 , wherein the fluorinated halogen compound is IF 5 . 3. The method according to claim 2 , wherein ICl is produced as a by-product, but no I 2 is produced. 4. The method according to claim 3 , wherein the sulfur chloride is sulfur monochloride. 5. The method according to claim 2 , wherein the sulfur chloride is sulfur monochloride. 6. The method according to claim 1 , wherein the sulfur chloride is sulfur monochloride. 7. A deoxyfluorination method of a carbonyl compound or a hydroxyl-containing organic compound, the method comprising employing a composition comprising sulfur tetrafluoride and ICl for the deoxyfluorination of the carbonyl compound or the hydroxyl-containing compound.
Halogenation · CPC title
of hydroxyl groups · CPC title
Sulfur tetrafluoride · CPC title
of oxygen atoms of carbonyl groups · CPC title
Fluorides · CPC title
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