Composition containing ester quat, cationic polysaccharide and nonionic polysaccharide

Patent metadata

Field	Value
Publication number	US-11332697-B2
Application number	US-201615545107-A
Country	US
Kind code	B2
Filing date	Jan 27, 2016
Priority date	Jan 28, 2015
Publication date	May 17, 2022
Grant date	May 17, 2022

Abstract

The present invention relates to a composition comprising: (a) a bis-(2-hydroxypropyl)-dimethylammonium methyl-sulphate fatty acid ester having an average chain length of the fatty acid moieties of from 12 to 30 carbon atoms; (b) a cationic poly saccharide; and (c) a nonionic polysaccharide. The present invention also relates to the method of use of the composition.

First claim

The invention claimed is:

1. A composition comprising:
(a) a bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester having an average chain length of the fatty acid moieties of from 12 to 30 carbon atoms and present in an amount of from 0.5 wt. % to 10 wt. % based on the total weight of the composition;
(b) from 0.2 to 2 wt. % of a cationic polysaccharide; and
(c) from 0.2 to 2 wt. % of a nonionic polysaccharide.

2. The composition according to claim 1 , wherein the bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester has a molar ratio of fatty acid moieties to amine moieties of from 1.85 to 1.99, an average chain length of the fatty acid moieties of from 16 to 18 carbon atoms and an iodine value of the fatty acid moieties, calculated for the free fatty acid, of from 0.5 to 60.

3. The composition according to claim 2 , wherein the bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester is a mixture of at least one di-ester of formula:
[(CH 3 ) 2 N + (CH 2 CH(CH 3 )OC(═O)R) 2 ]CH 3 SO 4   (I)

and at least one mono-ester of formula:
[(CH 3 ) 2 N + (CH 2 CH(CH 3 )OH)(CH 2 H(CH 3 )OC(═O)R)]CH 3 SO 4 −   (II),

wherein R is a hydrocarbon group.

4. The composition according to claim 1 , wherein the bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester is a mixture of at least one di-ester of formula:
[(CH 3 ) 2 N + (CH 2 CH(CH 3 )OC(═O)R) 2 ]CH 3 SO 4   (I)

and at least one mono-ester of formula:
[(CH 3 ) 2 N + (CH 2 CH(CH 3 )OH)(CH 2 H(CH 3 )OC(═O)R)]CH 3 SO 4 −   (II),

wherein R is a hydrocarbon group.

5. The composition according to claim 1 , wherein the cationic polysaccharide is a cationic guar.

6. The composition according to claim 1 , wherein the nonionic polysaccharide is a nonionic guar.

7. The composition according to claim 1 , wherein the cationic polysaccharide has an average molecular weight of between 100,000 daltons and 1,500,000 daltons.

8. The composition according to claim 1 , wherein the ratio of the weight of the bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester to the total weight of the cationic polysaccharide and the nonionic polysaccharide is between 100:1 and 2:1.

9. The composition according to claim 1 , wherein the composition further comprises a fatty acid.

10. The composition according to claim 1 , wherein the composition further comprises a fragrance material or perfume.

11. The composition according to claim 1 , wherein the composition further comprises a silicone compound.

12. The composition according to claim 1 , wherein the bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester is present in an amount of from 1 wt. % to 10 wt. % based on the total weight of the composition.

13. The composition according to claim 1 , wherein the bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester is present in an amount of from 3 wt. % to 8 wt. % based on the total weight of the composition.

14. A method for enhancing fragrance or perfume longevity of a composition by adding to the composition (a) a bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester having an average chain length of the fatty acid moieties of from 12 to 30 carbon atoms atoms, and present in an amount of from 0.5 wt. % to 10 wt. % based on the total weight of the composition; (b) from 0.2 to 2 wt. % of a cationic polysaccharide; (c) from 0.2 to 2 wt. % of a nonionic polysaccharide; and (d) a fragrance material or perfume.

15. The method according to claim 14 , wherein the composition further comprises a silicone compound.

16. A method for conditioning a fabric, wherein the method comprises a step of contacting the fabric with an aqueous medium, wherein the aqueous medium comprises the composition according to claim 1 .

17. The method according to claim 16 , wherein the cationic polysaccharide is a cationic guar and the nonionic polysaccharide is a nonionic guar.

18. A recipient comprising the composition according to claim 1 .

19. The recipient according to claim 18 , wherein the recipient has an opening and a cover for closing the opening.

20. A composition comprising:
(a) a bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester having an average chain length of the fatty acid moieties of from 12 to 30 carbon atoms and present in an amount of from 0.5 wt. % to 10 wt. % based on the total weight of the composition,
wherein the bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester is a mixture of at least one di-ester of formula:
[(CH 3 ) 2 N + (CH 2 CH(CH 3 )OC(═O)R) 2 ]CH 3 SO 4   (I)

and at least one mono-ester of formula:
[(CH 3 ) 2 N + (CH 2 CH(CH 3 )OH)(CH 2 H(CH 3 )OC(═O)R)]CH 3 SO 4 −   (II),

wherein R is a hydrocarbon group;
(b) from 0.2 to 2 wt. % of a cationic polysaccharide; and
(c) from 0.2 to 2 wt. % of a nonionic polysaccharide, and
wherein the ratio of the weight of the bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester to the total weight of the cationic polysaccharide and the nonionic polysaccharide is between 100:1 and 2:1.

Assignees

• Rhodia Operations

Inventors

• Zhang Hai Zhou
• Christov Nikolay
• Jin Da Wei
• He Lin

Classifications

• C11D3/222

  Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin · CPC title

• C11D3/50

  Perfumes · CPC title

• C11D1/62

  Quaternary ammonium compounds · CPC title

• C11D3/001 Primary

  Softening compositions · CPC title

• C11D3/349

  additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea · CPC title