Fluorine-containing ether compound, lubricant for magnetic recording medium and magnetic recording medium

Patent metadata

Field	Value
Publication number	US-11332686-B2
Application number	US-201716470713-A
Country	US
Kind code	B2
Filing date	Nov 24, 2017
Priority date	Dec 20, 2016
Publication date	May 17, 2022
Grant date	May 17, 2022

Abstract

A fluorine-containing ether compound represented by formula (1) shown below.R4—CH2—R3—CH2—R2—CH2—R1—CH2—R2—CH2—R3—CH2—R4  (1)(In formula (1), R1 and R3 represent different perfluoropolyether chains, R2 represents a linking group containing one or more polar groups, and R4 represents a terminal group containing two or more polar groups.)

First claim

The invention claimed is:

1. A fluorine-containing ether compound represented by a formula (1) shown below:
R 4 —CH 2 —R 3 —CH 2 —R 2 —CH 2 —R 1 —CH 2 —R 2 —CH 2 —R 3 —CH 2 —R 4   (1)

(wherein and R 3 represent different perfluoropolyether chains, R 2 is represented by a formula (6) shown below, and R 4 is a terminal group represented by one of formulas (2-2) to (2-5) shown below)

(wherein in formula (6), w represents an integer of 1),

(wherein in formula (2-2), p represents an integer of 1 to 5),

(wherein in formula (2-3), s represents an integer of 2 to 5),

(wherein in formula (2-4), t represents an integer of 1 to 5),

(wherein in formula (2-5), q represents an integer of 2 to 5).

2. The fluorine-containing ether compound according to claim 1 , wherein R′ in the formula (1) is a group represented by one of formulas (3-1), (3-2), (4) and (5) shown below:

(wherein in formula (3-1), m represents an integer of 1 to 20, and n represents an integer of 1 to 10),
—CF 2 —O—(CF 2 CF 2 O) g —CF 2 —  (3-2)

(wherein in formula (3-2), g represents an integer of 1 to 20),

(wherein in formula (4), u represents an integer of 1 to 30),

(wherein in formula (5), v represents an integer of 1 to 30).

3. The fluorine-containing ether compound according to claim 1 , wherein the compound represented by the formula (1) is represented by a formula (E) shown below, and Rf in the formula (E) shown below is represented by a formula (RF) shown below:

(wherein in formula (RF), x represents an integer of 1 to 7, and y represents an integer of 1 to 7).

4. The fluorine-containing ether compound according to claim 1 , wherein the compound represented by the formula (1) is represented by a formula (F) shown below, and Rf in the formula (F) shown below is represented by a formula (RF) shown below:

(wherein in formula (RF), x represents an integer of 1 to 7, and y represents an integer of 1 to 7).

5. The fluorine-containing ether compound according to claim 1 , wherein the compound represented by the formula (1) is represented by a formula (H) shown below, and Rf in the formula (H) shown below is represented by a formula (RF) shown below:

(wherein in formula (RF), x represents an integer of 1 to 7, and y represents an integer of 1 to 7).

6. The fluorine-containing ether compound according to claim 1 , wherein the compound represented by the formula (1) is represented by a formula (I) shown below, and Rf in the formula (I) shown below is represented by a formula (RF) shown below:

(wherein in formula (RF), x represents an integer of 1 to 7, and y represents an integer of 1 to 7).

7. The fluorine-containing ether compound according to claim 1 , wherein a number average molecular weight thereof is within a range from 1,000 to 10,000.

8. A lubricant for a magnetic recording medium comprising the fluorine-containing ether compound according to claim 1 .

9. A magnetic recording medium comprising at least a magnetic layer, a protective layer and a lubricant layer provided sequentially on a substrate, wherein the lubricant layer comprises the fluorine-containing ether compound according to claim 1 .

10. The magnetic recording medium according to claim 9 , wherein an average thickness of the lubricant layer is from 0.5 nm to 3 nm.

11. A fluorine-containing ether compound represented by a formula (1) shown below:
R 4 —CH 2 —R 3 —CH 2 —R 2 —CH 2 —R 1 —CH 2 —R 2 —CH 2 —R 3 —CH 2 —R 4   (1)

(wherein R 1 and R 3 represent different perfluoropolyether chains, R 1 is represented by a formula (RF-2) shown below or a formula (RF-3) shown below, R 2 represents a linking group containing one or more polar groups, and R 4 represents a terminal group containing two or more polar groups),
—CF 2 —O—(CF 2 CF 2 O) d —CF 2 —  (RF-2)

(wherein in formula (RF-2), d represents an integer of 1 to 12),
—CF 2 —O—(CF 2 CF 2 O) e —(CF 2 O) f —CF 2 —  (RF-3)

(wherein in formula (RF-3), e represents an integer of 1 to 20, and f represents an integer of 1 to 10).

12. The fluorine-containing ether compound according to claim 11 , wherein the compound represented by the formula (1) is represented by a formula (C) shown below, and Rf in the formula (C) shown below is represented by a formula (RF) shown below:

(wherein in formula (RF), x represents an integer of 1 to 7, and y represents an integer of 1 to 7).

13. The fluorine-containing ether compound according to claim 11 , wherein the compound represented by the formula (1) is represented by a formula (K) shown below, and in the formula (K) shown below, Rf is represented by a formula (RF) shown below, and Rf 1 is represented by a formula (RF-1) shown below:

(wherein in formula (RF), x represents an integer of 1 to 7, and y represents an integer of 1 to 7, and in formula (RF-1), z represents an integer of 1 to 10).

14. A lubricant for a magnetic recording medium comprising the fluorine-containing ether compound according to claim 11 .

15. A magnetic recording medium comprising at least a magnetic layer, a protective layer and a lubricant layer provided sequentially on a substrate, wherein the lubricant layer comprises the fluorine-containing ether compound according to claim 11 .

Assignees

• Showa Denko Kk

Inventors

• Fukumoto Naoya
• Yamaguchi Yuta
• Ito Naoko
• Murofushi Katsumi

Classifications

• C08G65/337

  containing other elements (organic compounds containing halogens only as halides of a carboxyl group C08G65/332) · CPC title

• C10M2213/043

  used as base material · CPC title

• C08G65/331

  containing oxygen {(cyclic ether compounds C08G65/26)} · CPC title

• C10M107/38 Primary

  containing halogen · CPC title

• C10M2213/0606

  used as base material · CPC title