Composition comprising heterophasic propylene copolymer

Patent metadata

Field	Value
Publication number	US-11332604-B2
Application number	US-201816635670-A
Country	US
Kind code	B2
Filing date	Aug 3, 2018
Priority date	Aug 8, 2017
Publication date	May 17, 2022
Grant date	May 17, 2022

Abstract

The invention relates to composition comprising (A) a propylene-based polymer, (B1) a first elastomer of ethylene and α-olefin comonomer having 4 to 10 carbon atoms, (B2) a second elastomer of ethylene and α-olefin comonomer having 4 to 10 carbon atoms and (C) an inorganic filler, wherein (B1) the first elastomer has a density of 0.850 to 0.890 g/cm3 and a melt flow index of 5 to 50 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 190° C., wherein (B2) the second elastomer has a density of 0.850 to 0.890 g/cm3 and a melt flow index of 0.55 to 4 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 190° C., wherein the total amount of (B1) the first elastomer and (B2) the second elastomer is 2 to 30 wt % based on the total composition, wherein the amount of (C) the inorganic filler is 0.1 to 30 wt % based on the total composition.

First claim

The invention claimed is:

1. A composition comprising:
(A) a propylene-based polymer,
(B1) a first elastomer that is ethylene-1-octene copolymer,
(B2) a second elastomer that is ethylene-1-octene copolymer and
(C) an inorganic filler,
wherein (B1) the first elastomer has a density of 0.850 to 0.890 g/cm 3 and a melt flow index of 5 to 50 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 190° C.,
wherein (B2) the second elastomer has a density of 0.850 to 0.890 g/cm 3 and a melt flow index of 0.55 to 4 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 190° C., and
wherein the total amount of (B1) the first elastomer and (B2) the second elastomer is 2 to 30 wt % based on the total composition,
wherein the amount of (C) the inorganic filler is 0.1 to 30 wt % based on the total composition.

2. The composition according to claim 1 , wherein the amount of the second elastomer with respect to the total of the first elastomer and the second elastomer in the composition is 10 to 90 wt %.

3. The composition according to claim 1 , wherein the melt flow index of the first elastomer is 5 to 35 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 190° C.

4. The composition according to claim 1 , wherein the density of the first elastomer is 0.855 to 0.880 g/cm 3 .

5. The composition according to claim 1 , wherein the density of the second elastomer is 0.850 to 0.870 g/cm 3 .

6. The composition according to claim 1 , wherein the melt flow index of the second elastomer is 0.7 to 3 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 190° C.

7. The composition according to claim 1 , wherein the melt flow index of the first elastomer is 10 to 50 dg/min and measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 190° C. and the melt flow index of the second elastomer is 0.55 to 3 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 190° C.

8. The composition according to claim 1 , wherein the composition is made by a process involving:
adding the first elastomer and the second elastomer as separate components,
adding the first elastomer and the second elastomer as one component made by melt-mixing the first elastomer and the second elastomer, or
adding the first elastomer and the second elastomer as a bimodal elastomer made by polymerizing the first elastomer and subsequently polymerizing the second elastomer in the presence of the first elastomer or polymerizing the second elastomer and subsequently polymerizing the first elastomer in the presence of the second elastomer.

9. The composition according to claim 8 , wherein the composition is made by a process involving
adding the first elastomer and the second elastomer as a bimodal elastomer made by polymerizing the first elastomer and subsequently polymerizing the second elastomer in the presence of the first elastomer or polymerizing the second elastomer and subsequently polymerizing the first elastomer in the presence of the second elastomer.

10. The composition according to claim 1 , wherein the propylene-based polymer is a heterophasic propylene copolymer consisting of
(a) a propylene-based matrix,
wherein the propylene-based matrix consists of a propylene homopolymer and/or a propylene copolymer consisting of at least 96 wt % of propylene monomer units and at most 4 wt % of ethylene monomer units and/or α-olefin monomer units having 4 to 10 carbon atoms, based on the total weight of the propylene-based matrix and
wherein the propylene-based matrix is present in an amount of 65 to 95 wt % based on the total heterophasic propylene copolymer and
(b) a dispersed ethylene-α-olefin copolymer, wherein the dispersed ethylene-α-olefin copolymer is an ethylene-propylene copolymer, wherein the ethylene-α olefin copolymer is present in an amount of 35 to 5 wt % based on the total heterophasic propylene copolymer.

11. The composition according to claim 10 , wherein
the propylene-based matrix is a propylene homopolymer, and/or
the ethylene-α olefin copolymer is present in an amount of 30 to 5 wt %, based on the total heterophasic propylene copolymer, and/or
the amount of ethylene monomer units in the ethylene-α-olefin copolymer is in the range of 40 to 65 wt %, based on the ethylene-α-olefin copolymer.

12. The composition according to claim 10 , wherein the propylene-based matrix has a melt flow index of 0.3 to 300 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C. and/or the dispersed ethylene-α-olefin copolymer has a melt flow index of 0.1 to 3 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C.

13. The composition according to claim 1 , wherein (A) the propylene-based polymer has a melt flow index of 30 to 150 dg/min measured according to ASTM D1238 2.16 kg/230° C. and/or the composition has a melt flow index of at least 20 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C.

14. The composition according to claim 1 , wherein the inorganic filler is selected from the group consisting of calcium carbonate, talc, magnesium carbonate, synthetic carbonates, wollastonite, dolomite, gypsum, kaolinite, aluminum hydroxide, aluminosilicates, mica, natural siliconates, silica containing aggregates, zeolites and mixtures thereof.

15. A process for the preparation of the composition according to claim 1 , comprising melt mixing (A), (B1), (B2) and (C).

16. An article comprising the composition of claim 1 .

Assignees

• Sabic Global Technologies Bv

Inventors

• Huang Ting
• Shi Hongtao
• Fu Yang
• Soliman Maria
• Wan Dong

Classifications

• C08L23/12 Primary

  Polypropene · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L2207/02

  Heterophasic composition · CPC title

• C08L23/16

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title