Laminated film and flexible electronic device
US-2017268929-A1 · Sep 21, 2017 · US
US11338499B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11338499-B2 |
| Application number | US-202016780243-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 3, 2020 |
| Priority date | Aug 18, 2017 |
| Publication date | May 24, 2022 |
| Grant date | May 24, 2022 |
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A substrate and a method for producing the same are disclosed herein. In some embodiments, a substrate includes a base layer, a black layer formed on the base layer, and column spacers formed on the black layer, wherein a loss rate of spacers measured by a peel test is 15% or less. The substrate can have excellent adhesiveness of the spacer to the base layer or the black layer and ensuring appropriate darkening properties. The method can effectively produce such a substrate without adverse effects such as occurrence of foreign materials without separate treatment such as heat treatment.
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The invention claimed is: 1. A substrate, comprising: a base layer; a black layer; an electrode layer disposed between the black layer and the base layer; and column spacers formed on the black layer, wherein the black layer is a multilayer structure comprising a first layer and at least one second layer, wherein the first layer is a metal layer and the at least one second layer is one of a metal oxide layer, a metal nitride layer, or a metal oxynitride layer, wherein each of the metals in the metal layer, the metal oxide layer, the metal nitride layer, and the metal oxynitride layer has a physical ductility value of 0.55 or more, wherein a loss rate of spacers is 15% or less, wherein the loss rate is measured by attaching a pressure-sensitive adhesive tape to the base layer, wherein the pressure-sensitive adhesive tape has a peel force of about 3.72 N/10 mm to about 4.16 N/10 mm, and peeling the pressure-sensitive adhesive tape from the base layer at a peel angle of 180 degrees in accordance with JIS Z 1522, and wherein the black layer is in contact with the electrode layer. 2. The substrate according to claim 1 , wherein the base layer is a flexible base layer. 3. The substrate according to claim 1 , wherein a ratio (T/B) of an area (B) of the black layer and an area (T) of a bottom of the column spacer is in a range of 0.5 to 1.5. 4. The substrate according to claim 1 , wherein the black layer is a multilayer structure comprising the first layer and two second layers, wherein each second layer is disposed on opposing sides of the first layer, and wherein the two second layers are the same, and one of the metal oxide layer, the metal nitride layer or the metal oxynitride layer. 5. The substrate according to claim 1 , wherein the black layer is a multilayer structure comprising the first layer and two second layers, each second layer on opposing sides of the first layer, and the two second layers are each, independently, one of the metal oxide layer, the metal nitride layer or the metal oxynitride layer. 6. The substrate according to claim 1 , wherein the spacers have a hemispherical portion on the ends of the spacers opposite the black layer. 7. An optical device, comprising: the substrate of claim 1 ; and a second substrate disposed opposite to the substrate, wherein a gap is maintained between the substrate and the second substrate by the column spacers.
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